The Mechanism of Silicon−Hydrogen and Carbon−Hydrogen Bond Activation by Iridium(III):  Production of a Silylene Complex and the First Direct Observation of Ir(III)/Ir(V) C−H Bond Oxidative Addition and Reductive Elimination

Steven R. Klei; T. Don Tilley; Robert G. Bergman

doi:10.1021/ja992954z

The Mechanism of Silicon−Hydrogen and Carbon−Hydrogen Bond Activation by Iridium(III): Production of a Silylene Complex and the First Direct Observation of Ir(III)/Ir(V) C−H Bond Oxidative Addition and Reductive Elimination

Journal of the American Chemical Society ◽

10.1021/ja992954z ◽

2000 ◽

Vol 122 (8) ◽

pp. 1816-1817 ◽

Cited By ~ 67

Author(s):

Steven R. Klei ◽

T. Don Tilley ◽

Robert G. Bergman

Keyword(s):

Hydrogen Bond ◽

Direct Observation ◽

Bond Activation ◽

Oxidative Addition ◽

Reductive Elimination ◽

Carbon Hydrogen Bond Activation

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Aromatic and aldehyde carbon–hydrogen bond activation at cationic Rh(III) centers. Evaluation of electronic substituent effects on aldehyde binding and C–H oxidative addition

Polyhedron ◽

10.1016/j.poly.2004.09.005 ◽

2004 ◽

Vol 23 (17) ◽

pp. 2943-2954 ◽

Cited By ~ 23

Author(s):

Britton K. Corkey ◽

Felicia L. Taw ◽

Robert G. Bergman ◽

Maurice Brookhart

Keyword(s):

Hydrogen Bond ◽

Bond Activation ◽

Oxidative Addition ◽

Substituent Effects ◽

Carbon Hydrogen Bond Activation

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ChemInform Abstract: CARBON-HYDROGEN BOND ACTIVATION BY TRANSITION METAL COMPLEXES. OXIDATIVE ADDITION OF ALKYL METHACRYLATE TO RUTHENIUM. THE STRUCTURE OF HYDRIDO(2-N-BUTOXYCARBONYLPROPENYL-C1,O)TRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II)

Chemischer Informationsdienst ◽

10.1002/chin.197638330 ◽

1976 ◽

Vol 7 (38) ◽

pp. no-no

Author(s):

SANSHIRO KOMIYA ◽

TAKASHI ITO ◽

MARTIN COWIE ◽

AKIO YAMAMOTO ◽

JAMES A. IBERS

Keyword(s):

Hydrogen Bond ◽

Transition Metal ◽

Metal Complexes ◽

Transition Metal Complexes ◽

Bond Activation ◽

Oxidative Addition ◽

Alkyl Methacrylate ◽

Carbon Hydrogen Bond Activation

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Carbon−Hydrogen Bond Activation with a Cyclometalated Zirconocene Hydride: Mechanistic Differences between Arene and Alkane Reductive Elimination

Organometallics ◽

10.1021/om0508379 ◽

2006 ◽

Vol 25 (5) ◽

pp. 1092-1100 ◽

Cited By ~ 11

Author(s):

Wesley H. Bernskoetter ◽

Jaime A. Pool ◽

Emil Lobkovsky ◽

Paul J. Chirik

Keyword(s):

Hydrogen Bond ◽

Bond Activation ◽

Reductive Elimination ◽

Carbon Hydrogen Bond Activation

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Carbon-hydrogen bond activation by transition metal complexes. Oxidative addition of alkyl methacrylate to ruthenium. The structure of hydrido(2-n-butoxycarbonylpropenyl-C1,O)tris(triphenylphosphine)ruthenium(II)

Journal of the American Chemical Society ◽

10.1021/ja00429a024 ◽

1976 ◽

Vol 98 (13) ◽

pp. 3874-3884 ◽

Cited By ~ 74

Author(s):

Sanshiro Komiya ◽

Takashi Ito ◽

Martin Cowie ◽

Akio Yamamoto ◽

James A. Ibers

Keyword(s):

Hydrogen Bond ◽

Transition Metal ◽

Metal Complexes ◽

Transition Metal Complexes ◽

Bond Activation ◽

Oxidative Addition ◽

Alkyl Methacrylate ◽

Carbon Hydrogen Bond Activation

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A structural, kinetic and thermodynamic study of the reversible thermal carbon-hydrogen bond activation/reductive elimination of alkanes at iridium

Journal of the American Chemical Society ◽

10.1021/ja00267a025 ◽

1986 ◽

Vol 108 (7) ◽

pp. 1537-1550 ◽

Cited By ~ 130

Author(s):

J. Michael. Buchanan ◽

Jeffrey M. Stryker ◽

Robert G. Bergman

Keyword(s):

Hydrogen Bond ◽

Bond Activation ◽

Reductive Elimination ◽

Thermodynamic Study ◽

Carbon Hydrogen Bond Activation ◽

Kinetic And Thermodynamic Study

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Pd‐Au Supported Reduced Graphene Oxide Catalyst for Carbon‐ Hydrogen Bond Activation in Benzene

