Thermodynamics of mixtures with strongly negative deviation from Raoult's law Part 1Application of the DISQUAC model to mixtures of alkan-1-ols and propanal or linear alkanones and trichloromethane

1997 ◽  
Vol 93 (21) ◽  
pp. 3773-3780 ◽  
Author(s):  
Juan Antonio Gonzalez ◽  
Isaias Garcia de la Fuente ◽  
and Jose Carlos Cobos

A general formula has been obtained for the number of distinct arrangements of a mixture of any number of different types of molecules each with its own geometric properties. From this are deduced the thermodynamic properties of such mixtures when the energies of mixing are zero. In particular, the generalization of Raoult’s law has been obtained. The technique used is considerably simpler than that previously applied to problems of this type.


2001 ◽  
Vol 190 (1-2) ◽  
pp. 113-125 ◽  
Author(s):  
S Villa ◽  
N Riesco ◽  
I Garcı́a de la Fuente ◽  
J.A González ◽  
J.C Cobos

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