scholarly journals Vertical profiles of activated ClO and ozone loss in the Arctic vortex in January and March 2000: In situ observations and model simulations

2003 ◽  
Vol 108 (D22) ◽  
Author(s):  
Bärbel Vogel ◽  
Jens‐Uwe Grooß ◽  
Rolf Müller ◽  
Terry Deshler ◽  
Juha Karhu ◽  
...  
Keyword(s):  
The Arctic ◽  
Vertical Profiles ◽  
Model Simulations ◽  
Ozone Loss ◽  
In Situ Observations

Could an ocean climate atlas generated by a model compete with an observational one?

2020 ◽  
Author(s):  
Georgy I. Shapiro ◽  
Jose M. Gonzalez-Ondina ◽  
Xavier Francis ◽  
Hyee S. Lim ◽  
Ali Almehrezi
Keyword(s):  
Standard Error ◽  
Sea Surface ◽  
Vertical Profiles ◽  
Individual Data ◽  
Model Simulations ◽  
Ocean Climate ◽  
Data Points ◽  
In Situ Observations ◽  
The Mean

<p>Modern numerical ocean models have matured over the last decades and are able to provide accurate fore- and hind-cast of the ocean state. The most accurate data could be obtained from the reanalysis where the model run in a hindcast mode with assimilation of available observational data. An obvious benefit of model simulation is that it provides the spatial density and temporal resolution which cannot be achieved by in-situ observations or satellite derived measurements. It is not unusual that even a relatively small area of the ocean model can have in access of 100,000 nodes in the horizontal, each containing vertical profiles of temperature, salinity, velocity and other ocean parameters with a temporal resolution theoretically as high as a few minutes. Remotely sensed (satellite) observations of sea surface temperature can compete with the models in terms of spatial resolution, however they only produce data at the sea surface not the vertical profiles. On the other hand, in-situ observations have a benefit of being much more precise than model simulations. For instance a widely used CTD profiler SBE 911plus has accuracy of about 0.001 °C, which is not achievable by models.</p><p>In the creation of a climatic atlas the higher accuracy of individual profiles provided by in-situ measurements may become less beneficial. Assuming the normal distribution of data at each location, the standard error of the mean (SEM) is calculated as SE=S/SQRT(N), where S is the standard deviation of individual data points around the mean, and N is the number of data points. The climatic data are obtained by averaging a large number of individual data points, and here the benefit of having more data points may become a greater advantage than the accuracy of a single observation.  </p><p>In this study we have created an ocean climate atlas for the northern part of the Indian Ocean including the Red Sea and the Arabian Gulf using model generated data. The data were taken from Copernicus Marine Environment Monitoring Service (CMEMS) reanalysis product GLOBAL_REANALYSIS_PHY_001_030 with 1/12° horizontal resolution and 50 vertical levels for the period 1998 to 2017. The model component is the NEMO platform driven at the surface by ECMWF ERA-Interim reanalysis. The model assimilates along track altimeter data, satellite Sea Surface Temperature, as well as in-situ temperature and salinity vertical profiles where available. The monthly data from CMEMS were then averaged over 20 years to produce an atlas at the surface, 10, 20, 30, 75, 100, 125, 150, 200, 250, 300, 400, and 500 m depths.  The standard error of the mean has been calculated for each point and each depth level on the native grid (1/12 degree).</p><p>The atlas based on model simulations was compared with the latest version of the World Ocean Atlas (WOA)  2018 published by the NCEI.  WOA has objectively analysed climatological mean fields on a ¼  degree grid. The differences between the mean values and SEMs from observational and simulated atlases are analysed, and the potential causes of mismatch are discussed.</p>

scholarly journals International Arctic Systems for Observing the Atmosphere: An International Polar Year Legacy Consortium

2016 ◽  
Vol 97 (6) ◽  
pp. 1033-1056 ◽  
Author(s):  
Taneil Uttal ◽  
Sandra Starkweather ◽  
James R. Drummond ◽  
Timo Vihma ◽  
Alexander P. Makshtas ◽  
...  
Keyword(s):  
United States ◽  
The United States ◽  
Satellite Observations ◽  
The Arctic ◽  
International Polar Year ◽  
Network Measurements ◽  
International Polar ◽  
In Situ Observations ◽  
Arctic Atmosphere

