Reaction of 2,8-Bis(o-hydroxyaryl)quinolines with Group 4 Metal Alkyls Resulting in Three Distinct Coordination Modes of the Tridentate Ligand. X-ray Structure of Complexes and Performance as Precursors in Ethylene Polymerization Catalysis

Ilya E. Nifant’ev; Pavel V. Ivchenko; Vladimir V. Bagrov; Sandor M. Nagy; Shahram Mihan; Linda N. Winslow; Andrei V. Churakov

doi:10.1021/om4001555

Reaction of 2,8-Bis(o-hydroxyaryl)quinolines with Group 4 Metal Alkyls Resulting in Three Distinct Coordination Modes of the Tridentate Ligand. X-ray Structure of Complexes and Performance as Precursors in Ethylene Polymerization Catalysis

Organometallics ◽

10.1021/om4001555 ◽

2013 ◽

Vol 32 (9) ◽

pp. 2685-2692 ◽

Cited By ~ 8

Author(s):

Ilya E. Nifant’ev ◽

Pavel V. Ivchenko ◽

Vladimir V. Bagrov ◽

Sandor M. Nagy ◽

Shahram Mihan ◽

...

Keyword(s):

Ethylene Polymerization ◽

Tridentate Ligand ◽

X Ray ◽

Coordination Modes ◽

Group 4 ◽

Polymerization Catalysis ◽

And Performance ◽

Group 4 Metal ◽

Metal Alkyls

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Group 4 Metal Amido Fluorides and Chlorides: Molecular Structures and the First Comparison in Ethylene Polymerization Catalysis

Organometallics ◽

10.1021/om960177v ◽

1996 ◽

Vol 15 (14) ◽

pp. 3176-3181 ◽

Cited By ~ 68

Author(s):

Syed A. A. Shah ◽

Hendrik Dorn ◽

Andreas Voigt ◽

Herbert W. Roesky ◽

Emilio Parisini ◽

...

Keyword(s):

Ethylene Polymerization ◽

Molecular Structures ◽

Group 4 ◽

Polymerization Catalysis ◽

Group 4 Metal

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Brønsted Base-Induced Rearrangement and Nucleophilic Addition of O/N-Functionalized NHCs and Relative Group 4 Metal Complexes for Ethylene Polymerization Catalysis

Organometallics ◽

10.1021/acs.organomet.5b00862 ◽

2016 ◽

Vol 35 (2) ◽

pp. 138-150 ◽

Cited By ~ 8

Author(s):

Li Wan ◽

Dao Zhang

Keyword(s):

Metal Complexes ◽

Nucleophilic Addition ◽

Ethylene Polymerization ◽

Group 4 ◽

Polymerization Catalysis ◽

Brønsted Base ◽

Group 4 Metal

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Quantification of active sites in single-site group 4 metal olefin polymerization catalysis

Coordination Chemistry Reviews ◽

10.1016/j.ccr.2019.01.025 ◽

2019 ◽

Vol 386 ◽

pp. 50-68 ◽

Cited By ~ 12

Author(s):

Xavier Desert ◽

Jean-François Carpentier ◽

Evgueni Kirillov

Keyword(s):

Active Sites ◽

Olefin Polymerization ◽

Single Site ◽

Group 4 ◽

Site Group ◽

Polymerization Catalysis ◽

Group 4 Metal

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Remarkably Robust Group 4 Metal Half-Sandwich Complexes Containing Two Higher Alkyl Ligands: X-ray Structure and Reactivity of the Di-n-butyl Complex [Hf(η5:η1:η1-C5Me4SiMe2NCH2CH2OMe)nBu2]

Organometallics ◽

10.1021/om970446x ◽

1997 ◽

Vol 16 (22) ◽

pp. 4765-4767 ◽

Cited By ~ 20

Author(s):

Francisco Amor ◽

Thomas P. Spaniol ◽

Jun Okuda

Keyword(s):

Sandwich Complexes ◽

X Ray ◽

Group 4 ◽

Group 4 Metal ◽

Half Sandwich

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Synthesis, mechanism and ethylene polymerization catalysis of Ge(iv), Sn(ii) and Zr(iv) complexes derived from substituted β-diketiminates

RSC Advances ◽

10.1039/c6ra11097e ◽

2016 ◽

Vol 6 (65) ◽

pp. 60723-60728 ◽

Cited By ~ 3

Author(s):

Xia Xiao ◽

Xiaomin Hao ◽

Jianliang Bai ◽

Jianbin Chao ◽

Wei Cao ◽

...

Keyword(s):

Ethylene Polymerization ◽

Elimination Reaction ◽

Synthesis Mechanism ◽

X Ray ◽

Polymerization Catalysis

Unusual X-ray characterized crystalline Sn(ii), Ge(iv) and Zr(iv) complexes have been prepared via a salt metathesis and elimination reaction.

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Influence of Metal‐Alkyls on Early‐Stage Ethylene Polymerization over a Cr/SiO 2 Phillips Catalyst: A Bulk Characterization and X‐ray Chemical Imaging Study

Chemistry - A European Journal ◽

10.1002/chem.202002632 ◽

2020 ◽

Author(s):

Maarten K. Jongkind ◽

Florian Meirer ◽

Koen W. Bossers ◽

Iris C. Have ◽

Hendrik Ohldag ◽

...

