Anab initiostudy of dissociative electron attachment to NaHCO3and NaCO3, and the role of these reactions in the formation of sudden sodium layers

1993 ◽  
Vol 20 (1) ◽  
pp. 21-24 ◽  
Author(s):  
B. Rajasekhar ◽  
John M. C. Plane
Keyword(s):  
Electron Attachment ◽  
Dissociative Electron Attachment

Photoinduced dissociative electron attachment of CH3Br on Pt(111): The role of the local work function

1992 ◽  
Vol 96 (12) ◽  
pp. 9114-9121 ◽  
Author(s):  
V. A. Ukraintsev ◽  
T. J. Long ◽  
T. Gowl ◽  
I. Harrison
Keyword(s):  
Work Function ◽  
Electron Attachment ◽  
Dissociative Electron Attachment ◽  
Local Work

The role of dissociative electron attachment to metal halides in a low-pressure glow discharge

2010 ◽  
Vol 4 (1) ◽  
pp. 1-7 ◽  
Author(s):  
S. O. Adamson ◽  
M. A. Deminskii ◽  
A. V. Zaitsevskii ◽  
B. V. Potapkin ◽  
M. Ya. Tudorovskaya ◽  
...  
Keyword(s):  
Glow Discharge ◽  
Electron Attachment ◽  
Low Pressure ◽  
Dissociative Electron Attachment ◽  
Metal Halides ◽  
Pressure Glow Discharge

scholarly journals Electron-Induced Decomposition of Uracil-5-yl O-(N,N-dimethylsulfamate): Role of Methylation in Molecular Stability

2021 ◽  
Vol 22 (5) ◽  
pp. 2344
Author(s):  
Eugene Arthur-Baidoo ◽  
Karina Falkiewicz ◽  
Lidia Chomicz-Mańka ◽  
Anna Czaja ◽  
Sebastian Demkowicz ◽  
...  
Keyword(s):  
Gas Phase ◽  
Quantum Chemical ◽  
Electron Attachment ◽  
Dissociative Electron Attachment ◽  
Stabilization Method ◽  
Radical Species ◽  
Molecular Stability ◽  
Resonance Stabilization ◽  
Induced Decomposition

The incorporation of modified uracil derivatives into DNA leads to the formation of radical species that induce DNA damage. Molecules of this class have been suggested as radiosensitizers and are still under investigation. In this study, we present the results of dissociative electron attachment to uracil-5-yl O-(N,N-dimethylsulfamate) in the gas phase. We observed the formation of 10 fragment anions in the studied range of electron energies from 0–12 eV. Most of the anions were predominantly formed at the electron energy of about 0 eV. The fragmentation paths were analogous to those observed in uracil-5-yl O-sulfamate, i.e., the methylation did not affect certain bond cleavages (O-C, S-O and S-N), although relative intensities differed. The experimental results are supported by quantum chemical calculations performed at the M06-2X/aug-cc-pVTZ level of theory. Furthermore, a resonance stabilization method was used to theoretically predict the resonance positions of the fragment anions O− and CH3−.

scholarly journals Electron Attachment to Cytosine: The Role of Water

2021 ◽  
Author(s):  
Pooja Verma ◽  
Debashree Ghosh ◽  
Achintya Kumar Dutta
Keyword(s):  
Electron Attachment
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