scholarly journals First measurements of ClOOCl in the stratosphere: The coupling of ClOOCl and ClO in the Arctic polar vortex

2004 ◽  
Vol 109 (D3) ◽  
pp. n/a-n/a ◽  
Author(s):  
R. M. Stimpfle ◽  
D. M. Wilmouth ◽  
R. J. Salawitch ◽  
J. G. Anderson
Keyword(s):  
Polar Vortex ◽  
The Arctic

scholarly journals The Diurnal Variation in Stratospheric Ozone from MACC Reanalysis, ERA-Interim, WACCM, and Earth Observation Data: Characteristics and Intercomparison

Atmosphere ◽  
2021 ◽  
Vol 12 (5) ◽  
pp. 625
Author(s):  
Ansgar Schanz ◽  
Klemens Hocke ◽  
Niklaus Kämpfer ◽  
Simon Chabrillat ◽  
Antje Inness ◽  
...  
Keyword(s):  
Diurnal Variation ◽  
Climate Model ◽  
Stratospheric Ozone ◽  
Polar Vortex ◽  
Model Systems ◽  
Atmospheric Composition ◽  
The Arctic ◽  
Observation Data ◽  
High Latitudes ◽  
Free Running

In this study, we compare the diurnal variation in stratospheric ozone of the MACC (Monitoring Atmospheric Composition and Climate) reanalysis, ECMWF Reanalysis Interim (ERA-Interim), and the free-running WACCM (Whole Atmosphere Community Climate Model). The diurnal variation of stratospheric ozone results from photochemical and dynamical processes depending on altitude, latitude, and season. MACC reanalysis and WACCM use similar chemistry modules and calculate a similar diurnal cycle in ozone when it is caused by a photochemical variation. The results of the two model systems are confirmed by observations of the Superconducting Submillimeter-Wave Limb-Emission Sounder (SMILES) experiment and three selected sites of the Network for Detection of Atmospheric Composition Change (NDACC) at Mauna Loa, Hawaii (tropics), Bern, Switzerland (midlatitudes), and Ny-Ålesund, Svalbard (high latitudes). On the other hand, the ozone product of ERA-Interim shows considerably less diurnal variation due to photochemical variations. The global maxima of diurnal variation occur at high latitudes in summer, e.g., near the Arctic NDACC site at Ny-Ålesund, Svalbard. The local OZORAM radiometer observes this effect in good agreement with MACC reanalysis and WACCM. The sensed diurnal variation at Ny-Ålesund is up to 8% (0.4 ppmv) due to photochemical variations in summer and negligible during the dynamically dominated winter. However, when dynamics play a major role for the diurnal ozone variation as in the lower stratosphere (100–20 hPa), the reanalysis models ERA-Interim and MACC which assimilate data from radiosondes and satellites outperform the free-running WACCM. Such a domain is the Antarctic polar winter where a surprising novel feature of diurnal variation is indicated by MACC reanalysis and ERA-Interim at the edge of the polar vortex. This effect accounts for up to 8% (0.4 ppmv) in both model systems. In summary, MACC reanalysis provides a global description of the diurnal variation of stratospheric ozone caused by dynamics and photochemical variations. This is of high interest for ozone trend analysis and other research which is based on merged satellite data or measurements at different local time.

scholarly journals Chemical ozone loss and ozone mini-hole event during the Arctic winter 2010/2011 as observed by SCIAMACHY and GOME-2

2014 ◽  
Vol 14 (7) ◽  
pp. 3247-3276 ◽  
Author(s):  
R. Hommel ◽  
K.-U. Eichmann ◽  
J. Aschmann ◽  
K. Bramstedt ◽  
M. Weber ◽  
...  
Keyword(s):  
Transport Model ◽  
Polar Vortex ◽  
The Arctic ◽  
Optical Absorption Spectroscopy ◽  
Late Winter ◽  
Total Column Ozone ◽  
Bromine Oxide ◽  
Ozone Loss ◽  
Catalytic Cycles ◽  
Total Column

