ChemInform Abstract: A Convenient Synthesis of Fluorobenzoic Acid Esters via Direct Halogen Exchange.

ChemInform ◽  
2010 ◽  
Vol 23 (13) ◽  
pp. no-no
Author(s):  
Y. YOSHIDA ◽  
O. FURUSAWA ◽  
Y. KIMURA
1991 ◽  
Vol 53 (2) ◽  
pp. 301-305 ◽  
Author(s):  
Yasuo Yoshida ◽  
Osamu Furusawa ◽  
Yoshikazu Kimura

2012 ◽  
Vol 8 ◽  
pp. 650-657 ◽  
Author(s):  
Xiufang Ji ◽  
Zhiming Li ◽  
Quanrui Wang ◽  
Andreas Goeke

The fused 2-vinyl or 2-phenyl substituted cyclobutanones 4 undergo stereoselective ring openings by the action of alkoxide ions (t-BuO− or MeO−) to produce novel vicinally disubstituted cycloalkene derivatives 5 and 6 in moderate to high yields. The ring cleavage usually occurs with complete regioselectivity. The accessibility of γ,δ-unsaturated ester or acid derivatives makes this transformation a good supplementary method for the well-established Johnson–Claisen rearrangement.


ChemInform ◽  
2010 ◽  
Vol 27 (25) ◽  
pp. no-no
Author(s):  
W. DUCZEK ◽  
J. DEUTSCH ◽  
S. VIETH ◽  
H.-J. NICLAS

ChemInform ◽  
2008 ◽  
Vol 39 (47) ◽  
Author(s):  
Jian Chen ◽  
Qiang Liu ◽  
Weicheng Zhang ◽  
Stephen Spinella ◽  
Aiwen Lei ◽  
...  

2002 ◽  
Vol 57 (10) ◽  
pp. 1125-1128 ◽  
Author(s):  
Michael J. Bayer ◽  
Walter Siebert

Reaction of 3,3-dimethyl-1-butynyllithiumwith boron trichloride followed by hydroboration with HBCl2 leads to 1,1-bis(dichloroboryl)-3,3-dimethylbutene (4a). Halogen exchange with boron triiodide yields the corresponding tetraiodide 4b, which undergoes a redox reaction with 3-hexyne to give the 1,3-dihydro-1,3-diborapentafulvene 3b. Its 1,3-dimethyl derivative 3c is less stable and rearranges to nido-C4B2 carboranes as well as to polymeric products. Hydroboration of 3c with HBEt2 results in the formation of the nido-C3B3 carborane 6c. The reaction of 3c with Mo(CO)6 yields the 1,3-diborapentafulvene complex 7c.


1986 ◽  
Vol 16 (5) ◽  
pp. 499-507 ◽  
Author(s):  
Takehiro Arnano ◽  
Kensei Yoshikawa ◽  
Tatsuhiko Sano ◽  
Yutaka Ohuchi ◽  
Manzo Shiono ◽  
...  

2014 ◽  
Vol 59 (1) ◽  
pp. 2359-2362 ◽  
Author(s):  
CARLOS JONNATAN PIMENTEL BARROS ◽  
ZILYANE CARDOSO DE SOUZA ◽  
JUCLEITON JOSÉRUFINO DE FREITAS ◽  
PAULO BRUNO NORBERTO DA SILVA ◽  
GARDENIA CARMEN GADELHA MILITÃO ◽  
...  

2008 ◽  
Vol 10 (14) ◽  
pp. 3033-3036 ◽  
Author(s):  
Jian Chen ◽  
Qiang Liu ◽  
Weicheng Zhang ◽  
Stephen Spinella ◽  
Aiwen Lei ◽  
...  

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