ChemistrySelect ◽

10.1002/slct.202101988 ◽

2021 ◽

Vol 6 (28) ◽

pp. 7111-7117

Author(s):

Deepika Sharma ◽

Kamal Kishor Thakur ◽

Neeraj Gupta

Keyword(s):

Hydrogen Bond ◽

Graphene Oxide ◽

Reduced Graphene Oxide ◽

Oxide Catalyst ◽

Bond Activation ◽

Reduced Graphene ◽

Carbon Hydrogen Bond Activation

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Modeling the Proposed Intermediate in Alkane Carbon−Hydrogen Bond Activation by Cp*(PMe3)Ir(Me)OTf: Synthesis and Stability of Novel Organometallic Iridium(V) Complexes

Organometallics ◽

10.1021/om990255p ◽

1999 ◽

Vol 18 (14) ◽

pp. 2707-2717 ◽

Cited By ~ 39

Author(s):

Peter J. Alaimo ◽

Robert G. Bergman

Keyword(s):

Hydrogen Bond ◽

Bond Activation ◽

Carbon Hydrogen Bond Activation

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Photochemical generation of reactive transition-metal intermediates from air-stable precursors. Carbon-hydrogen bond activation via near-ultraviolet photolysis of CpIr(L)(oxalate) and CpIr(L)(N3)2 complexes

Inorganic Chemistry ◽

10.1021/ic00004a043 ◽

1991 ◽

Vol 30 (4) ◽

pp. 836-840 ◽

Cited By ~ 16

Author(s):

Daniel A. Freedman ◽

Kent R. Mann

Keyword(s):

Hydrogen Bond ◽

Transition Metal ◽

Bond Activation ◽

Photochemical Generation ◽

Near Ultraviolet ◽

Carbon Hydrogen Bond Activation ◽

Ultraviolet Photolysis

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Carbon-hydrogen bond activation using a bis(phosphine)iridium carbonyl hydride and the carbonylation of benzene

Organometallics ◽

10.1021/om00078a013 ◽

1983 ◽

Vol 2 (6) ◽

pp. 764-767 ◽

Cited By ~ 42

Author(s):

Barbara J. Fisher ◽

Richard Eisenberg

Keyword(s):

Hydrogen Bond ◽

Bond Activation ◽

Carbon Hydrogen Bond Activation

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Cationic η2-arene complexes of rhenium in carbon-hydrogen bond activation

Journal of the American Chemical Society ◽

10.1021/ja00340a033 ◽

1983 ◽

Vol 105 (2) ◽

pp. 305-306 ◽

Cited By ~ 30

Author(s):

James R. Sweet ◽

William A. G. Graham

Keyword(s):

Hydrogen Bond ◽

Bond Activation ◽

Arene Complexes ◽

Carbon Hydrogen Bond Activation

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The Mechanism of Silicon−Hydrogen and Carbon−Hydrogen Bond Activation by Iridium(III): Production of a Silylene Complex and the First Direct Observation of Ir(III)/Ir(V) C−H Bond Oxidative Addition and Reductive Elimination

Aromatic and aldehyde carbon–hydrogen bond activation at cationic Rh(III) centers. Evaluation of electronic substituent effects on aldehyde binding and C–H oxidative addition

ChemInform Abstract: CARBON-HYDROGEN BOND ACTIVATION BY TRANSITION METAL COMPLEXES. OXIDATIVE ADDITION OF ALKYL METHACRYLATE TO RUTHENIUM. THE STRUCTURE OF HYDRIDO(2-N-BUTOXYCARBONYLPROPENYL-C1,O)TRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II)

Carbon−Hydrogen Bond Activation with a Cyclometalated Zirconocene Hydride: Mechanistic Differences between Arene and Alkane Reductive Elimination

Carbon-hydrogen bond activation by transition metal complexes. Oxidative addition of alkyl methacrylate to ruthenium. The structure of hydrido(2-n-butoxycarbonylpropenyl-C1,O)tris(triphenylphosphine)ruthenium(II)

A structural, kinetic and thermodynamic study of the reversible thermal carbon-hydrogen bond activation/reductive elimination of alkanes at iridium

Pd‐Au Supported Reduced Graphene Oxide Catalyst for Carbon‐ Hydrogen Bond Activation in Benzene

Modeling the Proposed Intermediate in Alkane Carbon−Hydrogen Bond Activation by Cp*(PMe3)Ir(Me)OTf: Synthesis and Stability of Novel Organometallic Iridium(V) Complexes

Photochemical generation of reactive transition-metal intermediates from air-stable precursors. Carbon-hydrogen bond activation via near-ultraviolet photolysis of Cp*Ir(L)(oxalate) and Cp*Ir(L)(N3)2 complexes

Carbon-hydrogen bond activation using a bis(phosphine)iridium carbonyl hydride and the carbonylation of benzene

Cationic η2-arene complexes of rhenium in carbon-hydrogen bond activation

Photochemical generation of reactive transition-metal intermediates from air-stable precursors. Carbon-hydrogen bond activation via near-ultraviolet photolysis of CpIr(L)(oxalate) and CpIr(L)(N3)2 complexes