scholarly journals Assessing denitrification in groundwater using natural gradient tracer tests with15N: In situ measurement of a sequential multistep reaction

2004 ◽  
Vol 40 (7) ◽  
Author(s):  
Richard L. Smith ◽  
John Karl Böhlke ◽  
Stephen P. Garabedian ◽  
Kinga M. Revesz ◽  
Tadashi Yoshinari
Keyword(s):  
Tracer Tests ◽  
In Situ Measurement ◽  
Natural Gradient ◽  
Multistep Reaction

In Situ Measurement of Soil Heat Flux with the Gradient Method

2003 ◽  
Vol 2 (4) ◽  
pp. 589
Author(s):  
Douglas R. Cobos ◽  
John M. Baker
Keyword(s):  
Heat Flux ◽  
Gradient Method ◽  
Soil Heat Flux ◽  
In Situ Measurement

In-Situ Measurement Technique of Stress and Structure Change

2015 ◽  
Vol 84 (8) ◽  
pp. 567-572
Author(s):  
Tadafumi HASHIMOTO ◽  
Masahito MOCHIZUKI
Keyword(s):  
Measurement Technique ◽  
Structure Change ◽  
In Situ Measurement

Synthesis of sandwich type acyclic tetra-nuclear silver(I)-N-heterocyclic carbene complexes for wound healing applications

2020 ◽  
Vol 75 (9-10) ◽  
pp. 369-376
Author(s):  
Ayesha Riaz ◽  
Muhammad Adnan Iqbal ◽  
Haq Nawaz Bhatti ◽  
Muhammad Shahid
Keyword(s):  
Alkyl Halides ◽  
Wound Contraction ◽  
Spectroscopic Techniques ◽  
Open Chain ◽  
Standard Drug ◽  
Sandwich Type ◽  
Benzimidazolium Salts ◽  
Multistep Reaction

AbstractTwo meta-xylyl linked tetrakis-benzimidazolium salts (L1-L2) as multidentate ligands and two respective silver complexes (C1 and C2) were synthesized. A multistep reaction was done at room temperature, starting with simple benzimidazole and alkyl halides, going through precursors and salt formation by reflux and finally in situ deprotonation of tetrabenzimidazolium salts with Ag2O to yield respective tetra-nuclear Ag(I)-N-heterocyclic Carbene (NHC) complexes. Propyl and butyl groups were bonded at the terminal positions of tetra-azolium open chain salts. Characterization of compounds was done by analytical and spectroscopic techniques. On the basis of spectroscopic data, a chemical structure with open chains having four Ag(I) ions sandwiched between NHC layers was established. Potential of synthesized complexes (C1 & C2) for wound contraction was evaluated and compared with standard wound contraction gel. Percentage wound contraction of both complexes was found very close to that of standard drug used in parallel.

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