Atmospheric wet sulphate deposition and lakewater chemistry

Nature ◽  
1988 ◽  
Vol 331 (6157) ◽  
pp. 607-609 ◽  
Author(s):  
T. J. Sullivan ◽  
J. M. Eilers ◽  
M. R. Church ◽  
D. J. Blick ◽  
K. N. Eshleman ◽  
...  
Keyword(s):  
Sulphate Deposition ◽  
Lakewater Chemistry

Modelling high-latitude explosive eruptions and their atmospheric and environmental impacts

2021 ◽  
Author(s):  
Herman Fuglestvedt ◽  
Zhihong Zhuo ◽  
Michael Sigl ◽  
Matthew Toohey ◽  
Michael Mills ◽  
...  
Keyword(s):  
Environmental Impacts ◽  
High Latitude ◽  
Radiative Forcing ◽  
General Circulation ◽  
Lower Thermosphere ◽  
Circulation Model ◽  
Ice Cores ◽  
Volcanic Eruptions ◽  
Explosive Eruptions ◽  
Sulphate Deposition

<p>Large explosive volcanic eruptions inject sulphur into the stratosphere where it is converted to sulphur dioxide and sulphate aerosols. Due to atmospheric circulation patterns, aerosols from high-latitude eruptions typically remain concentrated in the hemisphere in which they are injected. Eruptions in the high-latitude Northern Hemisphere could thus lead to a stronger hemispheric radiative forcing and surface climate response than tropical eruptions, a claim that is supported by a previous study based on proxy records and the coupled aerosol-general circulation model MAECHAM5-HAM. Additionally, the subsequent surface deposition of volcanic sulphate is potentially harmful to humans and ecosystems, and an improved understanding of the deposition over polar ice sheets can contribute to better reconstructions of historical volcanic forcing. On this basis, we model Icelandic explosive eruptions in a pre-industrial atmosphere, taking both volcanic sulphur and halogen loading into account. We use the fully coupled Earth system model CESM2 with the atmospheric component WACCM6, which extends to the lower thermosphere and has prognostic stratospheric aerosols and full chemistry. In order to study the volcanic impacts on the atmosphere, environment, and sulphate deposition, we vary eruption parameters such as sulphur and halogen loading, and injection altitude and season. The modelled volcanic sulphate deposition is compared to the deposition in ice cores following comparable historical eruptions. Furthermore, we evaluate the potential environmental impacts of sulphate deposition. To study inter-model differences, we also compare the CESM2-WACCM6 simulations to similar Icelandic eruption experiments simulated with MAECHAM5-HAM. </p>

scholarly journals Norwegian lakes show widespread recovery from acidification; results from national surveys of lakewater chemistry 1986-1997

1998 ◽  
Vol 2 (4) ◽  
pp. 555-562 ◽  
Author(s):  
B. L. Skjelkvåle ◽  
R. F. Wright ◽  
A. Henriksen
Keyword(s):  
Base Cations ◽  
Chemical Recovery ◽  
N Leaching ◽  
National Scale ◽  
Western Norway ◽  
Acid Neutralising Capacity ◽  
Recovery From Acidification ◽  
Lakewater Chemistry ◽  
Southern Norway ◽  
Eastern Norway

Abstract. Surveys of 485 lakes in Norway conducted in 1986 and again in 1995 reveal widespread chemical recovery from acidification. Sulphate concentrations in lakes have decreased by 40% in acidified areas in southern Norway. This decrease has been compensated about 25% by decreases in concentrations of base cations and of 75% by increased Acid Neutralising Capacity (ANC). The increased ANC in turn reflects lower concentrations of acidic cations Aluminum (ALn+) and Hydrogen (H+). A sub-set of 78 of the 485 lakes sampled yearly between 1986 and 1997 shows that, at first most of the decrease in non-marine sulphate (SO4*) was compensated by a decrease in base cations, such that ANC remained unchanged. Then as SO4* continued to decrease, the concentrations of non- marine calcium and magnesium ((Ca+Mg)*) levelled out. Consequently, ANC increased, and H+ and Aln+ started to decrease. In eastern Norway, this shift occurred in 1989–90, and came slightly later in southern and western Norway. Similar shifts in trends in about 1991–92 can also be seen in the non-acidified areas in central and northern Norway. This shift in trends is not as pronounced in western Norway, perhaps because of the confounding influence of sea-salt episodes on water chemistry. This is the first documented national-scale recovery from acidification due to reduced acid deposition. Future climate warming and potentially increased N-leaching can counteract the positive trends in recovery from acidification.