Abstract. Record breaking loss of ozone (O3) in the Arctic stratosphere has been reported in winter–spring 2010/2011. We examine in detail the composition and transformations occurring in the Arctic polar vortex using total column and vertical profile data products for O3, bromine oxide (BrO), nitrogen dioxide (NO2), chlorine dioxide (OClO), and polar stratospheric clouds (PSC) retrieved from measurements made by SCIAMACHY (Scanning Imaging Absorption SpectroMeter for Atmospheric CHartography) on-board Envisat (Environmental Satellite), as well as total column ozone amount, retrieved from the measurements of GOME-2 (Global Ozone Monitoring Experiment) on MetOp-A (Meteorological Experimental Satellite). Similarly we use the retrieved data from DOAS (Differential Optical Absorption Spectroscopy) measurements made in Ny-Ålesund (78.55° N, 11.55° E). A chemical transport model (CTM) has been used to relate and compare Arctic winter–spring conditions in 2011 with those in the previous year. In late winter–spring 2010/2011 the chemical ozone loss in the polar vortex derived from SCIAMACHY observations confirms findings reported elsewhere. More than 70% of O3 was depleted by halogen catalytic cycles between the 425 and 525 K isentropic surfaces, i.e. in the altitude range ~16–20 km. In contrast, during the same period in the previous winter 2009/2010, a typical warm Arctic winter, only slightly more than 20% depletion occurred below 20 km, while 40% of O3 was removed above the 575 K isentrope (~23 km). This loss above 575 K is explained by the catalytic destruction by NOx descending from the mesosphere. In both Arctic winters 2009/2010 and 2010/2011, calculated O3 losses from the CTM are in good agreement to our observations and other model studies. The mid-winter 2011 conditions, prior to the catalytic cycles being fully effective, are also investigated. Surprisingly, a significant loss of O3 around 60%, previously not discussed in detail, is observed in mid-January 2011 below 500 K (~19 km) and sustained for approximately 1 week. The low O3 region had an exceptionally large spatial extent. The situation was caused by two independently evolving tropopause elevations over the Asian continent. Induced adiabatic cooling of the stratosphere favoured the formation of PSC, increased the amount of active chlorine for a short time, and potentially contributed to higher polar ozone loss later in spring.

scholarly journals Volcanic activity sparks the Arctic Oscillation

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Weizheng Qu ◽  
Fei Huang ◽  
Jinping Zhao ◽  
Ling Du ◽  
Yong Cao
Keyword(s):  
Volcanic Activity ◽  
Volcanic Eruption ◽  
Arctic Oscillation ◽  
Polar Vortex ◽  
Volcanic Eruptions ◽  
The Arctic ◽  
Vortex System ◽  
Significant Fluctuation ◽  
The Arctic Oscillation

AbstractThe parasol effect of volcanic dust and aerosol caused by volcanic eruption results in the deepening and strengthening of the Arctic vortex system, thus stimulating or strengthening the Arctic Oscillation (AO). Three of the strongest AOs in more than a century have been linked to volcanic eruptions. Every significant fluctuation of the AO index (AOI = ΔH_middle latitudes − ΔH_Arctic) for many years has been associated with a volcanic eruption. Volcanic activity occurring at different locations in the Arctic vortex circulation will exert different effects on the polar vortex.

Record springtime stratospheric ozone depletion at 80°N in 2020

2021 ◽  
Author(s):  
Ramina Alwarda ◽  
Kristof Bognar ◽  
Kimberly Strong ◽  
Martyn Chipperfield ◽  
Sandip Dhomse ◽  
...  
Keyword(s):  
Ozone Depletion ◽  
Transport Model ◽  
Stratospheric Ozone ◽  
Polar Vortex ◽  
The Arctic ◽  
Optical Absorption Spectroscopy ◽  
Chemical Transport Model ◽  
Polar Stratospheric Clouds ◽  
Ozone Loss ◽  
Stratospheric Clouds

