Potassium monopersulfate and a water-soluble manganese porphyrin complex, [Mn(TMPyP)](OAc)5, as an efficient reagent for the oxidative cleavage of DNA

Biochemistry ◽  
1989 ◽  
Vol 28 (18) ◽  
pp. 7268-7275 ◽  
Author(s):  
Jean Bernadou ◽  
Genevieve Pratviel ◽  
Faiza Bennis ◽  
Marc Girardet ◽  
Bernard Meunier
Keyword(s):  
Oxidative Cleavage ◽  
Water Soluble ◽  
Manganese Porphyrin ◽  
Porphyrin Complex ◽  
Efficient Reagent

scholarly journals Oxidative cleavage of alkenes catalyzed by a water/organic soluble manganese porphyrin complex

Tetrahedron ◽  
2007 ◽  
Vol 63 (8) ◽  
pp. 1821-1825 ◽  
Author(s):  
Shiuh-Tzung Liu ◽  
K. Venugopal Reddy ◽  
Rung-Yi Lai
Keyword(s):  
Oxidative Cleavage ◽  
Manganese Porphyrin ◽  
Porphyrin Complex

scholarly journals Oxidative Cleavage of Alkenes Catalyzed by a Water/Organic Soluble Manganese Porphyrin Complex.

ChemInform ◽  
2007 ◽  
Vol 38 (23) ◽  
Author(s):  
Shiuh-Tzung Liu ◽  
K. Venugopal Reddy ◽  
Rung-Yi Lai
Keyword(s):  
Oxidative Cleavage ◽  
Manganese Porphyrin ◽  
Porphyrin Complex

Chlorite Dismutation to Chlorine Dioxide Catalyzed by a Water-Soluble Manganese Porphyrin

2010 ◽  
Vol 50 (3) ◽  
pp. 699-702 ◽  
Author(s):  
Scott D. Hicks ◽  
Jennifer L. Petersen ◽  
Curt J. Bougher ◽  
Mahdi M. Abu-Omar
Keyword(s):  
Chlorine Dioxide ◽  
Water Soluble ◽  
Manganese Porphyrin

Kinetic and Mechanistic Studies on the Reaction of Nitric Oxide with a Water-Soluble Octa-anionic Iron(III) Porphyrin Complex

2005 ◽  
Vol 44 (22) ◽  
pp. 7717-7731 ◽  
Author(s):  
Joo-Eun Jee ◽  
Siegfried Eigler ◽  
Frank Hampel ◽  
Norbert Jux ◽  
Maria Wolak ◽  
...  
Keyword(s):  
Nitric Oxide ◽  
Water Soluble ◽  
Mechanistic Studies ◽  
Porphyrin Complex

Mechanistic study of a manganese porphyrin catalyst for on-demand production of chlorine dioxide in water

2015 ◽  
Vol 19 (01-03) ◽  
pp. 492-499 ◽  
Author(s):  
Scott D. Hicks ◽  
Silei Xiong ◽  
Curt J. Bougher ◽  
Grigori A. Medvedev ◽  
James Caruthers ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Chlorine Dioxide ◽  
Transfer Reaction ◽  
Water Soluble ◽  
Reaction Pathways ◽  
Mechanistic Study ◽  
Manganese Porphyrin ◽  
Oxygen Atom Transfer ◽  
On Demand ◽  
Proton Coupled Electron Transfer

A water-soluble manganese porphyrin complex was examined for the catalytic formation of chlorine dioxide from chlorite under ambient temperature at pH 5.00 and 6.90. Quantitative kinetic modeling allowed for the deduction of a mechanism that accounts for all experimental observations. Catalysis is initiated via an OAT (Oxygen Atom Transfer) reaction resulting in formation of a putative manganese(V) oxo species, which undergoes ET (Electron Transfer) with chlorite to form chlorine dioxide. As chlorine dioxide accumulates in solution, chlorite consumption slows down and ClO 2 reaches a maximum as the system reaches equilibrium. In phosphate buffer at pH 6.90, manganese(IV) oxo accumulates and its reaction with ClO 2 gives ClO 3-. However, at pH 5.00 acetate buffer proton coupled electron transfer (PCET) from chlorite to manganese(IV) oxo is fast and irreversible leading to chlorate formation only via the putative manganese(V) oxo species. These differences underscore how PCET rates affect reaction pathways and mechanism. The ClO 2 product can be collected from the aqueous reaction mixture via purging with an inert gas, allowing for the preparation of chlorine dioxide on-demand.

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