Exploring Oxidation of Half-Sandwich Rhodium Complexes: Oxygen Atom Insertion into the Rhodium–Carbon Bond of κ2-Coordinated 2-Phenylpyridine

2014 ◽  
Vol 33 (17) ◽  
pp. 4442-4448 ◽  
Author(s):  
Christopher R. Turlington ◽  
James Morris ◽  
Peter S. White ◽  
William W. Brennessel ◽  
William D. Jones ◽  
...  
Keyword(s):  
Oxygen Atom ◽  
Rhodium Complexes ◽  
Carbon Bond ◽  
Half Sandwich ◽  
Oxygen Atom Insertion

Oxygen Atom Insertion into the Osmium–Carbon Bond via an Organometallic Oxido–Osmium(V) Intermediate

2021 ◽  
Vol 40 (2) ◽  
pp. 102-106
Author(s):  
Hideki Sugimoto ◽  
Kurumi Aoki ◽  
Mayuko Miyanishi ◽  
Yoshihito Shiota ◽  
Kazunari Yoshizawa ◽  
...  
Keyword(s):  
Oxygen Atom ◽  
Carbon Bond ◽  
Oxygen Atom Insertion

Structural and chemical properties of half-sandwich rhodium complexes supported by the bis(2-pyridyl)methane ligand

2019 ◽  
Vol 48 (33) ◽  
pp. 12396-12406 ◽  
Author(s):  
Davide Lionetti ◽  
Victor W. Day ◽  
James D. Blakemore
Keyword(s):  
Chemical Properties ◽  
Oxidation States ◽  
Rhodium Complexes ◽  
Half Sandwich ◽  
And Chemical Properties

The bis(2-pyridyl)methane ligand can support [Cp*Rh] complexes (Cp* = pentamethylcyclopentadienyl) in the Rh(iii) and Rh(ii) oxidation states. Structural and reactivity studies demonstrate significant differences between these complexes and notable analogues bearing the related dimethylbis(2-pyridyl)methane ligand.

scholarly journals Selective Oxygen Atom Insertion into an Aryl–Palladium Bond

2016 ◽  
Vol 35 (16) ◽  
pp. 2645-2654 ◽  
Author(s):  
Ava Behnia ◽  
Paul D. Boyle ◽  
Johanna M. Blacquiere ◽  
Richard J. Puddephatt
Keyword(s):  
Oxygen Atom ◽  
Oxygen Atom Insertion

Mechanistic insights and computational design of half-sandwich iridium and rhodium complexes for hydrogenation of quinoline

2019 ◽  
Vol 43 (22) ◽  
pp. 8459-8464
Author(s):  
Xiuli Yan ◽  
Xinzheng Yang
Keyword(s):  
Dft Calculations ◽  
Hydride Transfer ◽  
Computational Design ◽  
Transfer Mechanism ◽  
Rhodium Complexes ◽  
Half Sandwich

DFT calculations reveal a stepwise proton and hydride transfer mechanism for the hydrogenation of quinoline to 1,2,3,4-tetrahydroquinoline catalysed by half-sandwich Cp*Ir(NHC) complexes.

scholarly journals Strong metal–borane interactions in low-valent cyclopentadienyl rhodium complexes

2019 ◽  
Vol 55 (85) ◽  
pp. 12837-12840
Author(s):  
Maxime Boudjelel ◽  
Sonia Mallet-Ladeira ◽  
Ghenwa Bouhadir ◽  
Didier Bourissou
Keyword(s):  
Rhodium Complexes ◽  
Low Valent ◽  
Half Sandwich

Half-sandwich Rh(i) complexes stabilized by η3-BCC or η1-B borane coordination.

scholarly journals Facile Oxygen Atom Insertion into Unactivated C(sp3)–C(sp2) Single Bonds in Reactions of Iridium(III) Complexes with O2

2013 ◽  
Vol 32 (2) ◽  
pp. 714-717 ◽  
Author(s):  
Crispín Cristóbal ◽  
Eleuterio Álvarez ◽  
Margarita Paneque ◽  
Manuel L. Poveda
Keyword(s):  
Oxygen Atom ◽  
Single Bonds ◽  
Oxygen Atom Insertion

scholarly journals Oxygen Atom Insertion into Iron(II) Phenyl and Methyl Bonds: A Key Step for Catalytic Hydrocarbon Functionalization

2014 ◽  
Vol 33 (19) ◽  
pp. 5597-5605 ◽  
Author(s):  
Jiajun Mei ◽  
Daniel B. Pardue ◽  
Steven E. Kalman ◽  
T. Brent Gunnoe ◽  
Thomas R. Cundari ◽  
...  
Keyword(s):  
Oxygen Atom ◽  
Oxygen Atom Insertion
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