Reactions of sulfur containing heterocumulenes with low-valent molybdenum and tungsten complexes. Oxidative cleavage of a head-to-tail carbon disulfide dimer in a molybdenum complex

Ernesto Carmona; Agustin Galindo; Angeles Monge; Miguel Angel Munoz; Manuel L. Poveda; Caridad Ruiz

doi:10.1021/ic00350a013

Reactions of sulfur containing heterocumulenes with low-valent molybdenum and tungsten complexes. Oxidative cleavage of a head-to-tail carbon disulfide dimer in a molybdenum complex

Inorganic Chemistry ◽

10.1021/ic00350a013 ◽

1990 ◽

Vol 29 (25) ◽

pp. 5074-5080 ◽

Cited By ~ 20

Author(s):

Ernesto Carmona ◽

Agustin Galindo ◽

Angeles Monge ◽

Miguel Angel Munoz ◽

Manuel L. Poveda ◽

...

Keyword(s):

Carbon Disulfide ◽

Oxidative Cleavage ◽

Molybdenum Complex ◽

Tungsten Complexes ◽

Low Valent ◽

Sulfur Containing ◽

And Tungsten

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Oxidative addition of thiols, and thiol/thiolate exchange reactions of low valent molybdenum and tungsten complexes. Synthetic, structural and calorimetric study of trigonal prismatic W(CO)2(1,10-phenanthroline)(3,4-toluenedithiolate)

Inorganica Chimica Acta ◽

10.1016/s0020-1693(02)01489-5 ◽

2003 ◽

Vol 348 ◽

pp. 157-164 ◽

Cited By ~ 6

Author(s):

Russell F. Lang ◽

Telvin D. Ju ◽

Jeffrey C. Bryan ◽

Gregory J. Kubas ◽

Carl D. Hoff

Keyword(s):

Oxidative Addition ◽

Calorimetric Study ◽

Exchange Reactions ◽

Tungsten Complexes ◽

Low Valent ◽

Trigonal Prismatic ◽

And Tungsten

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ChemInform Abstract: SULFUR-CONTAINING METAL COMPLEXES. PART 9. SYNTHESIS OF TRISUBSTITUTED AMINOCARBENE-THIOETHER CHELATES OF CHROMIUM(0) AND TUNGSTEN(0)

Chemischer Informationsdienst ◽

10.1002/chin.198438275 ◽

1984 ◽

Vol 15 (38) ◽

Author(s):

J. C. VILJOEN ◽

S. LOTZ ◽

L. LINFORD ◽

H. G. RAUBENHEIMER

Keyword(s):

Metal Complexes ◽

Sulfur Containing ◽

And Tungsten

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Novel synthesis of reduced mixed-valence molybdenum and tungsten complexes by electrochemical oxidation of the seven-coordinate complexes MX(S2)(R2dtc)2 (M = Mo, X = O; M = W, X = O, S; R = alkyl; dtc = dithiocarbamate)

Inorganic Chemistry ◽

10.1021/ic00279a008 ◽

1988 ◽

Vol 27 (6) ◽

pp. 978-985 ◽

Cited By ~ 7

Author(s):

A. M. Bond ◽

J. A. Broomhead ◽

A. F. Hollenkamp

Keyword(s):

Electrochemical Oxidation ◽

Mixed Valence ◽

Tungsten Complexes ◽

Novel Synthesis ◽

And Tungsten

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Eine effiziente Synthesemethode für DiarylallenyIiden(pentacarbonyl)chrom- und -wolfram-Komplexe -Kristallstruktur von (CO)5Cr=C=C=CPh2 / An efficient Synthesis of Diarylallenylidene Pentacarbonyl Chromium and Tungsten Complexes - Crystal Structure of (CO)5Cr=C=C=CPh2

Zeitschrift für Naturforschung B ◽

10.1515/znb-1994-0909 ◽

1994 ◽

Vol 49 (9) ◽

pp. 1207-1214 ◽

Cited By ~ 18

Author(s):

Helmut Fischer ◽

David Reindl ◽

Gerhard Roth

Keyword(s):

