Molecular batteries: synthesis and characterization of a dendritic 19-electron FeI complex that reduces C60 to its mono-anionElectronic supplementary information (ESI) available: experimental procedures and characterization data for the new compounds. See http://www.rsc.org/suppdata/cc/b2/b202684h/

2002 ◽  
pp. 1108-1109 ◽  
Author(s):  
Jaime Ruiz ◽  
Charlotte Pradet ◽  
François Varret ◽  
Didier Astruc
Keyword(s):  
Supplementary Information ◽  
Synthesis And Characterization ◽  
New Compounds

Coordination Compounds of Some 3d-Transition Metal Ions with N1-[4-(4-bromo-phenylsulfonyl)-benzoyl]-N4-(4-methoxyphenyl)- thiosemicarbazide

2008 ◽  
Vol 59 (7) ◽  
Author(s):  
Madalina Angelusiu ◽  
Maria Negoiu ◽  
Stefania-Felicia Barbuceanu ◽  
Tudor Rosu
Keyword(s):  
Coordination Compounds ◽  
Magnetic Moments ◽  
Thermo Gravimetric Analysis ◽  
Electronic Spectroscopy ◽  
Transition Metal Ions ◽  
Synthesis And Characterization ◽  
Gravimetric Analysis ◽  
Thermo Gravimetric ◽  
New Compounds

The paper presents the synthesis and characterization of Cu(II), Co(II), Ni(II), Cd(II), Zn(II) and Hg(II) complexes with N1-[4-(4-bromo-phenylsulfonyl)-benzoyl]-N4-(4-methoxyphenyl)-thiosemicarbazide. The new compounds were characterized by IR, EPR, electronic spectroscopy, magnetic moments, thermo-gravimetric analysis and elemental analysis.

Synthesis and Characterization of Some Novel Homo- and Hetero-Diradicals of Hydrazyl and Nitroxide Type

2007 ◽  
Vol 60 (3) ◽  
pp. 173 ◽  
Author(s):  
Petre Ionita ◽  
Floriana Tuna ◽  
Marius Andruh ◽  
Titus Constantinescu ◽  
Alexandru T. Balaban
Keyword(s):  
Free Radical ◽  
Potassium Permanganate ◽  
Lead Dioxide ◽  
Magnetic Behaviour ◽  
Synthesis And Characterization ◽  
Stable Free Radical ◽  
Ms Analysis ◽  
New Compounds

Starting from the well known stable free radical 2,2-diphenyl-1-picrylhydrazyl (DPPH; 2a) and its congener 2,2-diphenyl-1-(4-cyano-2,6-dinitrophenyl)hydrazyl 2b, or from their reduced hydrazine counterparts 1a,b, it was possible to obtain the p-quinonoid compounds 4a,b by oxidation with ceric (Ce4+) sulfate, which by reduction gave the corresponding hydroxyl derivatives 2-phenyl-2-(4-hydroxyphenyl)-1-picrylhydrazine 5a or 2-phenyl-2-(4-hydroxyphenyl)-1-(4-cyano-2,6-dinitrophenyl)hydrazine 5b. These hydroxyl derivatives (5a,b) react with 4-carboxy-TEMPO or 2,2-diphenyl-1-(4-carboxy-2,6-dinitrophenyl)hydrazine to form the corresponding esters 6a,b or 8a,b. These esters (6a,b and 8a,b) lead to the hybrid hetero diradicals (nitroxide–hydrazyl type) 7a,b or homo biradicals (hydrazyl–hydrazyl type) 9a,b by oxidation with lead dioxide or potassium permanganate. The new compounds were characterized by UV-vis, NMR, EPR, and MS analysis, and their magnetic behaviour was investigated.

Darstellung und Charakterisierung des Zwitterions S2C—C(NMe2)2; eine übergangsmetallinduzierte C—C-Kopplung. Komplexchemie der Zwitterionen S2C—C(NR2)2 / Synthesis and Characterization of the Zwitter Ion S2C —C(NMe2)2; a Transition Metal Induced C —C Coupling. Complex Chemistry of the Zwitter Ions S2C —C(NR2)2

1987 ◽  
Vol 42 (11) ◽  
pp. 1411-1418 ◽  
Author(s):  
Manfred L. Ziegler ◽  
Hannelore Weber ◽  
Bernhard Nuber ◽  
Orhan Serhadle
Keyword(s):  
Transition Metal ◽  
Synthesis And Characterization ◽  
X Ray ◽  
Zwitter Ion ◽  
Complex Chemistry ◽  
New Compounds

A transition metal induced C-C coupling by the reaction of W2(N(CH3)2)6, (4) and CS2 yielded the zwitter ion S2C-C(N(CH3)2)2 (1d) besides W2(N(CH3)2)2(CS2)2S4 (5). The com- plex chemistry of the zwitter ions 1d and S2CC(N(CH2)4X)2 (X = CH2, O) has been investigated by their reaction with (η5-C5H5)2Mo2(CO)4 (2) and (η5-C5H5)Mo(CO)3Cl (3). Reaction of the former led to complexes (η5-C5H5)Mo(CO)2(S2CR) (R = N(CH3)2, N(CH2)4X) and the new compounds [(η5-C5H5)Mo(CO)2(S2C-CR2)]+. X-ray structure analyses of 1d and ((η5-C5H5)Mo(CO)2(S2C-C(N(CH2)5)2)]⊕PF6⊖ (10b) are described.

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