Selective Aerobic Oxidation of Primary Alcohols to Aldehydes over Nb2O5Photocatalyst with Visible Light

ChemPhysChem ◽  
2014 ◽  
Vol 15 (13) ◽  
pp. 2665-2667 ◽  
Author(s):  
Shinya Furukawa ◽  
Tetsuya Shishido ◽  
Kentaro Teramura ◽  
Tsunehiro Tanaka
Keyword(s):  
Visible Light ◽  
Aerobic Oxidation ◽  
Primary Alcohols ◽  
Selective Aerobic Oxidation

Spatial separation of dual-cocatalysts on bismuth vanadate for selective aerobic oxidation of benzylalcohols to benzaldehydes under visible light irradiation

2018 ◽  
Vol 8 (23) ◽  
pp. 6173-6179 ◽  
Author(s):  
Xu Jin ◽  
Rengui Li ◽  
Yue Zhao ◽  
Xiaodan Liu ◽  
Xiaoqi Wang ◽  
...  
Keyword(s):  
Visible Light ◽  
Visible Light Irradiation ◽  
Aerobic Oxidation ◽  
Spatial Separation ◽  
Bismuth Vanadate ◽  
Light Irradiation ◽  
Selective Aerobic Oxidation

Efficient converting of alcohols to aldehydes under visible light can be achieved on BiVO4 crystals with spatial separation of dual-cocatalysts.

Merging visible light photocatalysis of dye-sensitized TiO2 with TEMPO: the selective aerobic oxidation of alcohols

2017 ◽  
Vol 7 (21) ◽  
pp. 4955-4963 ◽  
Author(s):  
Yichi Zhang ◽  
Zhan Wang ◽  
Xianjun Lang
Keyword(s):  
Visible Light ◽  
Aerobic Oxidation ◽  
Visible Light Photocatalysis ◽  
Dye Sensitized ◽  
Oxidation Of Alcohols ◽  
Selective Aerobic Oxidation

Efficient visible-light-induced selective aerobic oxidation of alcohols was accomplished by merging the photocatalysis of dye-sensitized TiO2 with TEMPO catalysis.

scholarly journals Tertiary amine mediated aerobic oxidation of sulfides into sulfoxides by visible-light photoredox catalysis on TiO2

2015 ◽  
Vol 6 (8) ◽  
pp. 5000-5005 ◽  
Author(s):  
Xianjun Lang ◽  
Wei Hao ◽  
Wan Ru Leow ◽  
Shuzhou Li ◽  
Jincai Zhao ◽  
...  
Keyword(s):  
Visible Light ◽  
Tertiary Amine ◽  
Visible Light Irradiation ◽  
Aerobic Oxidation ◽  
Light Irradiation ◽  
Photoredox Catalysis ◽  
Synergistic Catalysis ◽  
Oxidation Of Sulfides ◽  
Selective Aerobic Oxidation

The selective aerobic oxidation of sulfides into sulfoxides on TiO2 under visible-light irradiation was accomplished through synergistic catalysis with triethylamine.

Selective Aerobic Oxidation of Primary Alcohols to Aldehydes

Synlett ◽  
2017 ◽  
Vol 28 (13) ◽  
pp. 1554-1557 ◽  
Author(s):  
Masatoshi Shibuya ◽  
Keisuke Furukawa ◽  
Yoshihiko Yamamoto
Keyword(s):  
Carboxylic Acid ◽  
Selective Oxidation ◽  
Aerobic Oxidation ◽  
Primary Alcohols ◽  
Co Catalyst ◽  
Tert Butyl ◽  
Selective Aerobic Oxidation

The 2-azaadamantane-N-oxyl (AZADO)- and 9-azanoradamantane-N-oxyl (nor-AZADO)-catalyzed selective oxidation of primary alcohols to the corresponding aldehydes is described. The use of tert-butyl nitrite as the co-catalyst enables efficient aerobic oxidation in MeCN instead of previously reported AcOH; this is important for the selectivity of the reaction. The addition of a solution of saturated aqueous NaHCO3 after the completion of the reaction was effective to suppress the overoxidation of the product to the corresponding carboxylic acid during the workup.

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