Effects of multiple stressors on lakes in south-central Ontario: 15 years of change in lakewater chemistry and sedimentary diatom assemblages

2012 ◽  
Vol 75 (3) ◽  
pp. 349-360 ◽  
Author(s):  
Kristopher R. Hadley ◽  
Andrew M. Paterson ◽  
Roland I. Hall ◽  
John P. Smol
Keyword(s):  
Multiple Stressors ◽  
Diatom Assemblages ◽  
South Central ◽  
Lakewater Chemistry

scholarly journals Five decades of declining methylmercury concentrations in boreal foodwebs suggest pivotal role for sulphate deposition

2020 ◽  
Vol 714 ◽  
pp. 136774 ◽  
Author(s):  
Hans Fredrik Veiteberg Braaten ◽  
Markus Lindholm ◽  
Heleen A. de Wit
Keyword(s):  
Pivotal Role ◽  
Sulphate Deposition

scholarly journals Response of sulphur dynamics in European catchments to decreasing sulphate deposition

2001 ◽  
Vol 5 (3) ◽  
pp. 311-326 ◽  
Author(s):  
A. Prechtel ◽  
C. Alewell ◽  
M. Armbruster ◽  
J. Bittersohl ◽  
J. M. Cullen ◽  
...  
Keyword(s):  
Czech Republic ◽  
Future Research ◽  
Clear Trend ◽  
Sulphur Deposition ◽  
The Czech Republic ◽  
Run Off ◽  
Major Interest ◽  
Sulphate Deposition ◽  
Long Term Trends

Abstract. Following the decline in sulphur deposition in Europe, sulphate dynamics of catchments and the reversibility of anthropogenic acidification of soils and freshwaters became of major interest. Long-term trends in sulphate concentrations and fluxes in precipitation/throughfall and freshwaters of 20 European catchments were analysed to evaluate catchment response to decreasing sulphate deposition. Sulphate deposition in the catchments studied declined by 38-82% during the last decade. Sulphate concentrations in all freshwaters decreased significantly, but acidification reversal was clearly delayed in the German streams. In Scandinavian streams and Czech/Slovakian lakes sulphate concentrations responded quickly to decreased input. Sulphate fluxes in run-off showed no clear trend in Germany and Italy but decreased in Scandinavia, the Czech Republic and Slovakia. The decrease, however, was less than the decline in input fluxes. While long-term sulphate output fluxes from catchments were generally correlated to input fluxes, most catchments started a net release of sulphate during the early 1990s. Release of stored sulphate leads to a delay of acidification reversal and can be caused by four major processes. Desorption and excess mineralisation were regarded as the most important for the catchments investigated, while oxidation and weathering were of lesser importance for the long-term release of sulphate. Input from weathering has to be considered for the Italian catchments. Sulphate fluxes in German catchments, with deeply weathered soils and high soil storage capacity, responded more slowly to decreased deposition than catchments in Scandinavia and the Czech Republic/Slovakia, which have thin soils and relatively small sulphate storage. For predictions of acidification reversal, soil characteristics, sulphur pools and their dynamics have to be evaluated in future research. Keywords: acidification reversal, sulphur, sulphate release, Europe, catchments, deposition, lake, stream

scholarly journals Recovery from acidification of lochs in Galloway, south-west Scotland, UK: 1979-1998

2001 ◽  
Vol 5 (3) ◽  
pp. 421-432 ◽  
Author(s):  
R. C. Ferrier ◽  
R. C. Helliwell ◽  
B. J. Cosby ◽  
A. Jenkins ◽  
R. F. Wright
Keyword(s):  
General Pattern ◽  
Base Cations ◽  
Rapid Decline ◽  
Sea Salts ◽  
South West ◽  
Acid Neutralising Capacity ◽  
Sulphate Deposition ◽  
Recovery From Acidification ◽  
Chloride Concentrations

Abstract. The Galloway region of south-west Scotland has historically been subject to long-term deposition of acidic precipitation which has resulted in acidification of soils and surface waters and subsequent damage to aquatic ecology. Since the end of the 1970s, however, acidic deposition has decreased substantially. The general pattern is for a rapid decline in non-marine sulphate in rainwater over the period 1978-1988 followed by stable concentrations to the mid-1990s. Concentrations of nitrate and ammonium in deposition have remained constant between 1980 and 1998. Seven water quality surveys of 48 lochs in the Galloway region have been conducted between 1979 and 1998. During the first 10 years, from 1979, there was a major decline in regional sulphate concentrations in the lochs, which was expected to have produced a decline in base cations and an increase in the acid neutralising capacity. But sea-salt levels (as indicated by chloride concentrations) were approximately 25% higher in 1988 than in 1979 and thus short-term acidification due to sea-salts offset much of the long-term recovery trend expected in the lochs. During the next 10 years, however, the chloride concentrations returned to 1979 levels and the lochs showed large increases in acid neutralising capacity despite little change in sulphate concentrations. From the observed decline in sulphate deposition and concentrations of sulphate in the lochs, it appears that approximately 75% of the possible improvement in acid neutralising capacity has already occurred over the 20-year period (1979-1998). The role of acid deposition as a driving factor for change in water chemistry in the Galloway lochs is confounded by concurrent changes in other driving variables, most notably, factors related to episodic and year-to-year variations in climate. In addition to inputs of sea-salts, climate probably also influences other chemical signals such as peaks in regional nitrate concentrations and the sharp increase in dissolved organic carbon during the 1990s. Keywords: acidification, recovery, Galloway, sulphur, nitrogen

Quantification of changes in lakewater chemistry in response to acidic deposition

Nature ◽  
1990 ◽  
Vol 345 (6270) ◽  
pp. 54-58 ◽  
Author(s):  
T. J. Sullivan ◽  
D. F. Charles ◽  
J. P. Smol ◽  
B. F. Cumming ◽  
A. R. Selle ◽  
...  
Keyword(s):  
Acidic Deposition ◽  
Lakewater Chemistry
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