<p>The Arctic winter of 2019-2020 was characterized by an unusually persistent polar vortex and temperatures in the lower stratosphere that were consistently below the threshold for the formation of polar stratospheric clouds (PSCs). These conditions led to ozone loss that is comparable to the Antarctic ozone hole. Ground-based measurements from a suite of instruments at the Polar Environment Atmospheric Research Laboratory (PEARL) in Eureka, Canada (80.05°N, 86.42°W) were used to investigate chemical ozone depletion. The vortex was located above Eureka longer than in any previous year in the 20-year dataset and lidar measurements provided evidence of polar stratospheric clouds (PSCs) above Eureka. Additionally, UV-visible zenith-sky Differential Optical Absorption Spectroscopy (DOAS) measurements showed record ozone loss in the 20-year dataset, evidence of denitrification along with the slowest increase of NO<sub>2</sub> during spring, as well as enhanced reactive halogen species (OClO and BrO). Complementary measurements of HCl and ClONO<sub>2</sub> (chlorine reservoir species) from a Fourier transform infrared (FTIR) spectrometer showed unusually low columns that were comparable to 2011, the previous year with significant chemical ozone depletion. Record low values of HNO<sub>3</sub> in the FTIR dataset are in accordance with the evidence of PSCs and a denitrified atmosphere. Estimates of chemical ozone loss were derived using passive ozone from the SLIMCAT offline chemical transport model to account for dynamical contributions to the stratospheric ozone budget.</p>

scholarly journals On the Nonlinearity of Winter Northern Hemisphere Atmospheric Variability

2019 ◽  
Vol 76 (1) ◽  
pp. 333-356 ◽  
Author(s):  
A. Hannachi ◽  
W. Iqbal
Keyword(s):  
North Atlantic ◽  
Polar Vortex ◽  
Principal Component ◽  
Empirical Orthogonal Functions ◽  
The Arctic ◽  
Climate Change Signal ◽  
Two Dimensional ◽  
Orthogonal Functions ◽  
Local Flow ◽  
The North

Abstract Nonlinearity in the Northern Hemisphere’s wintertime atmospheric flow is investigated from both an intermediate-complexity model of the extratropics and reanalyses. A long simulation is obtained using a three-level quasigeostrophic model on the sphere. Kernel empirical orthogonal functions (EOFs), which help delineate complex structures, are used along with the local flow tendencies. Two fixed points are obtained, which are associated with strong bimodality in two-dimensional kernel principal component (PC) space, consistent with conceptual low-order dynamics. The regimes reflect zonal and blocked flows. The analysis is then extended to ERA-40 and JRA-55 using daily sea level pressure (SLP) and geopotential heights in the stratosphere (20 hPa) and troposphere (500 hPa). In the stratosphere, trimodality is obtained, representing disturbed, displaced, and undisturbed states of the winter polar vortex. In the troposphere, the probability density functions (PDFs), for both fields, within the two-dimensional (2D) kernel EOF space are strongly bimodal. The modes correspond broadly to opposite phases of the Arctic Oscillation with a signature of the negative North Atlantic Oscillation (NAO). Over the North Atlantic–European sector, a trimodal PDF is also obtained with two strong and one weak modes. The strong modes are associated, respectively, with the north (or +NAO) and south (or −NAO) positions of the eddy-driven jet stream. The third weak mode is interpreted as a transition path between the two positions. A climate change signal is also observed in the troposphere of the winter hemisphere, resulting in an increase (a decrease) in the frequency of the polar high (low), consistent with an increase of zonal flow frequency.

scholarly journals Global Hawk dropsonde observations of the Arctic atmosphere obtained during the Winter Storms and Pacific Atmospheric Rivers (WISPAR) field campaign

2014 ◽  
Vol 7 (11) ◽  
pp. 3917-3926 ◽  
Author(s):  
J. M. Intrieri ◽  
G. de Boer ◽  
M. D. Shupe ◽  
J. R. Spackman ◽  
J. Wang ◽  
...  
Keyword(s):  
Large Scale ◽  
Polar Vortex ◽  
Unmanned Aircraft ◽  
The Arctic ◽  
Winter Storms ◽  
Field Campaign ◽  
Atmospheric Rivers ◽  
The North ◽  
Aircraft System ◽  
Global Hawk

