Crystal engineering of 2-D hydrogen bonded molecular networks based on the self-assembly of anionic and cationic modules

2000 ◽  
pp. 281-282 ◽  
Author(s):  
Olivier Félix ◽  
Mir Wais Hosseini ◽  
André De Cian ◽  
Jean Fischer
2006 ◽  
Vol 12 (36) ◽  
pp. 9161-9175 ◽  
Author(s):  
Josep Puigmartí-Luis ◽  
Andrea Minoia ◽  
Ángel Pérez del Pino ◽  
Gregori Ujaque ◽  
Concepció Rovira ◽  
...  

2018 ◽  
Vol 6 (15) ◽  
pp. 3968-3975 ◽  
Author(s):  
Paula Gómez ◽  
Stamatis Georgakopoulos ◽  
José Pedro Cerón ◽  
Iván da Silva ◽  
Miriam Más-Montoya ◽  
...  

Molecular design for the self-assembly of molecular materials.


2016 ◽  
Vol 18 (35) ◽  
pp. 24219-24227 ◽  
Author(s):  
Doan Chau Yen Nguyen ◽  
Lars Smykalla ◽  
Thi Ngoc Ha Nguyen ◽  
Michael Mehring ◽  
Michael Hietschold

Hydrogen-bonded supramolecular structures of BTP at the undecanol–graphite interface were studied by STM in dependence on the deposition temperature.


2016 ◽  
Vol 28 (3) ◽  
pp. 951-961 ◽  
Author(s):  
Chaoying Fu ◽  
Hua-ping Lin ◽  
Jennifer M. Macleod ◽  
Andrey Krayev ◽  
Federico Rosei ◽  
...  

Author(s):  
Kostiantyn V. Domasevitch ◽  
Vira V. Ponomarova

In the structures of the title salts, poly[[μ4-4-(3,5-dinitropyrazol-4-yl)-3,5-dinitropyrazol-1-ido]rubidium], [Rb(C6HN8O8)] n , (1), and its isostructural caesium analogue [Cs(C6HN8O8) n , (2), two independent cations M1 and M2 (M = Rb, Cs) are situated on a crystallographic twofold axis and on a center of inversion, respectively. Mutual intermolecular hydrogen bonding between the conjugate 3,5-dinitopyrazole NH-donor and 3,5-dinitropyrazole N-acceptor sites of the anions [N...N = 2.785 (2) Å for (1) and 2.832 (3) Å for (2)] governs the self-assembly of the translation-related anions in a predictable fashion. Such one-component modular construction of the organic subtopology supports the utility of the crystal-engineering approach towards designing the structures of polynitro energetic materials. The anionic chains are further linked by multiple ion–dipole interactions involving the 12-coordinate cations bonded to two pyrazole N-atoms [Rb—N = 3.1285 (16), 3.2261 (16) Å; Cs—N = 3.369 (2), 3.401 (2) Å] and all of the eight nitro O-atoms [Rb—O = 2.8543 (15)–3.6985 (16) Å; Cs—O = 3.071 (2)–3.811 (2) Å]. The resulting ionic networks follow the CsCl topological archetype, with either metal or organic ions residing in an environment of eight counter-ions. Weak lone pair–π-hole interactions [pyrazole-N atoms to NO2 groups; N...N = 2.990 (3)–3.198 (3) Å] are also relevant to the packing. The Hirshfeld surfaces and percentage two-dimensional fingerprint plots for (1) and (2) are described.


1999 ◽  
pp. 719-720 ◽  
Author(s):  
Tyler B. Norsten ◽  
Robert McDonald ◽  
Neil R. Branda

2017 ◽  
Vol 19 (29) ◽  
pp. 19205-19216 ◽  
Author(s):  
Yi Hu ◽  
Kai Miao ◽  
Li Xu ◽  
Bao Zha ◽  
Mengying Long ◽  
...  

We explored the chain length effect on inducing the self-assembly of diverse structures by tiny modification of the alkyl chains.


2012 ◽  
Vol 77 (18) ◽  
pp. 7858-7865 ◽  
Author(s):  
Alankriti Bajpai ◽  
Palani Natarajan ◽  
Paloth Venugopalan ◽  
Jarugu Narasimha Moorthy

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