Narcissistic self-sorting of hydrogen-bonded dimeric capsules formed through self-assembly of flexible tripodal receptors in polar solvents

2012 ◽  
Vol 48 (59) ◽  
pp. 7392 ◽  
Author(s):  
Ashutosh S. Singh ◽  
Shih-Sheng Sun
2017 ◽  
Vol 15 (40) ◽  
pp. 8513-8517 ◽  
Author(s):  
M. Grajda ◽  
M. J. Lewińska ◽  
A. Szumna

Complexation of a hydrophobic guest induces the self-assembly of peptide based cavitands to form hydrogen-bonded ordered capsules in polar solvents.


2021 ◽  
pp. 100519
Author(s):  
Ying He ◽  
Yanbin Zhang ◽  
Mengjia Liu ◽  
Kai Zhao ◽  
Chuan Shan ◽  
...  

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Jichuan Zhang ◽  
Yongan Feng ◽  
Richard J. Staples ◽  
Jiaheng Zhang ◽  
Jean’ne M. Shreeve

AbstractOwing to its simple preparation and high oxygen content, nitroformate [−C(NO2)3, NF] is an extremely attractive oxidant component for propellants and explosives. However, the poor thermostability of NF-based derivatives has been an unconquerable barrier for more than 150 years, thus hindering its application. In this study, the first example of a nitrogen-rich hydrogen-bonded organic framework (HOF-NF) is designed and constructed through self-assembly in energetic materials, in which NF anions are trapped in pores of the resulting framework via the dual force of ionic and hydrogen bonds from the strengthened framework. These factors lead to the decomposition temperature of the resulting HOF-NF moiety being 200 °C, which exceeds the challenge of thermal stability over 180 °C for the first time among NF-based compounds. A large number of NF-based compounds with high stabilities and excellent properties can be designed and synthesized on the basis of this work.


1960 ◽  
Vol 38 (1) ◽  
pp. 125-130 ◽  
Author(s):  
James B. Hyne

The results of an n.m.r. study of the diastereoisomeric ephedrine and ψ-ephedrine molecules in non-polar solvents are interpreted and discussed in terms of the relative stabilities of the intramolecularly hydrogen-bonded conformers.


2006 ◽  
Vol 12 (36) ◽  
pp. 9161-9175 ◽  
Author(s):  
Josep Puigmartí-Luis ◽  
Andrea Minoia ◽  
Ángel Pérez del Pino ◽  
Gregori Ujaque ◽  
Concepció Rovira ◽  
...  

2006 ◽  
pp. 538-540 ◽  
Author(s):  
Luís M. A. Perdigão ◽  
Neil R. Champness ◽  
Peter H. Beton

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