Synthetic hosts by monomolecular imprinting inside dendrimers

Nature ◽  
2002 ◽  
Vol 418 (6896) ◽  
pp. 399-403 ◽  
Author(s):  
Steven C. Zimmerman ◽  
Michael S. Wendland ◽  
Neal A. Rakow ◽  
Ilya Zharov ◽  
Kenneth S. Suslick
Keyword(s):  
Synthetic Hosts

Challenges to large molecular encapsulation

2014 ◽  
Vol 86 (1) ◽  
pp. 3-11 ◽  
Author(s):  
Daishi Fujita
Keyword(s):  
Molecular Weight ◽  
Personal Account ◽  
Molecular Encapsulation ◽  
Large Molecules ◽  
Design And Synthesis ◽  
Molecular Cages ◽  
History Of ◽  
Synthetic Scaffold ◽  
One To One ◽  
Synthetic Hosts

Abstract One-to-one capture and confinement of a molecule within a finely designed synthetic scaffold is a highly topical field of research that aims to control the functions, properties, and stabilities of trapped molecules. In this account, a brief history of molecular encapsulation, for the design and synthesis of suitable molecular cages for large molecules, summarizes the daunting synthetic challenge associated with increasing molecular weight, and the attendant challenge to encapsulate macromolecules like proteins by synthetic hosts. Recent approaches toward the overall objective of large molecular encapsulation are discussed, and a personal account is given of the design and assembly of an advanced scaffolding system, which offers the promise of unprecedented progress toward this goal.

Design of complexes between synthetic hosts and organic guests

1978 ◽  
Vol 11 (1) ◽  
pp. 8-14 ◽  
Author(s):  
Donald J. Cram ◽  
Jane M. Cram
Keyword(s):  
Organic Guests ◽  
Synthetic Hosts

scholarly journals Catalysis inside Supramolecular Capsules: Recent Developments

Catalysts ◽  
2019 ◽  
Vol 9 (7) ◽  
pp. 630 ◽  
Author(s):  
Pappalardo ◽  
Puglisi ◽  
Trusso Sfrazzetto
Keyword(s):  
Chemical Reactions ◽  
Bulk Solution ◽  
Chemical Transformations ◽  
Reaction Products ◽  
Molecular Receptors ◽  
Wide Range ◽  
Recent Developments ◽  
Internal Volume ◽  
Synthetic Hosts

In the last decades, supramolecular chemists have developed new molecular receptors able to include a wide range of guests. In addition, they have designed synthetic hosts able to form capsules having an internal volume of thousands of Å3. This inner space shows different features from the bulk solution. In particular, this environment has recently been employed to perform chemical reactions, obtaining reaction products different from the “normal” conditions. These supramolecular capsules act as nanoreactors, catalyzing many chemical transformations. This review collects the recent developments (since 2015) in this field, focusing on supramolecular capsules based on resorcinarene hexameric capsules and metal-cage capsules.

scholarly journals Complexation of neutral molecules by synthetic hosts

1993 ◽  
Vol 65 (5) ◽  
pp. 965-969 ◽  
Author(s):  
D. N. Reinhoudt ◽  
F. C. J. M. van Veggel
Keyword(s):  
Synthetic Hosts

Synthetic Hosts for Molecular Recognition of Ureas

2011 ◽  
Vol 76 (16) ◽  
pp. 6780-6788 ◽  
Author(s):  
Dolores Santa María ◽  
M. Ángeles Farrán ◽  
M. Ángeles García ◽  
Elena Pinilla ◽  
M. Rosario Torres ◽  
...  
Keyword(s):  
Molecular Recognition ◽  
Synthetic Hosts

ChemInform Abstract: Cation-π Interaction Between Synthetic Hosts and Alkali Metal Cations.

ChemInform ◽  
2010 ◽  
Vol 28 (33) ◽  
pp. no-no
Author(s):  
K.-S. JEONG ◽  
S. H. PARK ◽  
J. H. KIM ◽  
Y. L. CHO
Keyword(s):  
Alkali Metal ◽  
Metal Cations ◽  
Alkali Metal Cations ◽  
Synthetic Hosts
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