The stability of magnesite in the transition zone and the lower mantle as function of oxygen fugacity

2011 ◽  
Vol 38 (19) ◽  
pp. n/a-n/a ◽  
Author(s):  
V. Stagno ◽  
Y. Tange ◽  
N. Miyajima ◽  
C. A. McCammon ◽  
T. Irifune ◽  
...  
2019 ◽  
Vol 117 (1) ◽  
pp. 184-189 ◽  
Author(s):  
Yanhao Lin ◽  
Qingyang Hu ◽  
Yue Meng ◽  
Michael Walter ◽  
Ho-Kwang Mao

The distribution and transportation of water in Earth’s interior depends on the stability of water-bearing phases. The transition zone in Earth’s mantle is generally accepted as an important potential water reservoir because its main constituents, wadsleyite and ringwoodite, can incorporate weight percent levels of H2O in their structures at mantle temperatures. The extent to which water can be transported beyond the transition zone deeper into the mantle depends on the water carrying capacity of minerals stable in subducted lithosphere. Stishovite is one of the major mineral components in subducting oceanic crust, yet the capacity of stishovite to incorporate water beyond at lower mantle conditions remains speculative. In this study, we combine in situ laser heating with synchrotron X-ray diffraction to show that the unit cell volume of stishovite synthesized under hydrous conditions is ∼2.3 to 5.0% greater than that of anhydrous stishovite at pressures of ∼27 to 58 GPa and temperatures of 1,240 to 1,835 K. Our results indicate that stishovite, even at temperatures along a mantle geotherm, can potentially incorporate weight percent levels of H2O in its crystal structure and has the potential to be a key phase for transporting and storing water in the lower mantle.


1998 ◽  
Vol 20 (4) ◽  
pp. 163-169 ◽  
Author(s):  
Eiji OHTANI ◽  
Yasuhiro KUDOH ◽  
Hiroshi NAITO ◽  
Haruo ARASHI

1964 ◽  
Vol 4 (04) ◽  
pp. 356-362 ◽  
Author(s):  
J.M. Dumore

Abstract If, in a vertical, downward miscible displacement, the transition zone between the displacing and displaced fluids is neglected, a criterion for stable displacement can be obtained by considering a small hypothetical protrusion of one of the fluids into the other. This criterion leads to the definition of the well-known critical rate, uc = kg ??/?µ. The consideration is further extended by taking into account the transition zone that develops as a result of diffusion and mixing. A generalization of the previous criterion leads to the definition of another characteristic rate, the stable rate, which in actual miscible drives will be less than the critical rate. In such drives, the entire transition zone is stable at rates less than the stable rate. At rates between the stable and critical rates, the displacement is only partly stable, i.e. part of the transition zone adjacent to the displaced fluid is in an unstable position. From that part of the transition zone viscous fingers will develop. At rates greater than the critical rate the entire displacement is unstable and viscous fingers will develop more strongly. Results of laboratory experiments are in agreement with the expected behavior based on the theoretically deduced stability of the displacement. INTRODUCTION The simplest form of miscible drive in an oil-bearing formation is the injection of a fluid that is completely miscible* with the oil under reservoir conditions. In general, such a fluid, a solvent for example, is less dense and less viscous than the oil present in the formation. If it is injected into a horizontal homogeneous layer, gravitational forces will lead to the formation of a gravity tongue of solvent in the upper part of the layer and the adverse solvent-oil viscosity ratio will cause viscous fingers to develop. If, however, the solvent is injected up-structure into a dipping layer, gravity has a favorable effect, because it tends to keep the less dense solvent up-structure. Tongue formation and viscous fingering are consequently reduced and it is even possible that they will be suppressed completely. Viscous fingering and gravity tonguing are the consequences of the instability of the displacement. A stable displacement cannot result in growing viscous fingers and/or growing gravity tongues. Since large amounts of oil can be bypassed if there is viscous fingering and/or gravity tonguing, the stability of a miscible drive is very important with respect to the recovery efficiency of the drive. The stability is of particular importance in miscible-slug drives, as it determines how quickly the miscible slug between the displaced and displacing fluids will be distorted and broken up, after which the drive is no longer completely miscible. Stability is thus a most important factor in determining the success of a miscible drive, and it is considered that the aspects of stability considered in this paper will make a useful contribution to existing theories. Consideration is given only to vertical downward displacements, in which no gravity tongues can develop and which are therefore simpler than downward displacements in sloping layers.


