Thermodynamics of mixtures with strongly negative deviations from Raoult's law Part 2. Application of the DISQUAC model to mixtures of CHCl3 or CH2Cl2 with oxaalkanes. Comparison with Dortmund UNIFAC results

1999 ◽  
Vol 1 (2) ◽  
pp. 275-283 ◽  
Author(s):  
Juan Antonio González ◽  
Isías García de la Fuente ◽  
Jose´ Carlos Cobos
Keyword(s):  
Raoult’S Law ◽  
Disquac Model ◽  
Thermodynamics Of Mixtures ◽  
Raoult's Law

scholarly journals Statistical thermodynamics of mixtures with zero energies of mixing

1944 ◽  
Vol 183 (993) ◽  
pp. 203-212 ◽  
Keyword(s):  
Thermodynamic Properties ◽  
General Formula ◽  
Statistical Thermodynamics ◽  
Raoult’S Law ◽  
Geometric Properties ◽  
Different Types ◽  
Thermodynamics Of Mixtures ◽  
Raoult's Law

A general formula has been obtained for the number of distinct arrangements of a mixture of any number of different types of molecules each with its own geometric properties. From this are deduced the thermodynamic properties of such mixtures when the energies of mixing are zero. In particular, the generalization of Raoult’s law has been obtained. The technique used is considerably simpler than that previously applied to problems of this type.

Thermodynamics of mixtures with strongly negative deviations from Raoult’s law

2001 ◽  
Vol 190 (1-2) ◽  
pp. 113-125 ◽  
Author(s):  
S Villa ◽  
N Riesco ◽  
I Garcı́a de la Fuente ◽  
J.A González ◽  
J.C Cobos
Keyword(s):  
Raoult’S Law ◽  
Thermodynamics Of Mixtures ◽  
Raoult's Law
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