Abstract International Arctic Systems for Observing the Atmosphere (IASOA) activities and partnerships were initiated as a part of the 2007–09 International Polar Year (IPY) and are expected to continue for many decades as a legacy program. The IASOA focus is on coordinating intensive measurements of the Arctic atmosphere collected in the United States, Canada, Russia, Norway, Finland, and Greenland to create synthesis science that leads to an understanding of why and not just how the Arctic atmosphere is evolving. The IASOA premise is that there are limitations with Arctic modeling and satellite observations that can only be addressed with boots-on-the-ground, in situ observations and that the potential of combining individual station and network measurements into an integrated observing system is tremendous. The IASOA vision is that by further integrating with other network observing programs focusing on hydrology, glaciology, oceanography, terrestrial, and biological systems it will be possible to understand the mechanisms of the entire Arctic system, perhaps well enough for humans to mitigate undesirable variations and adapt to inevitable change.

scholarly journals Record-breaking ozone loss in the Arctic winter 2010/2011: comparison with 1996/1997

2012 ◽  
Vol 12 (15) ◽  
pp. 7073-7085 ◽  
Author(s):  
J. Kuttippurath ◽  
S. Godin-Beekmann ◽  
F. Lefèvre ◽  
G. Nikulin ◽  
M. L. Santee ◽  
...  
Keyword(s):  
Transport Model ◽  
Chemical Transport ◽  
The Arctic ◽  
Altitude Range ◽  
Chemical Transport Model ◽  
Model Simulations ◽  
Ozone Loss ◽  
Elevated Ozone ◽  
Record Value ◽  
First Time

Abstract. We present a detailed discussion of the chemical and dynamical processes in the Arctic winters 1996/1997 and 2010/2011 with high resolution chemical transport model (CTM) simulations and space-based observations. In the Arctic winter 2010/2011, the lower stratospheric minimum temperatures were below 195 K for a record period of time, from December to mid-April, and a strong and stable vortex was present during that period. Simulations with the Mimosa-Chim CTM show that the chemical ozone loss started in early January and progressed slowly to 1 ppmv (parts per million by volume) by late February. The loss intensified by early March and reached a record maximum of ~2.4 ppmv in the late March–early April period over a broad altitude range of 450–550 K. This coincides with elevated ozone loss rates of 2–4 ppbv sh−1 (parts per billion by volume/sunlit hour) and a contribution of about 30–55% and 30–35% from the ClO-ClO and ClO-BrO cycles, respectively, in late February and March. In addition, a contribution of 30–50% from the HOx cycle is also estimated in April. We also estimate a loss of about 0.7–1.2 ppmv contributed (75%) by the NOx cycle at 550–700 K. The ozone loss estimated in the partial column range of 350–550 K exhibits a record value of ~148 DU (Dobson Unit). This is the largest ozone loss ever estimated in the Arctic and is consistent with the remarkable chlorine activation and strong denitrification (40–50%) during the winter, as the modeled ClO shows ~1.8 ppbv in early January and ~1 ppbv in March at 450–550 K. These model results are in excellent agreement with those found from the Aura Microwave Limb Sounder observations. Our analyses also show that the ozone loss in 2010/2011 is close to that found in some Antarctic winters, for the first time in the observed history. Though the winter 1996/1997 was also very cold in March–April, the temperatures were higher in December–February, and, therefore, chlorine activation was moderate and ozone loss was average with about 1.2 ppmv at 475–550 K or 42 DU at 350–550 K, as diagnosed from the model simulations and measurements.

scholarly journals Integrative and comprehensive Understanding on Polar Environments (iCUPE): the concept and initial results

2020 ◽  
Author(s):  
Tuukka Petäjä ◽  
Ella-Maria Duplissy ◽  
Ksenia Tabakova ◽  
Julia Schmale ◽  
Barbara Altstädter ◽  
...  
Keyword(s):  
Remote Sensing ◽  
Natural Resources ◽  
Satellite Remote Sensing ◽  
Integrated Approach ◽  
The Arctic ◽  
Polar Regions ◽  
Comprehensive Understanding ◽  
In Situ Observations ◽  
Initial Results

