Unprecedented Conversion of Benzylideneanilines into Aryl Isocyanides Promoted by a Low-Valent Molybdenum Complex. X-ray Structure oftrans-[Mo(CNPh)(N2)(Ph2PCH2CH2PPh2)2]1

1998 ◽  
Vol 17 (6) ◽  
pp. 1010-1012 ◽  
Author(s):  
Goh Nakamura ◽  
Yuji Harada ◽  
Chirima Arita ◽  
Hidetake Seino ◽  
Yasushi Mizobe ◽  
...  
Keyword(s):  
Molybdenum Complex ◽  
X Ray ◽  
Low Valent

scholarly journals Preparation and Characterization of Immobilized Molybdenum Complex on Pillared Montmorillonite K-10

2018 ◽  
Vol 1 (1) ◽  
Author(s):  
Farah Wahida Harun ◽  
Siti Balkis Mahamat Nor ◽  
Siti Salhah Othman
Keyword(s):  
Structural Characteristics ◽  
Xrd Analysis ◽  
Attenuated Total Reflection ◽  
Basal Spacing ◽  
Molybdenum Complex ◽  
X Ray ◽  
Pillared Montmorillonite ◽  
Sem Micrograph ◽  
Pillaring Solution

This study was carried out to immobilize molybdenyl (VI) acetylacetonate (MoO2(acac)2) complex on alumina pillared montmorillonite K-10 (MMT K-10). Pillar MMT K-10 was produced by introducing MMT K-10 with a hydrolysis solution of NaOH with AlCl3. Different concentrations of pillaring solution were prepared in terms of OHto Al3+ ratio (0.5, 1.0, 1.5 and 2.0) to observe the structural characteristics of MMT K-10. The pillared materials were then immobilized with 0.1 M MoO2(acac)2 and were characterized using X-ray diffractometry (XRD), scanning electron microscopy coupled in an energy dispersive X-ray spectrometer (SEM-EDX) and Fourier transform infrared spectroscopy with attenuated total reflection (FTIR-ATR) techniques. FTIR bands at ca. 890 – 930 cm-1 indicate that the Mo complex was immobilized on the surface of pillared MMT K-10 not in between the layers. This is supported by the SEM and XRD analysis where the SEM micrograph showed deposition of Mo on the surface of MMT K-10 as well as no modification of basal spacing was observed by XRD. Meanwhile, the d(001) spacing of the alumina pillared MMT K10 samples were seen to increase slightly as the concentration of OH/Al3+ increased.

Preparation, X-ray crystal structure and theoretical study of the bonding in [Mo2O4I2L3] (L = OPPh3), an example of an unsymmetrical dinuclear molybdenum complex

Polyhedron ◽  
1993 ◽  
Vol 12 (10) ◽  
pp. 1215-1225 ◽  
Author(s):  
P. Rabe ◽  
J.E. Guerchais ◽  
J. Sala Pala ◽  
M. El Khalifa ◽  
J.-Y. Saillard ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Theoretical Study ◽  
Molybdenum Complex ◽  
X Ray

3-Hexyne Complexes of M olybdenum(II) and Tungsten(II) Containing 2, 2 '-Bipyridine. X-Ray Crystal Structure of [MoI2(CO)(bipy)(η2-EtC2Et)]

2000 ◽  
Vol 55 (11) ◽  
pp. 1095-1098
Author(s):  
Mutlaq Al-Jahdali ◽  
Paul K. Baker ◽  
Michael B. Hursthouse ◽  
Simon J. Coles
Keyword(s):  
Crystal Structure ◽  
Carbon Monoxide ◽  
Room Temperature ◽  
Octahedral Geometry ◽  
Cationic Complex ◽  
Molybdenum Complex ◽  
Neutral Complex ◽  
Nmr Studies ◽  
X Ray ◽  
C Nmr

Reaction of [MI2(CO)(NCMe)(η2-EtC2Et)2] (M = Mo,W) with one equivalent of 2,2' -bipyridine (bipy) in CH2C12 at room temperature gives either the neutral complex, [MoI2(CO)(bipy)- (η2-EtC2Et)] (1) or the cationic complex, [WI(CO)(bipy)(η2-EtC2Et)2]I (2). The neutral molybdenum complex 1, has been crystallographically characterised, and has a pseudo-octahedral geometry with the iodo-ligand trans to the 3-hexyne, and with the bipy, carbon monoxide and other iodo-ligand occupying the equatorial face. 13C NMR studies show the 3-hexyne is donating four electrons to the molybdenum in 1.

Reactions of sulfur containing heterocumulenes with low-valent molybdenum and tungsten complexes. Oxidative cleavage of a head-to-tail carbon disulfide dimer in a molybdenum complex

1990 ◽  
Vol 29 (25) ◽  
pp. 5074-5080 ◽  
Author(s):  
Ernesto Carmona ◽  
Agustin Galindo ◽  
Angeles Monge ◽  
Miguel Angel Munoz ◽  
Manuel L. Poveda ◽  
...  
Keyword(s):  
Carbon Disulfide ◽  
Oxidative Cleavage ◽  
Molybdenum Complex ◽  
Tungsten Complexes ◽  
Low Valent ◽  
Sulfur Containing ◽  
And Tungsten

X-Ray crystal structure of a molybdenum complex with both end-on hydrazido(2–)- and side-on hydrazido(1–)-ligands

1980 ◽  
Vol 0 (16) ◽  
pp. 786-787 ◽  
Author(s):  
Joseph Chatt ◽  
Jonathan R. Dilworth ◽  
Phillip L. Dahlstrom ◽  
Jon Zubieta
Keyword(s):  
Crystal Structure ◽  
Molybdenum Complex ◽  
X Ray

Reductive homologation of carbon monoxide to a ketenecarboxylate by a low-valent organolanthanide complex: synthesis and x-ray crystal structure of [(C5Me5)4Sm2(O2CCCO)(THF)]2

1985 ◽  
Vol 107 (12) ◽  
pp. 3728-3730 ◽  
Author(s):  
William J. Evans ◽  
Jay W. Grate ◽  
Laura A. Hughes ◽  
Hongming Zhang ◽  
Jerry L. Atwood
Keyword(s):  
Crystal Structure ◽  
Carbon Monoxide ◽  
X Ray ◽  
Low Valent
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