Polymer-supported nitroxyl radical catalyst for selective aerobic oxidation of primary alcohols to aldehydes

2005 ◽  
pp. 1085 ◽  
Author(s):  
Michelle Gilhespy ◽  
Martin Lok ◽  
Xavier Baucherel
Keyword(s):  
Nitroxyl Radical ◽  
Aerobic Oxidation ◽  
Primary Alcohols ◽  
Polymer Supported ◽  
Selective Aerobic Oxidation

Selective Aerobic Oxidation of Primary Alcohols to Aldehydes

Synlett ◽  
2017 ◽  
Vol 28 (13) ◽  
pp. 1554-1557 ◽  
Author(s):  
Masatoshi Shibuya ◽  
Keisuke Furukawa ◽  
Yoshihiko Yamamoto
Keyword(s):  
Carboxylic Acid ◽  
Selective Oxidation ◽  
Aerobic Oxidation ◽  
Primary Alcohols ◽  
Co Catalyst ◽  
Tert Butyl ◽  
Selective Aerobic Oxidation

The 2-azaadamantane-N-oxyl (AZADO)- and 9-azanoradamantane-N-oxyl (nor-AZADO)-catalyzed selective oxidation of primary alcohols to the corresponding aldehydes is described. The use of tert-butyl nitrite as the co-catalyst enables efficient aerobic oxidation in MeCN instead of previously reported AcOH; this is important for the selectivity of the reaction. The addition of a solution of saturated aqueous NaHCO3 after the completion of the reaction was effective to suppress the overoxidation of the product to the corresponding carboxylic acid during the workup.

scholarly journals Expansion of Substrate Scope for Nitroxyl Radical/Copper-Catalyzed Aerobic Oxidation of Primary Alcohols: A Guideline for Catalyst Selection

2021 ◽  
Vol 69 (5) ◽  
pp. 488-497
Author(s):  
Yusuke Sasano ◽  
Aoto Yamaichi ◽  
Ryota Sasaki ◽  
Shota Nagasawa ◽  
Yoshiharu Iwabuchi
Keyword(s):  
Nitroxyl Radical ◽  
Aerobic Oxidation ◽  
Primary Alcohols ◽  
Catalyst Selection

Selective aerobic oxidation of primary alcohols catalyzed by a Ru(PPh3)3Cl2/hydroquinone system

1998 ◽  
Vol 39 (31) ◽  
pp. 5557-5560 ◽  
Author(s):  
Atsushi Hanyu ◽  
Eiichiro Takezawa ◽  
Satoshi Sakaguchi ◽  
Yasutaka Ishii
Keyword(s):  
Aerobic Oxidation ◽  
Primary Alcohols ◽  
Selective Aerobic Oxidation

Selective Aerobic Oxidation of Primary Alcohols to Aldehydes over Nb2O5Photocatalyst with Visible Light

ChemPhysChem ◽  
2014 ◽  
Vol 15 (13) ◽  
pp. 2665-2667 ◽  
Author(s):  
Shinya Furukawa ◽  
Tetsuya Shishido ◽  
Kentaro Teramura ◽  
Tsunehiro Tanaka
Keyword(s):  
Visible Light ◽  
Aerobic Oxidation ◽  
Primary Alcohols ◽  
Selective Aerobic Oxidation

scholarly journals Selective Aerobic Oxidation of Alcohols with NO3 − Activated Nitroxyl Radical/Manganese Catalyst System

ChemCatChem ◽  
2018 ◽  
Vol 10 (13) ◽  
pp. 2908-2914 ◽  
Author(s):  
Kalle Lagerblom ◽  
Juha Keskiväli ◽  
Arno Parviainen ◽  
Jere Mannisto ◽  
Timo Repo
Keyword(s):  
Nitroxyl Radical ◽  
Aerobic Oxidation ◽  
Catalyst System ◽  
Oxidation Of Alcohols ◽  
Selective Aerobic Oxidation
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