Crystal Structure ◽

Structure Analysis ◽

Good Yield ◽

Efficient Synthesis ◽

X Ray ◽

Tungsten Complexes ◽

And Tungsten

An efficient synthesis of diarylallenylidene pentacarbonyl chromium and tungsten complexes is presented. Irradiation of M(CO)6 in THF affords (CO)sM[THF], Substitution of the THF ligand by diarylpropargylalcoholate and subsequent desoxygenation with COCF gives the title compounds in good yield. (The structure of diphenylallenylidene pentacarbonyl chromium has been determined by X-ray structure analysis

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ChemInform Abstract: Polynuclear Metal Complexes with Bridging Carbene or Carbyne Ligands. Part 92. Synthesis of Alkynylmethylidyne-Molybdenum and -Tungsten Complexes and Their Reactions with (Co2(CO)8) and (Mo2(CO)6(η-C5H5)2).

ChemInform ◽

10.1002/chin.199009283 ◽

1990 ◽

Vol 21 (9) ◽

Author(s):

I. J. HART ◽

A. F. HILL ◽

F. G. A. STONE

Keyword(s):

Metal Complexes ◽

Tungsten Complexes ◽

Polynuclear Metal Complexes ◽

And Tungsten

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Nature of M-(η2-H-SiR2) bonds in chromium, molybdenum and tungsten complexes [(η5-C5H5)(dmpe)M(η2-H-SiR2)] and [(η5-C5H5)(CO)2M(η2-H-SiMe2)]: A theoretical study

Polyhedron ◽

10.1016/j.poly.2013.03.034 ◽

2013 ◽

Vol 55 ◽

pp. 241-248 ◽

Cited By ~ 2

Author(s):

Krishna K. Pandey

Keyword(s):

Theoretical Study ◽

Tungsten Complexes ◽

And Tungsten

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Unprecedented Conversion of Benzylideneanilines into Aryl Isocyanides Promoted by a Low-Valent Molybdenum Complex. X-ray Structure oftrans-[Mo(CNPh)(N2)(Ph2PCH2CH2PPh2)2]1

Organometallics ◽

10.1021/om9711281 ◽

1998 ◽

Vol 17 (6) ◽

pp. 1010-1012 ◽

Cited By ~ 6

Author(s):

Goh Nakamura ◽

Yuji Harada ◽

Chirima Arita ◽

Hidetake Seino ◽

Yasushi Mizobe ◽

...

Keyword(s):

Molybdenum Complex ◽

X Ray ◽

Low Valent

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Molybdenum and Tungsten Nitrosyl Complexes with Dithiocarbamate Ligands

Australian Journal of Chemistry ◽

10.1071/ch9791187 ◽

1979 ◽

Vol 32 (6) ◽

pp. 1187 ◽

Cited By ~ 7

Author(s):

JA Broomhead ◽

JR Budge

Keyword(s):

Photochemical Reactions ◽

Molybdenum Complexes ◽

Tungsten Complexes ◽

Nitrosyl Complexes ◽

Infrared Studies ◽

In Cis ◽

And Tungsten

Molybdenum and tungsten nitrosyl complexes with dithiocarbamato ligands have been prepared and characterized by analysis, and 1H n.m.r, and infrared studies. The molybdenum complexes are formulated as seven-coordinate species [Mo(NCO)L(S2CNEt2)2NO]- (L = Cl-, N3-, NCS-),{Mo(NCO)(S2CNEt2)2NO}2N2H4 and [Mo(NCO)B(S2CNEt2)2NO](B = NH3, pyridine). Likely stereochemistries are discussed. New tungsten complexes have been prepared by photochemical reactions of cis-[W(S2CNEt2)2(NO)2] to give [WL2(S2CNEt2)2NO]-, [WL(S2CNEt2)2(Me2SO)NO](L = NCO-, N3-, NCS-) and [W(NCO)(S2CNEt2)2(MeCONMe2)NO]. Assignments for the nitrosyl infrared bands in cis-[MO(S2CNEt2)2(NO)2] and [Mo(NCO)(S,CNEt2)2(Me2SO)NO] havebeen made by using 15NO labelled ligands.

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