Gas phase spectroscopic studies on hydroquinone–water complex

2003 ◽  
Vol 5 (2) ◽  
pp. 294-299 ◽  
Author(s):  
P. S. Meenakshi ◽  
N. Biswas ◽  
S. Wategaonkar
Keyword(s):  
Gas Phase ◽  
Spectroscopic Studies ◽  
Water Complex

scholarly journals Ruthenium trisbipyridine as a candidate for gas-phase spectroscopic studies in a Fourier transform mass spectrometer

2004 ◽  
Vol 18 (2) ◽  
pp. 387-396 ◽  
Author(s):  
Jill R. Scott ◽  
Jason E. Ham ◽  
Bill Durham ◽  
Paul L. Tremblay
Keyword(s):  
Fourier Transform ◽  
Gas Phase ◽  
Mass Spectrometer ◽  
Rate Constant ◽  
Optical Detection ◽  
Sinapinic Acid ◽  
Spectroscopic Studies ◽  
Fluorescence Lifetimes ◽  
Fourier Transform Mass Spectrometer

Metal polypyridines are excellent candidates for gas-phase optical experiments where their intrinsic properties can be studied without complications due to the presence of solvent. The fluorescence lifetimes of [Ru(bpy)3]1+trapped in an optical detection cell within a Fourier transform mass spectrometer were obtained using matrix-assisted laser desorption/ionization to generate the ions with either 2,5-dihydroxybenzoic acid (DHB) or sinapinic acid (SA) as matrix. All transients acquired, whether using DHB or SA for ion generation, were best described as approximately exponential decays. The rate constant for transients derived using DHB as matrix was 4×107s−1, while the rate constant using SA was 1×107s−1. Some suggestions of multiple exponential decay were evident although limited by the quality of the signals. Photodissociation experiments revealed that [Ru(bpy)3]1+generated using DHB can decompose to [Ru(bpy)2]1+, whereas ions generated using SA showed no decomposition. Comparison of the mass spectra with the fluorescence lifetimes illustrates the promise of incorporating optical detection with trapped ion mass spectrometry techniques.

scholarly journals Structural characterization of nucleotide 5′-triphosphates by infrared ion spectroscopy and theoretical studies

2018 ◽  
Vol 20 (44) ◽  
pp. 28319-28330 ◽  
Author(s):  
Rianne E. van Outersterp ◽  
Jonathan Martens ◽  
Giel Berden ◽  
Jeffrey D. Steill ◽  
Jos Oomens ◽  
...  
Keyword(s):  
Gas Phase ◽  
Structural Properties ◽  
Structural Characterization ◽  
Spectroscopic Studies ◽  
Theoretical Studies ◽  
Ion Spectroscopy ◽  
Ir Spectroscopic

Gas-phase IR spectroscopic studies and supporting theoretical studies have been performed on adenosine 5′-triphosphate, cytosine 5′-triphosphate and guanosine 5′-triphosphate to elucidate the structural properties of the NTPs by focusing on the influence of the nucleobase and the extent of deprotonation.

scholarly journals Valence anions of N-acetylproline in the gas phase: Computational and anion photoelectron spectroscopic studies

2011 ◽  
Vol 135 (11) ◽  
pp. 114301 ◽  
Author(s):  
Lidia Chomicz ◽  
Janusz Rak ◽  
Piotr Paneth ◽  
Michael Sevilla ◽  
Yeon Jae Ko ◽  
...  
Keyword(s):  
Gas Phase ◽  
Spectroscopic Studies

scholarly journals Communication: Gas phase vibrational spectroscopy of the azide-water complex

2018 ◽  
Vol 149 (19) ◽  
pp. 191101 ◽  
Author(s):  
John T. Kelly ◽  
Thomas L. Ellington ◽  
Thomas More Sexton ◽  
Ryan C. Fortenberry ◽  
Gregory S. Tschumper ◽  
...  
Keyword(s):  
Gas Phase ◽  
Vibrational Spectroscopy ◽  
Water Complex

Spectroscopic studies of cold, gas-phase biomolecular ions

2009 ◽  
Vol 28 (3) ◽  
pp. 481-515 ◽  
Author(s):  
Thomas R. Rizzo ◽  
Jaime A. Stearns ◽  
Oleg V. Boyarkin
Keyword(s):  
Gas Phase ◽  
Spectroscopic Studies ◽  
Biomolecular Ions ◽  
Cold Gas

Integrated computational approaches for spectroscopic studies of molecular systems in the gas phase and in solution: pyrimidine as a test case

2012 ◽  
Vol 131 (4) ◽  
Author(s):  
Malgorzata Biczysko ◽  
Julien Bloino ◽  
Giuseppe Brancato ◽  
Ivo Cacelli ◽  
Chiara Cappelli ◽  
...  
Keyword(s):  
Gas Phase ◽  
Spectroscopic Studies ◽  
Test Case ◽  
Computational Approaches ◽  
Molecular Systems
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