Comparison of the cross-sections and thermal rate constants for the reactions of C(3PJ) atoms with O2 and NO

2000 ◽  
Vol 2 (13) ◽  
pp. 2873-2881 ◽  
Author(s):  
Wolf D. Geppert ◽  
Denis Reignier ◽  
Thierry Stoecklin ◽  
Christian Naulin ◽  
Michel Costes ◽  
...  

The intensity of fluorescence of thallium has been measured in hydrogen-oxygen flames diluted with each of the gases, argon, helium, nitrogen and carbon dioxide and the measurements used to obtain the following values for the quenching cross section (Å 2 ) for the 7 s 2 S ½ state of thallium σ 2 H 2 = 0.03, σ 2 O 2 = 13.2 ± 1.5, σ 2 N 2 = 6.4 ± 0.2, σ 2 H 2 O = 1.75 ± 0.2, σ 2 CO = 13.6 ± 0.8, σ 2 CO 2 = 32.5 ± 1.5, σ 2 Ar ≤ 0.1, σ 2 He ≤ 0.12. These values for the cross sections have been used to re-calculate the rate constants of the reactions, Tl + H + X → H X + Tl*, where X = H, OH, Cl or Br, from the data obtained by Phillips & Sugden (1961). The re-calculated values are lower than the original ones by a factor of 2.2.


2017 ◽  
Vol 19 (30) ◽  
pp. 20172-20187 ◽  
Author(s):  
P. Sundaram ◽  
V. Manivannan ◽  
R. Padmanaban

Initial state-selected and energy resolved channel-specific reaction probabilities, integral cross sections and thermal rate constants of the H(2S) + CH+(X1Σ+) reaction are calculated within the coupled states approximation by a time-dependent wave packet propagation method. The resonances formed during the course of the reaction are also identified.


1978 ◽  
Vol 56 (3) ◽  
pp. 387-391 ◽  
Author(s):  
S. J. Arnold ◽  
G. H. Kimbell

A discharge flow tube technique has been used to measure the deactivation of HF(ν = 1,2). Effective vibrational deactivation rate constants for HF(ν = 1,2) relaxed by C2H4, C2H3F, 1,1-C2H2F2, cis-1,2-C2H2F2, trans-1,2-C2H2F, C2HF3, and C2F4 have been determined. For HF(ν = 1) the values of the rate constants range from 4.9 × 104 s−1 Torr−1 for C2H4 to 3.5 × 103 s−1 Torr−1 for C2F4 and for HF(ν = 2) from 1.3 × 105 s−1 Torr−1 to 8.8 × 103 s−1 Torr−1. The cross sections for the deactivation of HF(ν = 1) and HF(ν = 2) by C2H4 and the fluoroethylenes are observed to scale linearly with the number of hydrogen atoms.


1971 ◽  
Vol 32 (1) ◽  
pp. 7-9 ◽  
Author(s):  
J. Galin ◽  
D. Guerreau ◽  
M. Lefort ◽  
X. Tarrago

The work of multilayer glass structures for central and eccentric compression and bending are considered. The substantiation of the chosen research topic is made. The description and features of laminated glass for the structures investigated, their characteristics are presented. The analysis of the results obtained when testing for compression, compression with bending, simple bending of models of columns, beams, samples of laminated glass was made. Overview of the types and nature of destruction of the models are presented, diagrams of material operation are constructed, average values of the resistance of the cross-sections of samples are obtained, the table of destructive loads is generated. The need for development of a set of rules and guidelines for the design of glass structures, including laminated glass, for bearing elements, as well as standards for testing, rules for assessing the strength, stiffness, crack resistance and methods for determining the strength of control samples is emphasized. It is established that the strength properties of glass depend on the type of applied load and vary widely, and significantly lower than the corresponding normative values of the strength of heat-strengthened glass. The effect of the connecting polymeric material and manufacturing technology of laminated glass on the strength of the structure is also shown. The experimental values of the elastic modulus are different in different directions of the cross section and in the direction perpendicular to the glass layers are two times less than along the glass layers.


2021 ◽  
Vol 2021 (1) ◽  
Author(s):  
Roman N. Lee ◽  
Alexey A. Lyubyakin ◽  
Vyacheslav A. Stotsky

Abstract Using modern multiloop calculation methods, we derive the analytical expressions for the total cross sections of the processes e−γ →$$ {e}^{-}X\overline{X} $$ e − X X ¯ with X = μ, γ or e at arbitrary energies. For the first two processes our results are expressed via classical polylogarithms. The cross section of e−γ → e−e−e+ is represented as a one-fold integral of complete elliptic integral K and logarithms. Using our results, we calculate the threshold and high-energy asymptotics and compare them with available results.


Author(s):  
Georges Griso ◽  
Larysa Khilkova ◽  
Julia Orlik ◽  
Olena Sivak

AbstractIn this paper, we study the asymptotic behavior of an $\varepsilon $ ε -periodic 3D stable structure made of beams of circular cross-section of radius $r$ r when the periodicity parameter $\varepsilon $ ε and the ratio ${r/\varepsilon }$ r / ε simultaneously tend to 0. The analysis is performed within the frame of linear elasticity theory and it is based on the known decomposition of the beam displacements into a beam centerline displacement, a small rotation of the cross-sections and a warping (the deformation of the cross-sections). This decomposition allows to obtain Korn type inequalities. We introduce two unfolding operators, one for the homogenization of the set of beam centerlines and another for the dimension reduction of the beams. The limit homogenized problem is still a linear elastic, second order PDE.


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