Carbon−Hydrogen Bond Oxidative Addition of Partially Fluorinated Aromatics to a Ni(PiPr3)2Synthon: The Influence of Steric Bulk on the Thermodynamics and Kinetics of C−H Bond Activation

Jillian A. Hatnean; Robert Beck; Jenna D. Borrelli; Samuel A. Johnson

doi:10.1021/om1008499

Carbon−Hydrogen Bond Oxidative Addition of Partially Fluorinated Aromatics to a Ni(PiPr3)2Synthon: The Influence of Steric Bulk on the Thermodynamics and Kinetics of C−H Bond Activation

Organometallics ◽

10.1021/om1008499 ◽

2010 ◽

Vol 29 (22) ◽

pp. 6077-6091 ◽

Cited By ~ 45

Author(s):

Jillian A. Hatnean ◽

Robert Beck ◽

Jenna D. Borrelli ◽

Samuel A. Johnson

Keyword(s):

Hydrogen Bond ◽

Bond Activation ◽

Oxidative Addition ◽

Thermodynamics And Kinetics ◽

Kinetics Of

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Aromatic and aldehyde carbon–hydrogen bond activation at cationic Rh(III) centers. Evaluation of electronic substituent effects on aldehyde binding and C–H oxidative addition

Polyhedron ◽

10.1016/j.poly.2004.09.005 ◽

2004 ◽

Vol 23 (17) ◽

pp. 2943-2954 ◽

Cited By ~ 23

Author(s):

Britton K. Corkey ◽

Felicia L. Taw ◽

Robert G. Bergman ◽

Maurice Brookhart

Keyword(s):

Hydrogen Bond ◽

Bond Activation ◽

Oxidative Addition ◽

Substituent Effects ◽

Carbon Hydrogen Bond Activation

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Intramolecular Hydrogen Bond-Controlled Prolyl Amide Isomerization in Glucosyl 3′(S)-Hydroxy-5′-hydroxymethylproline Hybrids: Influence of aC-5′-Hydroxymethyl Substituent on the Thermodynamics and Kinetics of Prolyl AmideCis/TransIsomerization

The Journal of Organic Chemistry ◽

10.1021/jo9003458 ◽

2009 ◽

Vol 74 (10) ◽

pp. 3735-3743 ◽

Cited By ~ 14

Author(s):

Kaidong Zhang ◽

Robel B. Teklebrhan ◽

G. Schreckenbach ◽

Stacey Wetmore ◽

Frank Schweizer

Keyword(s):

Hydrogen Bond ◽

Intramolecular Hydrogen Bond ◽

Thermodynamics And Kinetics ◽

Amide Isomerization ◽

Intramolecular Hydrogen ◽

Kinetics Of

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ChemInform Abstract: CARBON-HYDROGEN BOND ACTIVATION BY TRANSITION METAL COMPLEXES. OXIDATIVE ADDITION OF ALKYL METHACRYLATE TO RUTHENIUM. THE STRUCTURE OF HYDRIDO(2-N-BUTOXYCARBONYLPROPENYL-C1,O)TRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II)

Chemischer Informationsdienst ◽

10.1002/chin.197638330 ◽

1976 ◽

Vol 7 (38) ◽

pp. no-no

Author(s):

SANSHIRO KOMIYA ◽

TAKASHI ITO ◽

MARTIN COWIE ◽

AKIO YAMAMOTO ◽

JAMES A. IBERS

Keyword(s):

Hydrogen Bond ◽

Transition Metal ◽

Metal Complexes ◽

Transition Metal Complexes ◽

Bond Activation ◽

Oxidative Addition ◽

Alkyl Methacrylate ◽

Carbon Hydrogen Bond Activation

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Kinetics of terminal alkyne sp carbon-hydrogen bond activation catalyzed by silver(I)

Organometallics ◽

10.1021/om00072a028 ◽

1982 ◽

Vol 1 (12) ◽

pp. 1700-1705 ◽

Cited By ~ 23

Author(s):

Glenn S. Lewandos ◽

James W. Maki ◽

Jill P. Ginnebaugh

Keyword(s):

Hydrogen Bond ◽

Bond Activation ◽

Terminal Alkyne ◽

Carbon Hydrogen Bond Activation ◽

Kinetics Of

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The Mechanism of Silicon−Hydrogen and Carbon−Hydrogen Bond Activation by Iridium(III): Production of a Silylene Complex and the First Direct Observation of Ir(III)/Ir(V) C−H Bond Oxidative Addition and Reductive Elimination

Journal of the American Chemical Society ◽

10.1021/ja992954z ◽

2000 ◽

Vol 122 (8) ◽

pp. 1816-1817 ◽

Cited By ~ 67

Author(s):

Steven R. Klei ◽

T. Don Tilley ◽

Robert G. Bergman

Keyword(s):

Hydrogen Bond ◽

Direct Observation ◽

Bond Activation ◽

Oxidative Addition ◽

Reductive Elimination ◽

Carbon Hydrogen Bond Activation

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Carbon-hydrogen bond activation by transition metal complexes. Oxidative addition of alkyl methacrylate to ruthenium. The structure of hydrido(2-n-butoxycarbonylpropenyl-C1,O)tris(triphenylphosphine)ruthenium(II)

Journal of the American Chemical Society ◽

10.1021/ja00429a024 ◽

1976 ◽

Vol 98 (13) ◽

pp. 3874-3884 ◽

Cited By ~ 74

Author(s):

Sanshiro Komiya ◽

Takashi Ito ◽

Martin Cowie ◽

Akio Yamamoto ◽

James A. Ibers

Keyword(s):

Hydrogen Bond ◽

Transition Metal ◽

Metal Complexes ◽

Transition Metal Complexes ◽

Bond Activation ◽

Oxidative Addition ◽

Alkyl Methacrylate ◽

Carbon Hydrogen Bond Activation

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Use of Ligand Steric Properties to Control the Thermodynamics and Kinetics of Oxidative Addition and Reductive Elimination with Pincer-Ligated Rh Complexes

Organometallics ◽

10.1021/acs.organomet.0c00122 ◽

2020 ◽

Vol 39 (10) ◽

pp. 1917-1933 ◽

Cited By ~ 1

Author(s):

Shunyan Gu ◽

Robert J. Nielsen ◽

Kathleen H. Taylor ◽

George C. Fortman ◽

Junqi Chen ◽

...

Keyword(s):

Oxidative Addition ◽

Reductive Elimination ◽

Thermodynamics And Kinetics ◽

Kinetics Of

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Irradiation behavior of pyrolytic silicon carbide

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100074288 ◽

1983 ◽

Vol 41 ◽

pp. 72-73

Author(s):

R. J. Lauf

Keyword(s):

Silicon Carbide ◽

Fission Products ◽

Thermodynamics And Kinetics ◽

Neutron Fluences ◽

Fuel Particles ◽

Sic Coatings ◽

Irradiation Behavior ◽

Kinetics Of ◽

Htgr Fuel

Fuel particles for the High-Temperature Gas-Cooled Reactor (HTGR) contain a layer of pyrolytic silicon carbide to act as a miniature pressure vessel and primary fission product barrier. Optimization of the SiC with respect to fuel performance involves four areas of study: (a) characterization of as-deposited SiC coatings; (b) thermodynamics and kinetics of chemical reactions between SiC and fission products; (c) irradiation behavior of SiC in the absence of fission products; and (d) combined effects of irradiation and fission products. This paper reports the behavior of SiC deposited on inert microspheres and irradiated to fast neutron fluences typical of HTGR fuel at end-of-life.

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