2007 ◽  
Vol 260 (1-2) ◽  
pp. 1-9 ◽  
Author(s):  
Frank E. Brenker ◽  
Christian Vollmer ◽  
Laszlo Vincze ◽  
Bart Vekemans ◽  
Anja Szymanski ◽  
...  
Keyword(s):  

1980 ◽  
Vol 70 (2) ◽  
pp. 487-508
Author(s):  
Sonja Faber ◽  
Gerhard MÜller

abstract Precursors to S and SKS were observed in long-period SRO and WWSSN seismograms of the Romanian earthquake of March 4, 1977, recorded in the United States at distances from 68° to 93°. According to the fault-plane solution, the stations were close to a nodal plane and SV radiation was optimum in their direction. Particle-motion diagrams, constructed from the digital data of the SRO station ANMO (distance 89.1°), show the P-wave character of the precursors. Several interpretations are discussed; the most plausible is that the precursors are Sp phases generated by conversion from S to P below the station. The travel-time differences between S or SKS and Sp are about 60 sec and indicate conversion in the transition zone between the upper and lower mantle. Sp conversions were also observed at long-period WWSSN stations in the western United States for 2 Tonga-Fiji deep-focus earthquakes (distances from 82° to 96°). Special emphasis is given in this paper to the calculation of theoretical seismograms, both for Sp precursors and the P-wave coda, including high-order multiples such as sP4 which may arrive simultaneously with Sp. The Sp calculations show: (1) the conversions produced by S, ScS, and SKS at interfaces or transition zones between the upper and lower mantle form a complicated interference pattern, and (2) conversion at transition zones is less effective than at first-order discontinuities only if their thickness is greater than about half a wavelength of S waves. As a consequence, details of the velocity structure between the upper and lower mantle can only be determined within these limits from long-period Sp observations. Our observations are compatible with velocity models having pronounced transition zones at depths of 400 and 670 km as have been proposed for the western United States, and they exclude much smoother structures. Our study suggests that long-period Sp precursors from pure thrust or normal-fault earthquakes, observed at distances from 70° to 95° close to a nodal plane and at azimuths roughly perpendicular to its strike, offer a simple means for qualitative mapping of the sharpness of the transition zones between the upper and lower mantle.


Materials ◽  
2020 ◽  
Vol 13 (2) ◽  
pp. 408 ◽  
Author(s):  
Lidong Dai ◽  
Haiying Hu ◽  
Jianjun Jiang ◽  
Wenqing Sun ◽  
Heping Li ◽  
...  

In this paper, we present the recent progress in the experimental studies of the electrical conductivity of dominant nominally anhydrous minerals in the upper mantle and mantle transition zone of Earth, namely, olivine, pyroxene, garnet, wadsleyite and ringwoodite. The main influence factors, such as temperature, pressure, water content, oxygen fugacity, and anisotropy are discussed in detail. The dominant conduction mechanisms of Fe-bearing silicate minerals involve the iron-related small polaron with a relatively large activation enthalpy and the hydrogen-related defect with lower activation enthalpy. Specifically, we mainly focus on the variation of oxygen fugacity on the electrical conductivity of anhydrous and hydrous mantle minerals, which exhibit clearly different charge transport processes. In representative temperature and pressure environments, the hydrogen of nominally anhydrous minerals can tremendously enhance the electrical conductivity of the upper mantle and transition zone, and the influence of trace structural water (or hydrogen) is substantial. In combination with the geophysical data of magnetotelluric surveys, the laboratory-based electrical conductivity measurements can provide significant constraints to the water distribution in Earth’s interior.


Lithos ◽  
2020 ◽  
Vol 370-371 ◽  
pp. 105637
Author(s):  
Dinara Sagatova ◽  
Anton Shatskiy ◽  
Nursultan Sagatov ◽  
Pavel N. Gavryushkin ◽  
Konstantin D. Litasov

Minerals ◽  
2019 ◽  
Vol 10 (1) ◽  
pp. 18 ◽  
Author(s):  
Alexey Ragozin ◽  
Dmitry Zedgenizov ◽  
Vladislav Shatsky ◽  
Konstantin Kuper ◽  
Hiroyuki Kagi

The paper presents new data on the internal structure of super-deep (sublithospheric) diamonds from Saõ-Luiz river placers (Brazil) and from alluvial placers of the northeastern Siberian platform (Yakutia). The sublithospheric origin of these diamonds is supported by the presence of mineral inclusions corresponding to associations of the transition zone and lower mantle. The features of morphology and internal structure have been studied by optical and scanning electron microscopy (SEM), cathodoluminescence topography (CL), and electron backscatter diffraction (EBSD) techniques. Diamonds typically have complicated growth histories displaying alternating episodes of growth, dissolution, and post-growth deformation and crushing processes. Most crystals have endured both plastic and brittle deformation during the growth history. Abundant deformation and resorption/growth features suggest a highly dynamic growth environment for super-deep diamonds. High temperatures expected in the transition zone and lower mantle could explain the plastic deformations of super-deep diamonds with low nitrogen content.


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