Macrocyclic ligand design. Interaction of selected transition and post-transition metal ions with a new N2O2-donor macrocycle incorporating a pyridylmethyl pendant arm

2000 ◽  
pp. 1191-1198 ◽  
Author(s):  
Ian M. Atkinson ◽  
Jy D. Chartres ◽  
Grover W. Everett ◽  
Xue-Kui Ji ◽  
Leonard F. Lindoy ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Ions ◽  
Macrocyclic Ligand ◽  
Ligand Design ◽  
Transition Metal Ions ◽  
Pendant Arm

Macrocyclic ligand design: The interaction of selected transition and post-transition metal ions with a 14-membered N2S2-donor macrocycle

2006 ◽  
Vol 9 (7) ◽  
pp. 751-754 ◽  
Author(s):  
Jy D. Chartres ◽  
Murray S. Davies ◽  
Leonard F. Lindoy ◽  
George V. Meehan ◽  
Gang Wei
Keyword(s):  
Transition Metal ◽  
Metal Ions ◽  
Macrocyclic Ligand ◽  
Ligand Design ◽  
Transition Metal Ions

Intramolecular H-bond Stabilization of a Primary Hydroxylamine in Salen-Type Metal Complexes

2021 ◽  
Author(s):  
Hardeep Singh ◽  
Alyson MacKay ◽  
Nooshin Sheibany ◽  
Fei Chen ◽  
Maëlle Mosser ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Transition Metal ◽  
Metal Ions ◽  
Metal Complexes ◽  
Intramolecular Hydrogen Bond ◽  
Ligand Design ◽  
Transition Metal Ions ◽  
Intramolecular Hydrogen

Primary hydroxylamines, RNHOH, decompose readily in the presence of transition metal ions. We show that this reactivity can be arrested by ligand design via an intramolecular hydrogen bond. Six metal...

HREM Study of electron-induced surface radiation damage in ReO3

1991 ◽  
Vol 49 ◽  
pp. 636-637
Author(s):  
R. Ai ◽  
H.-J. Fan ◽  
L. D. Marks
Keyword(s):  
Transition Metal ◽  
Metal Ions ◽  
Metal Oxides ◽  
Electron Irradiation ◽  
Transition Metal Oxides ◽  
Carbon Film ◽  
Transition Metal Ions ◽  
Surface Radiation ◽  
Valence Transition ◽  
Electron Microscopes

It has been known for a long time that electron irradiation induces damage in maximal valence transition metal oxides such as TiO2, V2O5, and WO3, of which transition metal ions have an empty d-shell. This type of damage is excited by electronic transition and can be explained by the Knoteck-Feibelman mechanism (K-F mechanism). Although the K-F mechanism predicts that no damage should occur in transition metal oxides of which the transition metal ions have a partially filled d-shell, namely submaximal valence transition metal oxides, our recent study on ReO3 shows that submaximal valence transition metal oxides undergo damage during electron irradiation.ReO3 has a nearly cubic structure and contains a single unit in its cell: a = 3.73 Å, and α = 89°34'. TEM specimens were prepared by depositing dry powders onto a holey carbon film supported on a copper grid. Specimens were examined in Hitachi H-9000 and UHV H-9000 electron microscopes both operated at 300 keV accelerating voltage. The electron beam flux was maintained at about 10 A/cm2 during the observation.

Synthesis, Spectral and Antimicrobial Investigation of 2-(Naphthalenel-ylamino)-2- Phenylacetonitrile and 1, 10-Phenanthroline with Five Divalent Transition Metal Ions

2019 ◽  
Vol 10 (01) ◽  
Author(s):  
Mohammed Al-Amery1 ◽  
Ashraf Saad Rasheed ◽  
Dina A. Najeeb
Keyword(s):  
Transition Metal ◽  
Metal Ions ◽  
Transition Metal Ions ◽  
Molar Conductance ◽  
Octahedral Geometry ◽  
Mixed Ligand ◽  
Gram Negative Bacteria ◽  
Magnetic Studies ◽  
Gram Positive Bacteria

Five new mixed ligand metal complexes have been synthesized by the reaction of divalent transition metal ions (Hg, Ni, Zn, Cu and Cd) with 2-(naphthalen-l-ylamino)-2-phenylacetonitrile (L1 ) and 1,10-phenanthroline (L2). The coordination likelihood of the two ligands toward metal ions has been suggested in the light of elemental analysis, UV-Vis spectra, FTIR, 1H-NMR, flam atomic absorption, molar conductance and magnetic studies. Results data suggest that the octahedral geometry for all the prepared complexes. Antibacterial examination of synthesized complexes in vitro was performed against four bacterias. Firstly, Gram-negative bacteria namely, Pseudomonas aerugin and Escherichia. Secondly, Gram-positive bacteria namely, Bacillus subtilis, Staphylococcuaurouss. Results data exhibit that the synthesized complexes exhibited more biological activity than tetracycline pharmaceutical.

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