scholarly journals High-quality bulk hybrid perovskite single crystals within minutes by inverse temperature crystallization

2015 ◽  
Vol 6 (1) ◽  
Author(s):  
Makhsud I. Saidaminov ◽  
Ahmed L. Abdelhady ◽  
Banavoth Murali ◽  
Erkki Alarousu ◽  
Victor M. Burlakov ◽  
...  
Keyword(s):  
Single Crystals ◽  
Inverse Temperature ◽  
High Quality ◽  
Hybrid Perovskite ◽  
Temperature Crystallization

Room-temperature synthesis, growth mechanisms and opto-electronic properties of organic–inorganic halide perovskite CH3NH3PbX3 (X = I, Br, and Cl) single crystals

CrystEngComm ◽  
2021 ◽  
Author(s):  
Maryam Bari ◽  
Hua Wu ◽  
Alexei A. Bokov ◽  
Rana Faryad Ali ◽  
Hamel N. Tailor ◽  
...  
Keyword(s):  
Electronic Properties ◽  
Single Crystals ◽  
Room Temperature ◽  
Solubility Curve ◽  
Inverse Temperature ◽  
Growth Mechanisms ◽  
Temperature Synthesis ◽  
Room Temperature Synthesis ◽  
Halide Perovskite ◽  
Temperature Crystallization

Growth of MAPbX3 (X = I, Br, and Cl) single crystals by room temperature crystallization (RTC) method, and the crystallization pathway illustrated by the solubility curve of MAPbCl3 in DMSO, compared with inverse temperature crystallization (ITC) method.

scholarly journals Robot-Accelerated Perovskite Investigation and Discovery (RAPID): 1. Inverse Temperature Crystallization

2019 ◽  
Author(s):  
Zhi Li ◽  
Mansoor Ani Najeeb ◽  
Liana Alves ◽  
Alyssa Sherman ◽  
Peter Cruz Parrilla ◽  
...  
Keyword(s):  
Machine Learning ◽  
Single Crystal ◽  
High Throughput ◽  
Metal Halide ◽  
Crystal Formation ◽  
Inverse Temperature ◽  
High Quality ◽  
Metal Halide Perovskite ◽  
Halide Perovskite ◽  
Temperature Crystallization

Metal halide perovskites are a promising class of materials for next-generation photovoltaic and optoelectronic devices. The discovery and full characterization of new perovskite-derived materials are limited by the difficulty of growing high quality crystals needed for single-crystal X-ray diffraction studies. We present the first automated, high-throughput approach for metal halide perovskite single crystal discovery based on inverse temperature crystallization (ITC) as a means to rapidly identify and optimize synthesis conditions for the formation of high quality single crystals. Using this automated approach, a total of 1928 metal halide perovskite synthesis reactions were conducted using six organic ammonium cations (methylammonium, ethylammonium, n-butylammonium, formamidinium, guanidinium, and acetamidinium), increasing the number of metal halide perovskite materials accessible by ITC syntheses by three and resulting in the formation of a new phase, [C<sub>2</sub>H<sub>7</sub>N<sub>2</sub>][PbI<sub>3</sub>]. This comprehensive dataset allows for a statistical quantification of the total experimental space and of the likelihood of large single crystal formation. Moreover, this dataset enables the construction and evaluation of machine learning models for predicting crystal formation conditions. This work is a proof-of-concept that combining high throughput experimentation and machine learning accelerates and enhances the study of metal halide perovskite crystallization. This approach is designed to be generalizable to different synthetic routes for the acceleration of materials discovery.

Single-Crystalline Nanosheets of Hybrid Perovskite Fabricated by a Vapor-Solution Sequential Deposition Route

2019 ◽  
Vol 19 (6) ◽  
pp. 3669-3672
Author(s):  
Boya Zhao ◽  
Jie Liu ◽  
Zhi-Hua Li ◽  
Yao-Xuan Chen ◽  
Jie Ding ◽  
...  
Keyword(s):  
Single Crystals ◽  
Single Crystal Growth ◽  
Good Reproducibility ◽  
High Quality ◽  
Inorganic Hybrid ◽  
Single Crystalline ◽  
Sequential Deposition ◽  
Promising Strategy ◽  
Hybrid Perovskite ◽  
Crystallization Conditions

Organic–inorganic hybrid perovskite single crystals have attracted much attention due to their superior optoelectronic properties. Herein, we report a facile vapor-solution sequential route to prepare single-crystalline nanosheets of hybrid lead triiodide perovskite. It is found that this two-step deposition is able to fabricate sizeable high-quality single-crystalline nanosheets with no need of delicate control of crystallization conditions such as concentration or temperature for normal single crystal growth. The resulting perovskite nanosheets show good reproducibility and single crystallinity with bright and uniform photoluminescence. Our study provides a promising strategy for scalable fabrication of perovskite single crystals with great potential in optoelectronic applications.

scholarly journals Optimization of the Growth Conditions for High Quality CH3NH3PbBr3 Hybrid Perovskite Single Crystals

2020 ◽  
Vol 20 (3) ◽  
pp. 1665-1672 ◽  
Author(s):  
Smaïl Amari ◽  
Jean-Marie Verilhac ◽  
Eric Gros D’Aillon ◽  
Alain Ibanez ◽  
Julien Zaccaro
Keyword(s):  
Single Crystals ◽  
Growth Conditions ◽  
High Quality ◽  
Hybrid Perovskite

scholarly journals Robot-Accelerated Perovskite Investigation and Discovery (RAPID): 1. Inverse Temperature Crystallization

