Substituent Effects on P−C Reductive Elimination from Styrylpalladium(II) Phosphine Complexes†

2010 ◽  
Vol 29 (21) ◽  
pp. 5570-5578 ◽  
Author(s):  
Masayuki Wakioka ◽  
Fumiyuki Ozawa
Keyword(s):  
Substituent Effects ◽  
Reductive Elimination ◽  
Phosphine Complexes

Substituent Effects on Reductive Elimination from Disubstituted Aryl Hydride Complexes: Mechanistic and Thermodynamic Considerations

1995 ◽  
Vol 14 (12) ◽  
pp. 5677-5685 ◽  
Author(s):  
Anthony D. Selmeczy ◽  
William D. Jones ◽  
Robert Osman ◽  
Robin Perutz
Keyword(s):  
Substituent Effects ◽  
Reductive Elimination ◽  
Hydride Complexes

The importance of cyclopentadienyl substituent effects in group 4 metallocene dinitrogen chemistry

2005 ◽  
Vol 83 (4) ◽  
pp. 286-295 ◽  
Author(s):  
Jaime A Pool ◽  
Paul J Chirik
Keyword(s):  
Alkali Metal ◽  
Substituent Effects ◽  
Reductive Elimination ◽  
Sandwich Complex ◽  
Group 4 ◽  
Dinitrogen Complexes ◽  
The Future ◽  
Elimination Reactions

This article highlights some of our recent efforts and presents new data on the importance of cyclopentadienyl substituent effects on group 4 metallocene dinitrogen chemistry. Reactions such as the coordination of N2 to an isolated titanium sandwich complex, alkali-metal reductions of zirconocene dihalide complexes, alkane reductive elimination reactions, and the hydrogenation of zirconium dinitrogen complexes are all extremely sensitive to the groups present on the cyclopentadienyl rings. These results are promising for the future of N2 fixation, as the reactivity of a specific metallocene can be dramatically altered by subtle manipulations in ligand substituents.Key words: cyclopentadienyl, zirconium, dinitrogen, ammonia, sandwich.

Aryl-Halide versus Aryl−Aryl Reductive Elimination in Pt(IV)−Phosphine Complexes

2006 ◽  
Vol 128 (27) ◽  
pp. 8710-8711 ◽  
Author(s):  
Anette Yahav-Levi ◽  
Israel Goldberg ◽  
Arkadi Vigalok
Keyword(s):  
Aryl Halide ◽  
Reductive Elimination ◽  
Phosphine Complexes

Tethered Indenyl−Phosphine Complexes of Ruthenium(II) via Reductive Elimination of a Ruthenium(IV) Complex

2007 ◽  
Vol 26 (14) ◽  
pp. 3352-3361 ◽  
Author(s):  
Sin Yee Ng ◽  
Geok Kheng Tan ◽  
Lip Lin Koh ◽  
Weng Kee Leong ◽  
Lai Yoong Goh
Keyword(s):  
Reductive Elimination ◽  
Phosphine Complexes
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