Synthesis and Fluxional Behavior, Including a Comparative Analysis of the Pd−N Bond Rupture, of New Chiral Complexes of Palladium(0) and -(II) with a Rigid (Aminoferrocenyl)phosphine Ligand. Crystal Structure of the Two Rotamers of a Palladium(0) Maleic Anhydride Complex

1998 ◽  
Vol 17 (21) ◽  
pp. 4634-4644 ◽  
Author(s):  
Felipe Gómez-de la Torre ◽  
Félix A. Jalón ◽  
Ana López-Agenjo ◽  
Blanca R. Manzano ◽  
Ana Rodríguez ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Comparative Analysis ◽  
Maleic Anhydride ◽  
Phosphine Ligand ◽  
Bond Rupture ◽  
Chiral Complexes

scholarly journals Notizen: Ungewöhnliche Umlagerung eines Phosphinliganden in der Koordinationssphäre von Palladium / Unusual Rearrangement of a Phosphine Ligand in the Coordination Sphere of Palladium

1983 ◽  
Vol 38 (10) ◽  
pp. 1295-1298 ◽  
Author(s):  
D. Fenske ◽  
A. Christidis
Keyword(s):  
Crystal Structure ◽  
Maleic Anhydride ◽  
Structure Analysis ◽  
Coordination Sphere ◽  
Crystal Structure Analysis ◽  
Phosphine Ligand ◽  
X Ray ◽  
Unusual Rearrangement ◽  
New Type

(η3-Allyl)(η5-cyclopentadienyl)palladium reacts with bis(diphenylphosphino)maleic anhydride to form a complex in which the C5H5 ligand is inserted into a P-C bond of the phosphine ligand. Reaction of this compound with iodine leads to a new type of phosphino ligand. The structure is studied by X-ray crystal structure analysis.

The crystal structure of maleic anhydride

1962 ◽  
Vol 15 (1) ◽  
pp. 35-41 ◽  
Author(s):  
R. E. Marsh ◽  
E. Ubell ◽  
H. E. Wilcox
Keyword(s):  
Crystal Structure ◽  
Maleic Anhydride

Crystal architecture of R 2SnS5 (R = Pr, Nd, Gd and Tb): crystal structure relationships in chalcogenides

2008 ◽  
Vol 64 (2) ◽  
pp. 172-176 ◽  
Author(s):  
Marek Daszkiewicz ◽  
Lubomir D. Gulay ◽  
Vasylyna Ya. Shemet
Keyword(s):  
Crystal Structure ◽  
Comparative Analysis ◽  
Single Crystal ◽  
Copper Ions ◽  
Stoichiometric Compound ◽  
Single Crystal Diffraction ◽  
Interatomic Distances ◽  
X Ray ◽  
Structural Relationships ◽  
Complex Architecture

The crystal structure of the R 2SnS5 (R = Pr, Nd, Gd and Tb) compounds has been investigated using X-ray single-crystal diffraction. Crystal architecture and structural relationships among U3S5, Y2HfS5, R 2SnS5 compounds are discussed and a structural origin is determined. It is shown that the complex architecture of the crystal structure of Eu5Sn3S12 is a result of interweaving of the simple crystal structures. The location of the copper ions in the non-stoichiometric compound Y2Cu0.20Sn0.95S5 is proposed on the basis of comparative analysis of the R—S interatomic distances in the R 2SnS5 series of compounds.

scholarly journals The putative polysaccharide deacetylase Ba0331: cloning, expression, crystallization and structure determination

2019 ◽  
Vol 75 (4) ◽  
pp. 312-320
Author(s):  
Athena Andreou ◽  
Petros Giastas ◽  
Sofia Arnaouteli ◽  
Mary Tzanodaskalaki ◽  
Socrates J. Tzartos ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Comparative Analysis ◽  
Bacillus Anthracis ◽  
Structure Determination ◽  
Cell Shape ◽  
Catalytic Domain ◽  
Extreme Conditions ◽  
Carbohydrate Esterase ◽  
Type 3 ◽  
Fibronectin Type

Ba0331 is a putative polysaccharide deacetylase from Bacillus anthracis, the etiological agent of the disease anthrax, that contributes to adaptation of the bacterium under extreme conditions and to maintenance of the cell shape. In the present study, the crystal structure of Ba0331 was determined at 2.6 Å resolution. The structure consists of two domains: a fibronectin type 3-like (Fn3-like) domain and a NodB catalytic domain. The latter is present in all carbohydrate esterase family 4 enzymes, while a comparative analysis of the Fn3-like domain revealed structural plasticity despite the retention of the conserved Fn3-like domain characteristics.

