Effects of β-Substituents and Ancillary Ligands on the Structure and Stability of (η3-Allyl)palladium Complexes. Implications for the Regioselectivity in Nucleophilic Addition Reactions

1996 ◽  
Vol 118 (33) ◽  
pp. 7818-7826 ◽  
Author(s):  
Kálmán J. Szabó
Keyword(s):  
Nucleophilic Addition ◽  
Palladium Complexes ◽  
Addition Reactions ◽  
Ancillary Ligands ◽  
Structure And Stability

scholarly journals Nucleophilic Addition Reactions of Nitriles to Nitrones under Mild Silylation Conditions

Synlett ◽  
2014 ◽  
Vol 25 (13) ◽  
pp. 1863-1868 ◽  
Author(s):  
Fumihiko Yoshimura ◽  
Keiji Tanino ◽  
Taiki Abe
Keyword(s):  
Nucleophilic Addition ◽  
Addition Reactions

Amide-Directed Reactions of Small Carbocycles

2021 ◽  
Vol 25 ◽  
Author(s):  
Pavel M. Yamanushkin ◽  
Marina Rubina ◽  
Michael Rubin
Keyword(s):  
Transition Metal ◽  
Transition Metals ◽  
Nucleophilic Addition ◽  
Addition Reactions ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

: The topic of this review is the amide-directed functionalization of strained carbocycles — specifically, unsaturated or saturated three- and four-membered rings. The following approaches are discussed: a) directed carbometallation and hydrometallation of cyclopropenes catalyzed by transition metals; b) directed metal-templated nucleophilic addition reactions; c) directed C-H functionalization, including transition metal-catalyzed C-H-activation reactions; and d) directed radical additions.

A Facile Synthesis of a Spironitrone and a Study of Its Cycloaddition and Nucleophilic Addition Reactions

Synthesis ◽  
2008 ◽  
Vol 2008 (20) ◽  
pp. 3319-3325
Author(s):  
Margaret Brimble ◽  
Daryl Crimmins ◽  
Ivaylo Dimitrov ◽  
Patrick O’Connor ◽  
Vittorio Caprio
Keyword(s):  
Nucleophilic Addition ◽  
Addition Reactions ◽  
Facile Synthesis
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