Fast, greener and scalable direct coupling of organolithium compounds with no additional solvents

Erik B. Pinxterhuis; Massimo Giannerini; Valentín Hornillos; Ben L. Feringa

doi:10.1038/ncomms11698

Fast, greener and scalable direct coupling of organolithium compounds with no additional solvents

Nature Communications ◽

10.1038/ncomms11698 ◽

2016 ◽

Vol 7 (1) ◽

Cited By ~ 28

Author(s):

Erik B. Pinxterhuis ◽

Massimo Giannerini ◽

Valentín Hornillos ◽

Ben L. Feringa

Keyword(s):

Direct Coupling ◽

Organolithium Compounds

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ChemInform Abstract: Direct Coupling of Functionalized Organolithium Compounds with Aryl and Vinyl Halides.

ChemInform ◽

10.1002/chin.199409105 ◽

2010 ◽

Vol 25 (9) ◽

pp. no-no

Author(s):

J. BARLUENGA ◽

J. M. MONTSERRAT ◽

J. FLOREZ

Keyword(s):

Direct Coupling ◽

Organolithium Compounds ◽

Vinyl Halides

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ChemInform Abstract: Direct Coupling Between β-Functionalized Organolithium Compounds and Aryl and Vinyl Halides.

ChemInform ◽

10.1002/chin.199310069 ◽

2010 ◽

Vol 24 (10) ◽

pp. no-no

Author(s):

J. BARLUENGA ◽

J. M. MONTSERRAT ◽

J. FLOREZ

Keyword(s):

Direct Coupling ◽

Organolithium Compounds ◽

Vinyl Halides

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Direct coupling between β-functionalized organolithium compounds and aryl and vinyl halides

Tetrahedron Letters ◽

10.1016/s0040-4039(00)60038-2 ◽

1992 ◽

Vol 33 (41) ◽

pp. 6183-6186 ◽

Cited By ~ 9

Author(s):

José Barluenga ◽

Javier M. Montserrat ◽

Josefa Flórez

Keyword(s):

Direct Coupling ◽

Organolithium Compounds ◽

Vinyl Halides

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Direct coupling of functionalized organolithium compounds with aryl and vinyl halides

The Journal of Organic Chemistry ◽

10.1021/jo00074a025 ◽

1993 ◽

Vol 58 (22) ◽

pp. 5976-5980 ◽

Cited By ~ 34

Author(s):

Jose Barluenga ◽

Javier M. Montserrat ◽

Josefa Florez

Keyword(s):

Direct Coupling ◽

Organolithium Compounds ◽

Vinyl Halides

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Faculty Opinions recommendation of Synchronization of neurogenesis and motor neuron specification by direct coupling of bHLH and homeodomain transcription factors.

Faculty Opinions – Post-Publication Peer Review of the Biomedical Literature ◽

10.3410/f.1003973.192887 ◽

2003 ◽

Author(s):

Andrew Lumsden

Keyword(s):

Transcription Factors ◽

Motor Neuron ◽

Direct Coupling ◽

Homeodomain Transcription Factors

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Faculty Opinions recommendation of Synchronization of neurogenesis and motor neuron specification by direct coupling of bHLH and homeodomain transcription factors.

Faculty Opinions – Post-Publication Peer Review of the Biomedical Literature ◽

10.3410/f.1003973.192829 ◽

2003 ◽

Author(s):

Judith S Eisen

Keyword(s):

Transcription Factors ◽

Motor Neuron ◽

Direct Coupling ◽

Homeodomain Transcription Factors

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Faculty Opinions recommendation of Synchronization of neurogenesis and motor neuron specification by direct coupling of bHLH and homeodomain transcription factors.

Faculty Opinions – Post-Publication Peer Review of the Biomedical Literature ◽

10.3410/f.1003973.191881 ◽

2003 ◽

Author(s):

Gordon Fishell

Keyword(s):

Transcription Factors ◽

Motor Neuron ◽

Direct Coupling ◽

Homeodomain Transcription Factors

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Functionalized Organolithium Compounds: New Synthetic Adventures

Current Organic Chemistry ◽

10.2174/1385272033486675 ◽

2003 ◽

Vol 7 (9) ◽

pp. 867-926 ◽

Cited By ~ 57

Author(s):

Carmen Najera ◽

Miguel Yus

Keyword(s):

Organolithium Compounds

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Mixed Aggregates of Organolithium Compounds

Mini-Reviews in Organic Chemistry ◽

10.2174/1570193043488863 ◽

2004 ◽

Vol 1 (2) ◽

pp. 209-217 ◽

Cited By ~ 20

Author(s):

Lawrence Pratt

Keyword(s):

Organolithium Compounds ◽

Mixed Aggregates

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Reaction of organolithium compounds with 1-substituted 2,4,6-triphenylpyridinium perchlorates

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19891880 ◽

1989 ◽

Vol 54 (7) ◽

pp. 1880-1887 ◽

Cited By ~ 3

Author(s):

Marián Schwarz ◽

Josef Kuthan

Keyword(s):

Visible Range ◽

Molecular Spectra ◽

Organolithium Compounds ◽

Phenylmagnesium Bromide

The reaction of organolithium compounds with 1-substituted 2,4,6-triphenylpyridinium perchlorates Ia-Ic produces mixtures of 1,4-dihydropyridines IIa-IIe and 1,2-dihydropyridines IIIa-IIIe. Analogous reactions of phenylmagnesium bromide with compounds Ia-Ic proceed with very low conversions (less than 1%). Photochromism in visible range is observed only with the compounds II which have two aromatic substituents at 4-position, whereas compounds III and IId show no visible photochromism. The molecular spectra of the compounds newly prepared are discussed.

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