Highly stable cage-like complexes by self-assembly of tetracationic Zn(II) porphyrinates and tetrasulfonatocalix[4]arenes in polar solvents

2000 ◽  
pp. 2313-2314 ◽  
Author(s):  
Roberto Fiammengo ◽  
Peter Timmerman ◽  
Feike de Jong ◽  
David N. Reinhoudt
Keyword(s):  
Self Assembly ◽  
Polar Solvents

Speeding up the self-assembly of a DNA nanodevice using a variety of polar solvents

Nanoscale ◽  
2014 ◽  
Vol 6 (23) ◽  
pp. 14153-14157 ◽  
Author(s):  
Di kang ◽  
Ruixue Duan ◽  
Yerpeng Tan ◽  
Fan Hong ◽  
Boya Wang ◽  
...  
Keyword(s):  
Self Assembly ◽  
The Self ◽  
Polar Solvents ◽  
Specific Recognition

The specific recognition and programmable assembly properties make DNA a potential material for nanodevices.

scholarly journals Addition to “Molecular Origin and Self-Assembly of Fluorescent Carbon Nanodots in Polar Solvents”

2017 ◽  
Vol 8 (23) ◽  
pp. 5861-5864 ◽  
Author(s):  
Arjun Sharma ◽  
Trilochan Gadly ◽  
Suman Neogy ◽  
Sunil Kumar Ghosh ◽  
Manoj Kumbhakar
Keyword(s):  
Self Assembly ◽  
Carbon Nanodots ◽  
Polar Solvents ◽  
Molecular Origin ◽  
Fluorescent Carbon Nanodots ◽  
Fluorescent Carbon

Guest Encapsulation and Self-Assembly of Molecular Capsules in Polar Solvents via Multiple Ionic Interactions

2002 ◽  
Vol 124 (23) ◽  
pp. 6569-6575 ◽  
Author(s):  
Francesca Corbellini ◽  
Roberto Fiammengo ◽  
Peter Timmerman ◽  
Mercedes Crego-Calama ◽  
Kees Versluis ◽  
...  
Keyword(s):  
Self Assembly ◽  
Ionic Interactions ◽  
Polar Solvents ◽  
Molecular Capsules

scholarly journals Industrially-relevant polymerization-induced self-assembly formulations in non-polar solvents: RAFT dispersion polymerization of benzyl methacrylate

2015 ◽  
Vol 6 (16) ◽  
pp. 3054-3062 ◽  
Author(s):  
Matthew J. Derry ◽  
Lee A. Fielding ◽  
Steven P. Armes
Keyword(s):  
Diblock Copolymer ◽  
Self Assembly ◽  
Dispersion Polymerization ◽  
Mineral Oil ◽  
Polar Solvents ◽  
One Pot

Diblock copolymer spheres, worms and vesicles are prepared via RAFT dispersion polymerization of benzyl methacrylate in either mineral oil or a poly(α-olefin) using polymerization-induced self-assembly; an efficient ‘one-pot’ protocol is reported for spheres at 30% solids in mineral oil.

Alcohol-based PISA in batch and flow: exploring the role of photoinitiators

2019 ◽  
Vol 10 (19) ◽  
pp. 2406-2414 ◽  
Author(s):  
Neomy Zaquen ◽  
Wan A. A. W. Azizi ◽  
Jonathan Yeow ◽  
Rhiannon P. Kuchel ◽  
Tanja Junkers ◽  
...  
Keyword(s):  
Self Assembly ◽  
Continuous Flow ◽  
Polar Solvents ◽  
Flow Reactors ◽  
Reversible Addition ◽  
Radical Transfer ◽  
Continuous Flow Reactors

Polymerization-induced self-assembly (PISA) via PhotoRAFT (photoinduced reversible addition–fragmentation radical transfer) was investigated in polar solvents via continuous flow reactors.

scholarly journals Self-assembly of tholins in environments simulating Titan liquidospheres: implications for formation of primitive coacervates on Titan

2013 ◽  
Vol 12 (4) ◽  
pp. 282-291 ◽  
Author(s):  
Jun Kawai ◽  
Seema Jagota ◽  
Takeo Kaneko ◽  
Yumiko Obayashi ◽  
Yoshitaka Yoshimura ◽  
...  
Keyword(s):  
Organic Compounds ◽  
Self Assembly ◽  
Aqueous Ammonia ◽  
Aqueous Environment ◽  
Plasma Discharges ◽  
Atmospheric Gases ◽  
Polar Solvents ◽  
Average Temperature ◽  
Magnetosphere Of Saturn ◽  
Complex Organic

AbstractTitan, the largest satellite of Saturn, has a thick atmosphere containing nitrogen and methane. A variety of organic compounds have been detected in the atmosphere, most likely produced when atmospheric gases are exposed to ultraviolet light, electrons captured by the magnetosphere of Saturn and cosmic rays. The Cassini/Huygens probe showed that the average temperature on the surface of Titan is 93.7 K, with lakes of liquid ethane and methane. Sub-surface mixtures of liquid ammonia and water may also be present. We have synthesized complex organic compounds (tholins) by exposing a mixture of nitrogen and methane to plasma discharges, and investigated their interactions with several different liquids that simulate Titan's liquidosphere. We found that coacervates formed when tholins were extracted in non-polar solvents followed by exposure to aqueous ammonia solutions. The results suggest that coacervates can self-assemble in Titan's liquidosphere which have the potential to undergo further chemical evolution. Similar processes are likely to occur in the early evolution of habitable planets when tholin-like compounds undergo phase separation into microscopic structures dispersed in a suitable aqueous environment.

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