Keyword(s):

Ethylene Polymerization ◽

Early Stage ◽

Imaging Study ◽

Chemical Imaging ◽

X Ray ◽

Phillips Catalyst ◽

Metal Alkyls

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Group 4 Metal Complexes of the Tetradentate (.eta.4-N,N',S,S')Ph4P2N4S22- and Ph4P2N4S2R- Anions. X-ray Structures of {CpHfCl2[Ph4P2N3(NH)S2]}2, CpZrCl2[Ph4P2N4S(SMe)], and [Me3PNPPh2NSMeNPPh2NH2]Cl

Inorganic Chemistry ◽

10.1021/ic00111a012 ◽

1995 ◽

Vol 34 (7) ◽

pp. 1681-1687 ◽

Cited By ~ 3

Author(s):

Tristram Chivers ◽

Xiaoliang Gao ◽

Masood Parvez

Keyword(s):

Metal Complexes ◽

X Ray ◽

Group 4 ◽

Group 4 Metal

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Alkyl Complexes of Group 4 Metals Containing a Tridentate-Linked Amido−Cyclopentadienyl Ligand: Synthesis, Structure, and Reactivity Including Ethylene Polymerization Catalysis

Organometallics ◽

10.1021/om980722n ◽

1998 ◽

Vol 17 (26) ◽

pp. 5836-5849 ◽

Cited By ~ 46

Author(s):

Francisco Amor ◽

Angelika Butt ◽

Karen E. du Plooy ◽

Thomas P. Spaniol ◽

Jun Okuda

Keyword(s):

Ethylene Polymerization ◽

Alkyl Complexes ◽

Group 4 ◽

Cyclopentadienyl Ligand ◽

Polymerization Catalysis ◽

Group 4 Metals ◽

Ligand Synthesis

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Ethylene polymerization catalyzed by group 4 metal complexes of tridentate heteroscorpionate ligands

Topics in Catalysis ◽

10.1007/s11244-006-0118-2 ◽

2006 ◽

Vol 40 (1-4) ◽

pp. 163-172 ◽

Cited By ~ 13

Author(s):

Stefano Milione ◽

Cinzia Cuomo ◽

Alfonso Grassi

Keyword(s):

Metal Complexes ◽

Ethylene Polymerization ◽

Group 4 ◽

Group 4 Metal

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Preparation of N,N‘-Disilylated 1,8-Diaminonaphthalene Chelates and Their Group 4 Metal Complexes for Ethylene Polymerization

Organometallics ◽

10.1021/om980187r ◽

1998 ◽

Vol 17 (17) ◽

pp. 3648-3655 ◽

Cited By ~ 36

Author(s):

Choong Hoon Lee ◽

Young-Hye La ◽

Soo Jin Park ◽

Joon Won Park

Keyword(s):

Metal Complexes ◽

Ethylene Polymerization ◽

Group 4 ◽

Group 4 Metal

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Reaction of 2,8-Bis(o-hydroxyaryl)quinolines with Group 4 Metal Alkyls Resulting in Three Distinct Coordination Modes of the Tridentate Ligand. X-ray Structure of Complexes and Performance as Precursors in Ethylene Polymerization Catalysis

Group 4 Metal Amido Fluorides and Chlorides: Molecular Structures and the First Comparison in Ethylene Polymerization Catalysis

Brønsted Base-Induced Rearrangement and Nucleophilic Addition of O/N-Functionalized NHCs and Relative Group 4 Metal Complexes for Ethylene Polymerization Catalysis

Quantification of active sites in single-site group 4 metal olefin polymerization catalysis

Remarkably Robust Group 4 Metal Half-Sandwich Complexes Containing Two Higher Alkyl Ligands: X-ray Structure and Reactivity of the Di-n-butyl Complex [Hf(η5:η1:η1-C5Me4SiMe2NCH2CH2OMe)nBu2]

Synthesis, mechanism and ethylene polymerization catalysis of Ge(iv), Sn(ii) and Zr(iv) complexes derived from substituted β-diketiminates

Influence of Metal‐Alkyls on Early‐Stage Ethylene Polymerization over a Cr/SiO 2 Phillips Catalyst: A Bulk Characterization and X‐ray Chemical Imaging Study

Group 4 Metal Complexes of the Tetradentate (.eta.4-N,N',S,S')Ph4P2N4S22- and Ph4P2N4S2R- Anions. X-ray Structures of {Cp*HfCl2[Ph4P2N3(NH)S2]}2, Cp*ZrCl2[Ph4P2N4S(SMe)], and [Me3PNPPh2NSMeNPPh2NH2]Cl

Alkyl Complexes of Group 4 Metals Containing a Tridentate-Linked Amido−Cyclopentadienyl Ligand: Synthesis, Structure, and Reactivity Including Ethylene Polymerization Catalysis

Ethylene polymerization catalyzed by group 4 metal complexes of tridentate heteroscorpionate ligands

Preparation of N,N‘-Disilylated 1,8-Diaminonaphthalene Chelates and Their Group 4 Metal Complexes for Ethylene Polymerization

Group 4 Metal Complexes of the Tetradentate (.eta.4-N,N',S,S')Ph4P2N4S22- and Ph4P2N4S2R- Anions. X-ray Structures of {CpHfCl2[Ph4P2N3(NH)S2]}2, CpZrCl2[Ph4P2N4S(SMe)], and [Me3PNPPh2NSMeNPPh2NH2]Cl