scholarly journals Synthesis, characterisation, and molecular and electronic structure of CpMoCl2(R1CCR2) (R1, R2 = Ph, Et, Me): a new class of half-sandwich 17-electron molybdenum(III) organometallics

2000 ◽  
pp. 1499-1506 ◽  
Author(s):  
Erwan Le Grognec ◽  
Rinaldo Poli ◽  
Philippe Richard
Keyword(s):  
Electronic Structure ◽  
New Class ◽  
Half Sandwich ◽  
Molecular And Electronic Structure

scholarly journals A new class of pyrenyl solid-state emitters: 1-pyrenyl ynones. Synthesis via the Friedel–Crafts route, molecular and electronic structure and photophysical properties

RSC Advances ◽  
2014 ◽  
Vol 4 (60) ◽  
pp. 31594-31601 ◽  
Author(s):  
Rafał Flamholc ◽  
Damian Plażuk ◽  
Janusz Zakrzewski ◽  
Rémi Métivier ◽  
Keitaro Nakatani ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Solid State ◽  
Photophysical Properties ◽  
Trifluoroacetic Anhydride ◽  
Triflic Acid ◽  
New Class ◽  
Efficient Route ◽  
Molecular And Electronic Structure

Friedel-Crafts acylation of pyrene with alkynoic acids in the presence of trifluoroacetic anhydride and triflic acid constitutes a direct and efficient route to 1-pyrenyl ynones fluorescent in solution and in the solid state.

Synthesis, molecular and electronic structure of a stacked half-sandwich dititanium complex incorporating a cyclic π-faced bridging ligand

RSC Advances ◽  
2016 ◽  
Vol 6 (96) ◽  
pp. 94149-94159
Author(s):  
Róbert Gyepes ◽  
Jiří Pinkas ◽  
Ivana Císařová ◽  
Jiří Kubišta ◽  
Michal Horáček ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Singlet State ◽  
Bridging Ligand ◽  
Ground Singlet State ◽  
Half Sandwich ◽  
Molecular And Electronic Structure

The thermally robust ground singlet state complex [bis(η5-pentamethylcyclopentadienyltitanium)-μ-(η4:η4-1,2,4,5-tetrakis(trimethylsilyl)cyclohexa-1-4-diene-3,6-diyl)] (3) arises from thermolysis of Cp*TiMe3.

Synthesis, Molecular, and Electronic Structure of (η8-C8H8)Ln(scorpionate) Half-Sandwich Complexes: An Experimental Key to a Better Understanding of f-Element-Cyclooctatetraenyl Bonding†

2009 ◽  
Vol 48 (2) ◽  
pp. 760-772 ◽  
Author(s):  
Hanns-Dieter Amberger ◽  
Frank T. Edelmann ◽  
Jochen Gottfriedsen ◽  
Regine Herbst-Irmer ◽  
Stefan Jank ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Sandwich Complexes ◽  
Half Sandwich ◽  
Molecular And Electronic Structure

Electronic structure studies of conducting polymers by electron energy-loss spectroscopy

1996 ◽  
Vol 54 ◽  
pp. 160-161
Author(s):  
J. Fink
Keyword(s):  
Electronic Structure ◽  
Conducting Polymers ◽  
Conjugated Polymers ◽  
Electron Acceptors ◽  
Electron Donors ◽  
Light Emitting ◽  
One Dimensional ◽  
New Class ◽  
Electrical Conductivities ◽  
Electron Energy Loss

Conducting polymers comprises a new class of materials achieving electrical conductivities which rival those of the best metals. The parent compounds (conjugated polymers) are quasi-one-dimensional semiconductors. These polymers can be doped by electron acceptors or electron donors. The prototype of these materials is polyacetylene (PA). There are various other conjugated polymers such as polyparaphenylene, polyphenylenevinylene, polypoyrrole or polythiophene. The doped systems, i.e. the conducting polymers, have intersting potential technological applications such as replacement of conventional metals in electronic shielding and antistatic equipment, rechargable batteries, and flexible light emitting diodes.Although these systems have been investigated almost 20 years, the electronic structure of the doped metallic systems is not clear and even the reason for the gap in undoped semiconducting systems is under discussion.

Synthesis of uranium complexes incorporating extended azo-imine ligands: Molecular and electronic structure

2021 ◽  
pp. 100049
Author(s):  
Poulami Pattanayak ◽  
Sankar Prasad Parua ◽  
Debprasad Patra ◽  
Ashoke Prasun Chattopadhyay ◽  
Surajit Chattopadhyay
Keyword(s):  
Electronic Structure ◽  
Uranium Complexes ◽  
Imine Ligands ◽  
Molecular And Electronic Structure

scholarly journals Molecular and Electronic Structure of Dinuclear Uranium Bis-μ-Oxo Complexes with Diamond Core Structural Motifs

2014 ◽  
Vol 136 (34) ◽  
pp. 11980-11993 ◽  
Author(s):  
Anna-Corina Schmidt ◽  
Frank W. Heinemann ◽  
Wayne W. Lukens ◽  
Karsten Meyer
Keyword(s):  
Electronic Structure ◽  
Structural Motifs ◽  
Oxo Complexes ◽  
Molecular And Electronic Structure
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