The formation of neutral CCC and its radical cation from the CCC radical anion in the gas phase. A joint experimental and theoretical study

2002 ◽  
pp. 1647-1652 ◽  
Author(s):  
Andrew M. McAnoy ◽  
Suresh Dua ◽  
Detlef Schröder ◽  
John H. Bowie ◽  
Helmut Schwarz
Keyword(s):  
Gas Phase ◽  
Radical Cation ◽  
Radical Anion ◽  
Theoretical Study

Energiebilanz einer Reaktion zwischen Radikal-Kation und Radikal-Anion / Energy Turnover of a Reaction between Radical Cation and Radical Anion

1981 ◽  
Vol 36 (5) ◽  
pp. 601-608 ◽  
Author(s):  
Alfred Stanienda
Keyword(s):  
Gas Phase ◽  
Radical Cation ◽  
Radical Anion ◽  
Energy Turnover ◽  
Entropy Term ◽  
Solvation Energies ◽  
Coulomb Energies

⊿G for the reaction R·+ + R·- → 2 R + ⊿G was calculated according to ⊿G = -(IP-EA) = -⊿ E1 for the reaction in gas phase under ideal conditions. The result was compared with ⊿H in solution measured calorimetrically and the entropy term measured voltammetrically according to ⊿G = ⊿H - T⊿S. Both values for ⊿G agreed satisfactorily. From this it was derived that the solvation energies of R·+ and R·- compensate mutually. The Coulomb energies have little influence on ⊿G only

Structure of tetramethylsilane radical cation: an ESR and theoretical study

1991 ◽  
Vol 95 (8) ◽  
pp. 3132-3135 ◽  
Author(s):  
L. Bonazzola ◽  
J. P. Michaut ◽  
J. Roncin
Keyword(s):  
Radical Cation ◽  
Theoretical Study

Photoelectron Spectroscopy and Theoretical Study of AlnC5-/0 (n = 1-5) clusters: Structural Evolution, Relative Stability of Star-Like Cluster, and Planar Tetracoordinate Carbon Structure

2021 ◽  
Author(s):  
Chao-Jiang Zhang ◽  
Peng Wang ◽  
Xi-Ling Xu ◽  
Hong-Guang Xu ◽  
Weijun Zheng
Keyword(s):  
Gas Phase ◽  
Photoelectron Spectroscopy ◽  
Relative Stability ◽  
Theoretical Study ◽  
Structural Evolution ◽  
Carbon Structure ◽  
Anion Photoelectron Spectroscopy

The AlnC5- (n = 1-5) clusters were detected in the gas-phase and were investigated by mass-selected anion photoelectron spectroscopy. The structures of AlnC5-/0 (n = 1-5) were explored by theoretical...

scholarly journals Negative ion photoelectron spectroscopy confirms the prediction that D3h carbon trioxide (CO3) has a singlet ground state

2016 ◽  
Vol 7 (2) ◽  
pp. 1142-1150 ◽  
Author(s):  
David A. Hrovat ◽  
Gao-Lei Hou ◽  
Bo Chen ◽  
Xue-Bin Wang ◽  
Weston Thatcher Borden
Keyword(s):  
Gas Phase ◽  
Ground State ◽  
Photoelectron Spectroscopy ◽  
Radical Anion ◽  
Negative Ion ◽  
Singlet Ground State

The CO3 radical anion (CO3˙−) has been formed by electrospraying carbonate dianion (CO32−) into the gas phase.

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