Time-resolved gas-phase kinetic study of the germylene addition reaction, GeH2 + C2D4, as a function of temperature and pressure: isotope effects and mechanistic complexities

2002 ◽  
Vol 4 (24) ◽  
pp. 6001-6005 ◽  
Author(s):  
Rosa Becerra ◽  
Robin Walsh
Keyword(s):  
Kinetic Study ◽  
Gas Phase ◽  
Addition Reaction ◽  
Isotope Effects ◽  
Time Resolved ◽  
Temperature And Pressure

A kinetic study of the reactions of OH radicals with fluoroethanes. Estimates of C—H bond strengths in fluoroalkanes

1983 ◽  
Vol 61 (5) ◽  
pp. 861-865 ◽  
Author(s):  
Jean-Pierre Martin ◽  
George Paraskevopoulos
Keyword(s):  
Kinetic Study ◽  
Gas Phase ◽  
Rate Constants ◽  
Flash Photolysis ◽  
Oh Radicals ◽  
Bond Dissociation Energies ◽  
Time Resolved ◽  
Dissociation Energies ◽  
Bond Strengths ◽  
Vacuum Uv

A kinetic study of the reactions of OH radicals with a series of fluoroethanes in the gas phase is presented. OH radicals were generated by flash photolysis of H2O vapor in the vacuum uv (λ > 165 nm) and were monitored in absorption by time-resolved attenuation of resonance radiation at 308.15 nm [OH(A2Σ+ → X2Π)]. The following absolute rate constants (in units of 109 cm3mol−1 s−1 at the 95% confidence limit) were determined at [Formula: see text][Formula: see text][Formula: see text][Formula: see text][Formula: see text]From a linear correlation of the present and previously published rate constants with bond dissociation energies, the following quantities (in kcal mol−1 at 298 K) were estimated to be: D(CH3CHF—H) = 96.3 ± 1.5, D(CH2FCHF—H = 98.8 ± 1.0, D(CF3CHF—H) = 103.5 ± 1.0, D(CHF2CF2—H) = 103.0 ± 1.5, and [Formula: see text][Formula: see text]

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