2019 ◽  
Author(s):  
Zhi Li ◽  
Mansoor Ani Najeeb ◽  
Liana Alves ◽  
Alyssa Sherman ◽  
Peter Cruz Parrilla ◽  
...  
Keyword(s):  
Machine Learning ◽  
Single Crystal ◽  
High Throughput ◽  
Metal Halide ◽  
Crystal Formation ◽  
Inverse Temperature ◽  
High Quality ◽  
Metal Halide Perovskite ◽  
Halide Perovskite ◽  
Temperature Crystallization

Metal halide perovskites are a promising class of materials for next-generation photovoltaic and optoelectronic devices. The discovery and full characterization of new perovskite-derived materials are limited by the difficulty of growing high quality crystals needed for single-crystal X-ray diffraction studies. We present the first automated, high-throughput approach for metal halide perovskite single crystal discovery based on inverse temperature crystallization (ITC) as a means to rapidly identify and optimize synthesis conditions for the formation of high quality single crystals. Using this automated approach, a total of 1928 metal halide perovskite synthesis reactions were conducted using six organic ammonium cations (methylammonium, ethylammonium, n-butylammonium, formamidinium, guanidinium, and acetamidinium), increasing the number of metal halide perovskite materials accessible by ITC syntheses by three and resulting in the formation of a new phase, [C<sub>2</sub>H<sub>7</sub>N<sub>2</sub>][PbI<sub>3</sub>]. This comprehensive dataset allows for a statistical quantification of the total experimental space and of the likelihood of large single crystal formation. Moreover, this dataset enables the construction and evaluation of machine learning models for predicting crystal formation conditions. This work is a proof-of-concept that combining high throughput experimentation and machine learning accelerates and enhances the study of metal halide perovskite crystallization. This approach is designed to be generalizable to different synthetic routes for the acceleration of materials discovery.

scholarly journals CH3NH3PbCl3 Single Crystals: Inverse Temperature Crystallization and Visible-Blind UV-Photodetector

2015 ◽  
Vol 6 (19) ◽  
pp. 3781-3786 ◽  
Author(s):  
Giacomo Maculan ◽  
Arif D. Sheikh ◽  
Ahmed L. Abdelhady ◽  
Makhsud I. Saidaminov ◽  
Md Azimul Haque ◽  
...  
Keyword(s):  
Single Crystals ◽  
Inverse Temperature ◽  
Uv Photodetector ◽  
Visible Blind ◽  
Temperature Crystallization

scholarly journals Single crystals of mixed Br/Cl and Sn-doped formamidinium lead halide perovskites via inverse temperature crystallization

RSC Advances ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 3832-3836
Author(s):  
Michael Ng ◽  
Jonathan E. Halpert
Keyword(s):  
Single Crystals ◽  
Inverse Temperature ◽  
Halide Perovskites ◽  
Lead Halide ◽  
Temperature Crystallization

FAPbBr3−xClx and doped FAPb1−xSnxBr3 perovskite single crystals were synthesized using inverse temperature crystallization (ITC). The single crystals displayed a bandgap tuneability of 2.05 eV to 2.57 eV and trap densities between 109 to 1011 cm−3.

Defect states of organic lead halide single crystals grown by inverse-temperature crystallization

2019 ◽  
Vol 115 (15) ◽  
pp. 153302 ◽  
Author(s):  
Thi Kim Oanh Vu ◽  
Dong Uk Lee ◽  
Kyoung Su Lee ◽  
Dae Young Park ◽  
Mun Seok Jeong ◽  
...  
Keyword(s):  
Single Crystals ◽  
Inverse Temperature ◽  
Defect States ◽  
Organic Lead ◽  
Lead Halide ◽  
Temperature Crystallization

scholarly journals Growth of single crystals of methylammonium lead mixedhalide perovskites

2018 ◽  
Vol 28 (3) ◽  
pp. 237 ◽  
Author(s):  
Thuat Nguyen-Tran ◽  
Mai Ngoc An ◽  
Trang Thu Luong ◽  
Hung Huy Nguyen ◽  
Tu Thanh Truong
Keyword(s):  
Single Crystals ◽  
Growth Parameters ◽  
Optical Microscope ◽  
Inverse Temperature ◽  
X Ray Diffraction ◽  
X Ray ◽  
Bulk Single Crystals ◽  
Halide Perovskites ◽  
Temperature Crystallization

We report the growth and characterization of different bulk single crystals of organo lead mixed halide perovskites CH3NH3PbI3−xBrx by two different crystal growth approaches: (i)anti-solvent diffusion, and (ii) inverse temperature crystallization. In order to control the size and the shape of crystals, we have investigated different experimental growth parameters such as temperature and precursor concentration. The morphology of obtained crystals was observed by optical microscope, whereas their intrinsic crystalline properties were characterized by single crystal as well as powder X-ray diffraction. The results illustrated that the growth and crystalline structure of mixed halide perovskites CH3NH3PbI3−xBrx could be easily tuned.

Sign in / Sign up

Export Citation Format

Share Document