Coupled Redox Reactions, Linkage Isomerization, Hydride Formation, and Acid−Base Relationships in the Decaphenylferrocene System

1997 ◽  
Vol 16 (13) ◽  
pp. 2787-2797 ◽  
Author(s):  
Alan M. Bond ◽  
Ray Colton ◽  
Dirk A. Fiedler ◽  
Leslie D. Field ◽  
Taian He ◽  
...  
Keyword(s):  
Redox Reactions ◽  
Acid Base ◽  
Hydride Formation ◽  
Linkage Isomerization

Acid—base and redox reactions in fused sodium nitrite

1984 ◽  
Vol 74 (1-3) ◽  
pp. 131-141 ◽  
Author(s):  
Osami Abe ◽  
Taizo Utsunomiya ◽  
Yoshio Hoshino
Keyword(s):  
Sodium Nitrite ◽  
Redox Reactions ◽  
Acid Base

scholarly journals TO THE ISSUE OF FINDING THE STOICHIOMETRIC COEFFICIENTS IN THE CHEMICAL REACTIONS

2021 ◽  
Vol 2 ◽  
pp. 19-48
Author(s):  
Jekaterina Aleksejeva ◽  
Sharif Guseynov
Keyword(s):  
Chemical Reactions ◽  
Redox Reactions ◽  
Algebraic Equations ◽  
Computer Implementation ◽  
Acid Base ◽  
Linear Algebraic Equations ◽  
Ill Posed ◽  
Computational Errors

In the present paper, on the basis of the theory of inverse and ill-posed problems, an algorithm is proposed that allows to unambiguously determine the stoichiometric coefficients in the equations of chemical reactions of any type, including redox reactions and acid-base reactions, and, regardless of whether the constructed system of linear algebraic equations for the desired stoichiometric coefficients is underdetermined (i.e. there are fewer equations than unknowns) or overdetermined (i.e. there are more equations than unknowns). The proposed algorithm is a regularized algorithm (according to Tikhonov), which ensures that, in a computer implementation, possible computational errors will not make the comprised system of linear algebraic equations to be incapable of solving.

A new classification scheme for teaching reaction types in general chemistry

2019 ◽  
Vol 0 (0) ◽  
Author(s):  
Bin Wang
Keyword(s):  
General Chemistry ◽  
Chemical Reactions ◽  
Redox Reactions ◽  
Classification Scheme ◽  
College Level ◽  
New Classification ◽  
Acid Base ◽  
Oxidation Reduction ◽  
Upper Level ◽  
Nuanced Understanding

AbstractGeneral chemistry is a freshman-level class required for most science majors and pre-professional undergraduates. A variety of concepts are introduced in this course; among them, chemical reactions are fundamental, but remain a central topic. The author compared 10 textbooks widely used for college-level general chemistry courses. They all cover the three major classes of chemical reactions: precipitation reactions, acid-base reactions, and oxidation-reduction (redox) reactions. However, significant differences in the way these textbooks present the material may cause confusion and misunderstanding for students, including when they move to upper-level courses. The author suggests a modified reaction classification scheme for general chemistry courses, which will provide students a more complete and nuanced understanding of chemical reactions.

Actinide binding by Kläui ligands: REDOX speciation and sorption on an extraction chromatography resin

2008 ◽  
Vol 96 (12) ◽  
Author(s):  
Tatiana G. Levitskaia ◽  
Sergey I. Sinkov ◽  
Gregg J. Lumetta
Keyword(s):  
Extraction Chromatography ◽  
Redox Reactions ◽  
Oxidation States ◽  
Sorption Behavior ◽  
Acid Solutions ◽  
Methyl Derivative ◽  
Acid Base ◽  
High Affinity ◽  
Nitric Acid Solutions ◽  
Actinide Ions

AbstractThe sorption of Eu(III) and actinide ions in various oxidation states from nitric acid solutions by an extraction chromatography resin containing 1 wt. % of the Kläui ligand CpResin samples loaded with various actinide ions were examined spectrophotometrically. No Np(V) and Pu(III) species were identified on the resin; rather, reduction–oxidation (REDOX) reactions occurred during equilibration, resulting in their complete conversion to M(IV) species bound by the Kläui ligand. Similarly, the sorption behavior of Pu(VI) and Np(VI) was complicated by their reduction to M(IV) upon sorption. The observed REDOX processes were apparently driven by the extremely high affinity of the Kläui ligand for the tetravalent ions. The acid–base properties of the methyl derivative of the Kläui ligand were investigated in aqueous solution, and its p

On the Reaction of Naphthalene Diimides with Fluoride Ions: Acid/Base versus Redox Reactions

2017 ◽  
Vol 129 (33) ◽  
pp. 10090-10093 ◽  
Author(s):  
Guillaume Bélanger‐Chabot ◽  
Ahmed Ali ◽  
François P. Gabbaï
Keyword(s):  
Redox Reactions ◽  
Acid Base ◽  
Fluoride Ions ◽  
Naphthalene Diimides

On the Reaction of Naphthalene Diimides with Fluoride Ions: Acid/Base versus Redox Reactions

2017 ◽  
Vol 56 (33) ◽  
pp. 9958-9961 ◽  
Author(s):  
Guillaume Bélanger‐Chabot ◽  
Ahmed Ali ◽  
François P. Gabbaï
Keyword(s):  
Redox Reactions ◽  
Acid Base ◽  
Fluoride Ions ◽  
Naphthalene Diimides
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