Conformational Studies of Triazole Based Flexible Molecules: A Comparative Analysis of Crystal Structure and Optimized Structure for DNA Binding Ability

2017 ◽  
Vol 2 (12) ◽  
pp. 3444-3451
Author(s):  
Ranjeet Kumar ◽  
Pratima Yadav ◽  
Shiv Pal ◽  
Krishnan R. Kumar ◽  
Balasubramanian Sridhar ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Comparative Analysis ◽  
Dna Binding ◽  
Binding Ability ◽  
Conformational Studies ◽  
Flexible Molecules

Synthese, Struktur und Reaktivität labiler Rhodium(I)-Komplexe mit iPr2PC2H4NMe2 und iPr2PC2H4OMe als Phosphanliganden / Synthesis, Structure and Reactivity of Labile Rhodium(I) Complexes Containing iPr2PC2H4NMe2 and iPr2PC2H4OMe as Phosphine Ligands

1990 ◽  
Vol 45 (11) ◽  
pp. 1548-1558 ◽  
Author(s):  
Helmut Werner ◽  
Andreas Hampp ◽  
Karl Peters ◽  
Eva Maria Peters ◽  
Leonhard Walz ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Chelate Ring ◽  
Parent Compound ◽  
Phosphine Ligand ◽  
Phosphine Ligands ◽  
X Ray ◽  
Vinylidene Complexes ◽  
Square Planar

Square-planar rhodium(I) complexes [RhCl(iPr2PC2H4Y)2] (8, 9) containing one chelating and one P-bonded monodentate phosphine ligand are prepared from [RhCl(C8H14)2]2 (7) and the new functionalized phosphines iPr2PC2H4Y (5,6). Reaction of 9 (Y = NMe2) with CO and of 8 (Y = OMe) with CO, C2H4, C2H2, C2Ph2 and HC2Ph leads to opening of the chelate ring and formation of the complexes trans-[RhCl(L)(η1-P–iPr2PC2H4Y)2] (10-15). Treatment of 8 with H2 gives the dihydridorhodium(III) compound [RhH2Cl(iPr2PC2H4OMe)2] (16). The vinylidene complexes trans-[RhCl(=C=CHR)(η1-P– iPr2PC2H4OMe)2] (17, 18) are obtained by thermal or pyridine promoted rearrangement of 13 (L = C2H2) and 15 (L = HC2Ph). 13 and 15 have also been used as starting materials for the synthesis of the cyclopentadienyl alkyne and vinylidene complexes 19-21. The X-ray crystal structure of the parent compound 8 was determined.

Influence of Crystal Structure on Thermo-Mechanical Properties of Injection Molded 𝛃-Nucleated iPP

2021 ◽  
Vol 36 (5) ◽  
pp. 545-556
Author(s):  
A. Hamza ◽  
R. K. Arya ◽  
A. D. Palsodkar ◽  
G. R. Bhadu ◽  
S. J. A. Rizvi
Keyword(s):  
Crystal Structure ◽  
Mechanical Properties ◽  
Maleic Anhydride ◽  
Isotactic Polypropylene ◽  
Coupling Agent ◽  
Scanning Calorimetry ◽  
Slow Cooling ◽  
Melt Compounding ◽  
Crystal Fraction ◽  
Injection Molded

Abstract Isotactic polypropylene (iPP) was nucleated in-situ with calcium pimelate during melt compounding. Calcium pimelate is a highly effective β-nucleator for isotactic polypropylene (iPP). The β-nucleated iPP was characterized by wide angle x-ray diffraction (WAXD) and differential scanning calorimetry (DSC) for its crystallinity and crystal structure. In addition, the injection-molded samples were tested for thermo-mechanical properties. It is found that very low quantity (< 0.1 wt. %) of β-nucleator is required to produce sufficiently high β-crystal fraction (Kβ) in isotactic polypropylene. β-nucleated iPP shows increment of 11 to 14 °C in its heat deflection temperature (HDT). It was also observed that slow cooling rate of β-nucleated iPP promotes the formation of β-crystals and that tensile stretching leads to complete transformation of β crystals into a-crystals at room temperature. It was also revealed that the presence of maleic anhydride grafted polypropylene (PP-g-MA), a well-known coupling agent (or compatibilizer), may reduce the (Kβ) value to a marginal extent. It was also observed that the thermo-mechanical properties were not much affected by the presence of PP-g-MA. Therefore, calcium pimelate may be used as β-nucleator in case of neat as well as reinforced polypropylene containing maleic anhydride as coupling agent.

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