Synthesis, Molecular, and Electronic Structure of (η8-C8H8)Ln(scorpionate) Half-Sandwich Complexes: An Experimental Key to a Better Understanding of f-Element-Cyclooctatetraenyl Bonding†

2009 ◽  
Vol 48 (2) ◽  
pp. 760-772 ◽  
Author(s):  
Hanns-Dieter Amberger ◽  
Frank T. Edelmann ◽  
Jochen Gottfriedsen ◽  
Regine Herbst-Irmer ◽  
Stefan Jank ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Sandwich Complexes ◽  
Half Sandwich ◽  
Molecular And Electronic Structure

Synthesis, molecular and electronic structure of a stacked half-sandwich dititanium complex incorporating a cyclic π-faced bridging ligand

RSC Advances ◽  
2016 ◽  
Vol 6 (96) ◽  
pp. 94149-94159
Author(s):  
Róbert Gyepes ◽  
Jiří Pinkas ◽  
Ivana Císařová ◽  
Jiří Kubišta ◽  
Michal Horáček ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Singlet State ◽  
Bridging Ligand ◽  
Ground Singlet State ◽  
Half Sandwich ◽  
Molecular And Electronic Structure

The thermally robust ground singlet state complex [bis(η5-pentamethylcyclopentadienyltitanium)-μ-(η4:η4-1,2,4,5-tetrakis(trimethylsilyl)cyclohexa-1-4-diene-3,6-diyl)] (3) arises from thermolysis of Cp*TiMe3.

Monomeric Fe(iii) half-sandwich complexes [Cp′FeX2] – synthesis, properties and electronic structure

2018 ◽  
Vol 47 (31) ◽  
pp. 10517-10526 ◽  
Author(s):  
Matthias Reiners ◽  
Miyuki Maekawa ◽  
Dirk Baabe ◽  
Marc-Kevin Zaretzke ◽  
Peter Schweyen ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Sandwich Complexes ◽  
Synthesis Properties ◽  
Half Sandwich

Bis(alkyl)iron(iii) half-sandwich complexes exhibit solvent dependent reactivity when treated with H2.

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