Practical and convenient synthesis of coumarins from phenols and propiolic acid esters

2007 ◽  
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pp. 845-848 ◽  
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Juzo Oyamada ◽  
Toshiki Tsubota
1985 ◽  
Vol 16 (1) ◽  
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Xiufang Ji ◽  
Zhiming Li ◽  
Quanrui Wang ◽  
Andreas Goeke

The fused 2-vinyl or 2-phenyl substituted cyclobutanones 4 undergo stereoselective ring openings by the action of alkoxide ions (t-BuO− or MeO−) to produce novel vicinally disubstituted cycloalkene derivatives 5 and 6 in moderate to high yields. The ring cleavage usually occurs with complete regioselectivity. The accessibility of γ,δ-unsaturated ester or acid derivatives makes this transformation a good supplementary method for the well-established Johnson–Claisen rearrangement.


1991 ◽  
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pp. 301-305 ◽  
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Stephen Spinella ◽  
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PAULO BRUNO NORBERTO DA SILVA ◽  
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