Central versus Terminal Attack in Nucleophilic Addition to (π-Allyl)palladium Complexes. Ligand Effects and Mechanism

1997 ◽  
Vol 16 (5) ◽  
pp. 1058-1064 ◽  
Author(s):  
Attila Aranyos ◽  
Kálmán J. Szabó ◽  
Ana M. Castaño ◽  
Jan-E Bäckvall
Keyword(s):  
Nucleophilic Addition ◽  
Palladium Complexes ◽  
Ligand Effects

Ligand effects and nucleophilic addition to (.eta.3-allyl)palladium complexes. A carbon-13 NMR study

1987 ◽  
Vol 6 (3) ◽  
pp. 620-628 ◽  
Author(s):  
Bjoern. Aakermark ◽  
Bertil. Krakenberger ◽  
Sverker. Hansson ◽  
Aldo. Vitagliano
Keyword(s):  
Nucleophilic Addition ◽  
Palladium Complexes ◽  
Ligand Effects ◽  
Nmr Study

Computed ligand effects on the oxidative addition of phenyl halides to phosphine supported palladium(0) catalysts

2014 ◽  
Vol 43 (36) ◽  
pp. 13545-13556 ◽  
Author(s):  
Claire L. McMullin ◽  
Natalie Fey ◽  
Jeremy N. Harvey
Keyword(s):  
Oxidative Addition ◽  
Palladium Complexes ◽  
Reaction Pathways ◽  
Ligand Effects ◽  
Supported Palladium

Reaction pathways for oxidative addition of phenyl halides to palladium complexes have been investigated computationally for L = PCy3, PPh3, PtBu3 and SPhos.

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