scholarly journals Catalytic and asymmetric aziridination of alkenes catalysed by a chiral manganese porphyrin complex

1997 ◽  
pp. 2373-2374 ◽  
Author(s):  
Tat-Shing Lai ◽  
Chi-Ming Che ◽  
Hoi-Lun Kwong ◽  
Shie-Ming Peng
Keyword(s):  
Manganese Porphyrin ◽  
Porphyrin Complex ◽  
Asymmetric Aziridination

Potassium monopersulfate and a water-soluble manganese porphyrin complex, [Mn(TMPyP)](OAc)5, as an efficient reagent for the oxidative cleavage of DNA

Biochemistry ◽  
1989 ◽  
Vol 28 (18) ◽  
pp. 7268-7275 ◽  
Author(s):  
Jean Bernadou ◽  
Genevieve Pratviel ◽  
Faiza Bennis ◽  
Marc Girardet ◽  
Bernard Meunier
Keyword(s):  
Oxidative Cleavage ◽  
Water Soluble ◽  
Manganese Porphyrin ◽  
Porphyrin Complex ◽  
Efficient Reagent

scholarly journals A Manganese–Porphyrin Complex Decomposes H2O2, Inhibits Apoptosis, and Acts as a Radiation Mitigator in Vivo

2011 ◽  
Vol 2 (11) ◽  
pp. 814-817 ◽  
Author(s):  
Detcho A. Stoyanovsky ◽  
Zhentai Huang ◽  
Jianfei Jiang ◽  
Natalia A. Belikova ◽  
Vladimir Tyurin ◽  
...  
Keyword(s):  
Manganese Porphyrin ◽  
Porphyrin Complex

scholarly journals Aerobic Epoxidation of Low-Molecular-Weight and Polymeric Olefins by a Supramolecular Manganese Porphyrin Catalyst

Catalysts ◽  
2019 ◽  
Vol 9 (2) ◽  
pp. 195 ◽  
Author(s):  
Ivan Bernar ◽  
Floris Rutjes ◽  
Johannes Elemans ◽  
Roeland Nolte
Keyword(s):  
Molecular Weight ◽  
Ambient Temperature ◽  
High Activity ◽  
Molecular Oxygen ◽  
Low Molecular Weight ◽  
Mechanistic Studies ◽  
Manganese Porphyrin ◽  
Reaction Conditions ◽  
Porphyrin Complex ◽  
Epoxidation Reaction

We report on the highly efficient epoxidation of low-molecular-weight and polymeric olefins catalyzed by a supramolecular manganese porphyrin complex using molecular oxygen as an oxidant and an aldehyde as a co-reductant. At ambient temperature and under optimized reaction conditions, the catalyst showed high activity and stereoselectivity. The efficiency of the supramolecular manganese porphyrin was higher than that of a reference porphyrin catalyst, possibly because it was more stable under the applied reaction conditions. Mechanistic studies suggest that a manganese oxo porphyrin complex may be an intermediate in the epoxidation reaction.

scholarly journals Enantioselective oxygenation of exocyclic methylene groups by a manganese porphyrin catalyst with a chiral recognition site

2020 ◽  
Vol 11 (8) ◽  
pp. 2121-2129 ◽  
Author(s):  
Finn Burg ◽  
Stefan Breitenlechner ◽  
Christian Jandl ◽  
Thorsten Bach
Keyword(s):  
Hydrogen Bonding ◽  
Chiral Recognition ◽  
Recognition Site ◽  
Manganese Porphyrin ◽  
Porphyrin Complex ◽  
Site Selectivity ◽  
Methylene Groups ◽  
Exocyclic Methylene

A Mn porphyrin complex with a remote hydrogen bonding motif induces a high enantioselectivity in the oxygenation of 3-alkylquinolones. Compared to an achiral Mn complex, the site-selectivity was completely altered in favour of less reactive methylene groups.

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