Abstract. In February and March of 2011, the Global Hawk unmanned aircraft system (UAS) was deployed over the Pacific Ocean and the Arctic during the Winter Storms and Pacific Atmospheric Rivers (WISPAR) field campaign. The WISPAR science missions were designed to (1) mprove our understanding of Pacific weather systems and the polar atmosphere; (2) evaluate operational use of unmanned aircraft for investigating these atmospheric events; and (3) demonstrate operational and research applications of a UAS dropsonde system at high latitudes. Dropsondes deployed from the Global Hawk successfully obtained high-resolution profiles of temperature, pressure, humidity, and wind information between the stratosphere and surface. The 35 m wingspan Global Hawk, which can soar for ~ 31 h at altitudes up to ~ 20 km, was remotely operated from NASA's Dryden Flight Research Center at Edwards Air Force Base (AFB) in California. During the 25 h polar flight on 9–10 March 2011, the Global Hawk released 35 sondes between the North Slope of Alaska and 85° N latitude, marking the first UAS Arctic dropsonde mission of its kind. The polar flight transected an unusually cold polar vortex, notable for an associated record-level Arctic ozone loss, and documented polar boundary layer variations over a sizable ocean–ice lead feature. Comparison of dropsonde observations with atmospheric reanalyses reveal that, for this day, large-scale structures such as the polar vortex and air masses are captured by the reanalyses, while smaller-scale features, including low-level jets and inversion depths, are mischaracterized. The successful Arctic dropsonde deployment demonstrates the capability of the Global Hawk to conduct operations in harsh, remote regions. The limited comparison with other measurements and reanalyses highlights the potential value of Arctic atmospheric dropsonde observations where routine in situ measurements are practically nonexistent.

scholarly journals Analysis of Arctic Spring Ozone Anomaly in the Phases of QBO and 11-year Solar Cycle for 1979–2011

2021 ◽  
Author(s):  
Yousuke Yamashita ◽  
Hideharu Akiyoshi ◽  
Masaaki Takahashi
Keyword(s):  
Solar Cycle ◽  
Climate Model ◽  
Polar Vortex ◽  
Reanalysis Data ◽  
Early Spring ◽  
The Arctic ◽  
Negative Anomaly ◽  
Late Winter ◽  
Quasi Biennial Oscillation ◽  
Biennial Oscillation

Arctic ozone amount in winter to spring shows large year-to-year variation. This study investigates Arctic spring ozone in relation to the phase of quasi-biennial oscillation (QBO)/the 11-year solar cycle, using satellite observations, reanalysis data, and outputs of a chemistry climate model (CCM) during the period of 1979–2011. For this duration, we found that the composite mean of the Northern Hemisphere high-latitude total ozone in the QBO-westerly (QBO-W)/solar minimum (Smin) phase is slightly smaller than those averaged for the QBO-W/Smax and QBO-E/Smax years in March. An analysis of a passive ozone tracer in the CCM simulation indicates that this negative anomaly is primarily caused by transport. The negative anomaly is consistent with a weakening of the residual mean downward motion in the polar lower stratosphere. The contribution of chemical processes estimated using the column amount difference between ozone and the passive ozone tracer is between 10–20% of the total anomaly in March. The lower ozone levels in the Arctic spring during the QBO-W/Smin years are associated with a stronger Arctic polar vortex from late winter to early spring, which is linked to the reduced occurrence of sudden stratospheric warming in the winter during the QBO-W/Smin years.

scholarly journals Polar processing in a split vortex: early winter Arctic ozone loss in 2012/13

2015 ◽  
Vol 15 (4) ◽  
pp. 4973-5029 ◽  
Author(s):  
G. L. Manney ◽  
Z. D. Lawrence ◽  
M. L. Santee ◽  
N. J. Livesey ◽  
A. Lambert ◽  
...  
Keyword(s):  
Nitric Acid ◽  
Lower Stratosphere ◽  
Polar Vortex ◽  
The Arctic ◽  
Early Winter ◽  
Sudden Stratospheric Warming ◽  
Ozone Loss ◽  
Chlorine Monoxide ◽  
Polar Stratospheric Cloud ◽  
Vortex Split