Abstract. The role of polar regions increases in terms of megatrends such as globalization, new transport routes, demography and use of natural resources consequent effects of regional and transported pollutant concentrations. We set up the ERA-PLANET Strand 4 project iCUPE – integrative and Comprehensive Understanding on Polar Environments to provide novel insights and observational data on global grand challenges with an Arctic focus. We utilize an integrated approach combining in situ observations, satellite remote sensing Earth Observations (EO) and multi-scale modeling to synthesize data from comprehensive long-term measurements, intensive campaigns and satellites to deliver data products, metrics and indicators to the stakeholders concerning the environmental status, availability and extraction of natural resources in the polar areas. The iCUPE work consists of thematic state-of-the-art research and provision of novel data in atmospheric pollution, local sources and transboundary transport, characterization of arctic surfaces and their changes, assessment of concentrations and impacts of heavy metals and persistent organic pollutants and their cycling, quantification of emissions from natural resource extraction and validation and optimization of satellite Earth Observation (EO) data streams. In this paper we introduce the iCUPE project and summarize initial results arising out of integration of comprehensive in situ observations, satellite remote sensing and multiscale modeling in the Arctic context.

scholarly journals A re-evaluation of the ClO/Cl<sub>2</sub>O<sub>2</sub> equilibrium constant based on stratospheric in-situ observations

2005 ◽  
Vol 5 (3) ◽  
pp. 693-702 ◽  
Author(s):  
M. von Hobe ◽  
J.-U. Grooß ◽  
R. Müller ◽  
S. Hrechanyy ◽  
U. Winkler ◽  
...  
Keyword(s):  
Temperature Dependence ◽  
Equilibrium Constant ◽  
Thermal Equilibrium ◽  
Loss Rate ◽  
Equilibrium Constants ◽  
The Arctic ◽  
Strong Temperature Dependence ◽  
Atmospheric Models ◽  
Ozone Loss

Abstract. In-situ measurements of ClO and its dimer carried out during the SOLVE II/VINTERSOL-EUPLEX and ENVISAT Validation campaigns in the Arctic winter 2003 suggest that the thermal equilibrium between the dimer formation and dissociation is shifted significantly towards the monomer compared to the current JPL 2002 recommendation. Detailed analysis of observations made in thermal equilibrium allowed to re-evaluate the magnitude and temperature dependence of the equilibrium constant. A fit of the JPL format for equilibrium constants yields KEQ=3.61x10-27exp(8167/T), but to reconcile the observations made at low temperatures with the existing laboratory studies at room temperature, a modified equation, KEQ=5.47x10-25(T/300)-2.29exp(6969/T), is required. This format can be rationalised by a strong temperature dependence of the reaction enthalpy possibly induced by Cl2O2 isomerism effects. At stratospheric temperatures, both equations are practically equivalent. Using the equilibrium constant reported here rather than the JPL 2002 recommendation in atmospheric models does not have a large impact on simulated ozone loss. Solely at large zenith angles after sunrise, a small decrease of the ozone loss rate due to the ClO dimer cycle and an increase due to the ClO-BrO cycle (attributed to the enhanced equilibrium ClO concentrations) is observed, the net effect being a slightly stronger ozone loss rate.

scholarly journals The Energy Budget of the Polar Atmosphere in MERRA

2012 ◽  
Vol 25 (1) ◽  
pp. 5-24 ◽  
Author(s):  
Richard I. Cullather ◽  
Michael G. Bosilovich
Keyword(s):  
Energy Budget ◽  
The Arctic ◽  
Polar Regions ◽  
Polar Cap ◽  
The South ◽  
Atmospheric Energy ◽  
In Situ Observations ◽  
Energy Convergence ◽  
South Polar

Abstract Components of the atmospheric energy budget from the Modern-Era Retrospective Analysis for Research and Applications (MERRA) are evaluated in polar regions for the period 1979–2005 and compared with previous estimates, in situ observations, and contemporary reanalyses. Closure of the budget is reflected by the analysis increments term, which indicates an energy surplus of 11 W m−2 over the North Polar cap (70°–90°N) and 22 W m−2 over the South Polar cap (70°–90°S). Total atmospheric energy convergence from MERRA compares favorably with previous studies for northern high latitudes but exceeds the available previous estimate for the South Polar cap by 46%. Discrepancies with the Southern Hemisphere energy transport are largest in autumn and may be related to differences in topography with earlier reanalyses. For the Arctic, differences between MERRA and other sources in top of atmosphere (TOA) and surface radiative fluxes are largest in May. These differences are concurrent with the largest discrepancies between MERRA parameterized and observed surface albedo. For May, in situ observations of the upwelling shortwave flux in the Arctic are 80 W m−2 larger than MERRA, while the MERRA downwelling longwave flux is underestimated by 12 W m−2 throughout the year. Over grounded ice sheets, the annual mean net surface energy flux in MERRA is erroneously nonzero. Contemporary reanalyses from the Climate Forecast Center (CFSR) and the Interim Re-Analyses of the European Centre for Medium-Range Weather Forecasts (ERA-I) are found to have better surface parameterizations; however, these reanalyses also disagree with observed surface and TOA energy fluxes. Discrepancies among available reanalyses underscore the challenge of reproducing credible estimates of the atmospheric energy budget in polar regions.

