The equilibrium between the oxidation of hydrogen peroxide by oxygen and the dismutation of peroxyl or superoxide radicals in aqueous solutions in contact with oxygen

1998 ◽  
Vol 94 (18) ◽  
pp. 2763-2767 ◽  
Author(s):  
Jerzy Petlicki ◽  
Theo G. M. van de Ven
Keyword(s):  
Hydrogen Peroxide ◽  
Aqueous Solutions ◽  
Superoxide Radicals ◽  
Oxidation Of Hydrogen

Oxidation of hydrogen peroxide at the dropping mercury electrode

1984 ◽  
Vol 49 (10) ◽  
pp. 2320-2331 ◽  
Author(s):  
Miroslav Březina ◽  
Martin Wedell
Keyword(s):  
Hydrogen Peroxide ◽  
Superoxide Anion ◽  
Ph Value ◽  
Mercury Electrode ◽  
Electrode Process ◽  
Electrochemical Processes ◽  
Dropping Mercury Electrode ◽  
Oxidation Of Hydrogen ◽  
Decreasing Ph ◽  
Rate Controlling Step

Reduction of oxygen and oxidation of hydrogen peroxide at the dropping mercury electrode are electrochemical processes strongly influenced both by the pH value and the anions in solution. With decreasing pH, both processes become irreversible, especially in the presence of anions with a negative φ2 potential of the diffusion part of the double layer. In the case of irreversible oxygen reduction, the concept that the rate-controlling step of the electrode process is the acceptance of the first electron with the formation of the superoxide anion, O2-, was substantiated. Oxidation of hydrogen peroxide becomes irreversible at a lower pH value than the reduction of oxygen. The slowest, i.e. rate-controlling step of the electrode process in borate buffers at pH 9-10 is the transfer of the second electron, i.e. oxidation of superoxide to oxygen.

Radiation-induced oxidation of 2-propanol by hydrogen peroxide in aqueous solutions

1970 ◽  
Vol 48 (18) ◽  
pp. 2948-2948
Author(s):  
C. E. Burchill ◽  
I. S. Ginns
Keyword(s):  
Hydrogen Peroxide ◽  
Aqueous Solutions ◽  
Radiation Induced

not available

Oxidation-reduction chemistry of hydrogen peroxide in aprotic and aqueous solutions

1979 ◽  
Vol 18 (7) ◽  
pp. 1971-1973 ◽  
Author(s):  
Mark M. Morrison ◽  
Julian L Roberts ◽  
Donald T. Sawyer
Keyword(s):  
Hydrogen Peroxide ◽  
Aqueous Solutions ◽  
Oxidation Reduction

Hydrogen Peroxide Yields in X-Irradiated Aqueous Solutions A Sensitive Method Based on Hydrazide Chemiluminescence

1955 ◽  
Vol 3 (4) ◽  
pp. 379 ◽  
Author(s):  
W. V. Mayneord ◽  
W. Anderson ◽  
H. D. Evans ◽  
D. Rosen
Keyword(s):  
Hydrogen Peroxide ◽  
Aqueous Solutions ◽  
Sensitive Method

Study on the Electrochemical Behavior of Ferric Stearate and its Electro-Catalytic Oxidation of Hydrogen Peroxide

2009 ◽  
Vol 610-613 ◽  
pp. 161-164
Author(s):  
Li Li Liang ◽  
Xue Gang Luo ◽  
Xiao Yan Lin
Keyword(s):  
Hydrogen Peroxide ◽  
Cyclic Voltammetry ◽  
Catalytic Oxidation ◽  
Tin Oxide ◽  
Electrochemical Behavior ◽  
Doctor Blade ◽  
Conductive Glass ◽  
Oxidation Of Hydrogen ◽  
Electro Catalytic Oxidation ◽  
Catalytic Effects

A ferric stearate electrode was made by doctor-blade methods using the Fluorine tin oxide (FTO) conductive glass. The electrochemical behavior of ferric stearate electrode was studied by the cyclic voltammetry. The electro-catalytic effects of ferric stearate on H2O2 were also investigated by cyclic voltammetry.

Gamma radiolysis of alachlor aqueous solutions in the presence of hydrogen peroxide

2010 ◽  
Vol 184 (1-3) ◽  
pp. 308-312 ◽  
Author(s):  
Dongkyu Choi ◽  
O-Mi Lee ◽  
Seungho Yu ◽  
Seung-Woo Jeong
Keyword(s):  
Hydrogen Peroxide ◽  
Aqueous Solutions ◽  
Gamma Radiolysis
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