Abstract. A sudden stratospheric warming (SSW) in early January 2013 caused the polar vortex to split. After the lower stratospheric vortex split on 8 January, the two offspring vortices – one over Canada and the other over Siberia – remained intact, well-confined, and largely at latitudes that received sunlight until they reunited at the end of January. As the SSW began, temperatures abruptly rose above chlorine activation thresholds throughout the lower stratosphere. The vortex was very disturbed prior to the SSW, and was exposed to much more sunlight than usual in December 2012 and January 2013. Aura Microwave Limb Sounder (MLS) nitric acid (HNO3) data and observations from CALIPSO (Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations) indicate extensive polar stratospheric cloud (PSC) activity, with evidence of PSCs containing solid nitric acid trihydrate particles during much of December 2012. Consistent with the sunlight exposure and PSC activity, MLS observations show that chlorine monoxide (ClO) became enhanced early in December. Despite the cessation of PSC activity with the onset of the SSW, enhanced vortex ClO persisted until mid-February, indicating lingering chlorine activation. The smaller Canadian offspring vortex had lower temperatures, lower HNO3, lower hydrogen chloride (HCl), and higher ClO in late January than the Siberian vortex. Chlorine deactivation began later in the Canadian than in the Siberian vortex. HNO3 remained depressed within the vortices after temperatures rose above the PSC existence threshold, and passive transport calculations indicate vortex-averaged denitrification of about 4 ppbv; the resulting low HNO3 values persisted until the vortex dissipated in mid-February. Consistent with the strong chlorine activation and exposure to sunlight, MLS measurements show rapid ozone loss commencing in mid-December and continuing through January. Lagrangian transport estimates suggest ~ 0.7–0.8 ppmv (parts per million by volume) vortex-averaged chemical ozone loss by late January near 500 K (~ 21 km), with substantial loss occurring from ~ 450 to 550 K. The surface area of PSCs in December 2012 was larger than that in any other December observed by CALIPSO. As a result of denitrification, HNO3 abundances in 2012/13 were among the lowest in the MLS record for the Arctic. ClO enhancement was much greater in December 2012 through mid-January 2013 than that at the corresponding time in any other Arctic winter observed by MLS. Furthermore, reformation of HCl appeared to play a greater role in chlorine deactivation than in more typical Arctic winters. Ozone loss in December 2012 and January 2013 was larger than any previously observed in those months. This pattern of exceptional early winter polar processing and ozone loss resulted from the unique combination of dynamical conditions associated with the early January 2013 SSW, namely unusually low temperatures in December 2012 and offspring vortices that remained well-confined and largely in sunlit regions for about a month after the vortex split.

scholarly journals Analyzing ozone variations and uncertainties at high latitudes during Sudden Stratospheric Warming events using MERRA-2

2021 ◽  
Author(s):  
Shima Bahramvash Shams ◽  
Von P. Walden ◽  
James W. Hannigan ◽  
William J. Randel ◽  
Irina V. Petropavlovskikh ◽  
...  
Keyword(s):  
Stratospheric Ozone ◽  
Polar Vortex ◽  
The Arctic ◽  
High Latitudes ◽  
Stratospheric Warming ◽  
Sudden Stratospheric Warming ◽  
Total Column Ozone ◽  
Northern Latitudes ◽  
Stratospheric Dynamics ◽  
Zonal Average

Abstract. Stratospheric circulation is a critical part of the Arctic ozone cycle. Sudden stratospheric warming events (SSWs) manifest the strongest alteration of stratospheric dynamics. Changes in planetary wave propagation vigorously influence zonal mean zonal wind, temperature, and tracer concentrations in the stratosphere over the high latitudes. In this study, we examine six major SSWs from 2004 to 2020 using the Modern-Era Retrospective analysis for Research and Applications, Version 2 (MERRA-2). Using the unique density of observations around the Greenland sector at high latitudes, we perform comprehensive comparisons of high latitude observations with the MERRA-2 ozone dataset during the six major SSWs. Our results show that MERRA-2 captures the high variability of mid stratospheric ozone fluctuations during SSWs over high latitudes. However, larger uncertainties are observed in the lower stratosphere and troposphere. The zonally averaged stratospheric ozone shows a dramatic increase of 9–29 % in total column ozone (TCO) near the time of each SSW, which lasts up to two months. The SSWs exhibit a more significant impact on ozone over high northern latitudes when the polar vortex is mostly elongated as seen in 2009 and 2018 compared to the events in which the polar vortex is displaced towards Europe. The regional impact of SSWs over Greenland has a similar structure as the zonal average, however, exhibits more intense ozone anomalies which is reflected by 15–37 % increase in TCO. The influence of SSW on mid stratospheric ozone levels persists longer than their impact on temperature. This paper is focused on the increased (suppressed) wave activity before (after) the SSWs and their impact on ozone variability at high latitudes. This includes an investigation of the different terms of tracer continuity using MERRA-2 parameters, which emphasizes the key role of vertical advection on mid-stratospheric ozone during the SSWs.

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