scholarly journals Vertical profiles of pure dust and mixed smoke–dust plumes inferred from inversion of multiwavelength Raman/polarization lidar data and comparison to AERONET retrievals and in situ observations

2013 ◽  
Vol 52 (14) ◽  
pp. 3178 ◽  
Author(s):  
Detlef Müller ◽  
Igor Veselovskii ◽  
Alexei Kolgotin ◽  
Matthias Tesche ◽  
Albert Ansmann ◽  
...  
Keyword(s):  
Lidar Data ◽  
Vertical Profiles ◽  
In Situ Observations

Gelatinous zooplankton of the Arctic Ocean: in situ observations under the ice

Polar Biology ◽  
2004 ◽  
Vol 28 (3) ◽  
pp. 207-217 ◽  
Author(s):  
K. A. Raskoff ◽  
J. E. Purcell ◽  
R. R. Hopcroft
Keyword(s):  
Arctic Ocean ◽  
Gelatinous Zooplankton ◽  
The Arctic ◽  
The Arctic Ocean ◽  
In Situ Observations

scholarly journals Model simulations of stratospheric ozone loss caused by enhanced mesospheric NO<sub>x</sub> during Arctic Winter 2003/2004

2008 ◽  
Vol 8 (2) ◽  
pp. 4911-4947
Author(s):  
B. Vogel ◽  
P. Konopka ◽  
J.-U. Grooß ◽  
R. Müller ◽  
B. Funke ◽  
...  
Keyword(s):  
Stratospheric Ozone ◽  
Potential Temperature ◽  
Satellite Observations ◽  
The Arctic ◽  
Local Production ◽  
Model Simulations ◽  
Ozone Loss ◽  
Upper Limit ◽  
Non Local ◽  
The Impact

Abstract. Satellite observations show that the enormous solar proton events (SPEs) in October–November 2003 had significant effects on the composition of the stratosphere and mesosphere in the polar regions. After the October–November 2003 SPEs and in early 2004 significant enhancements of NOx(=NO+NO2) in the upper stratosphere and lower mesosphere in the Northern Hemisphere were observed by several satellite instruments. Here we present global full chemistry calculations performed with the CLaMS model to study the impact of mesospheric NOx intrusions on Arctic polar ozone loss processes in the stratosphere. Several model simulations are preformed with different upper boundary conditions for NOx at 2000 K potential temperature (≈50 km altitude). In our study we focus on the impact of the non-local production of NOx which means the downward transport of enhanced NOx from the mesosphere in the stratosphere. The local production of NOx in the stratosphere is neglected. Our findings show that intrusions of mesospheric air into the stratosphere, transporting high burdens of NOx, affect the composition of the Arctic polar region down to about 400 K (≈17–18 km). We compare our simulated NOx and O3 mixing ratios with satellite observations by ACE-FTS and MIPAS processed at IMK/IAA and derive an upper limit for the ozone loss caused by enhanced mesospheric NOx. Our findings show that in the Arctic polar vortex (Equivalent Lat.>70° N) the accumulated column ozone loss between 350–2000 K potential temperature (≈14–50 km altitude) caused by the SPEs in October–November 2003 in the stratosphere is up to 3.3 DU with an upper limit of 5.5 DU until end of November. Further we found that about 10 DU but lower than 18 DU accumulated ozone loss additionally occurs until end of March 2004 caused by the transport of mesospheric NOx-rich air in early 2004. In the lower stratosphere (350–700 K≈14–27 km altitude) the SPEs of October–November 2003 have negligible small impact on ozone loss processes until end of November and the mesospheric NOx intrusions in early 2004 yield ozone loss about 3.5 DU, but clearly lower than 6.5 DU until end of March. Overall, the non-local production of NOx is an additional variability to the existing variations of the ozone loss observed in the Arctic.

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