Aryl-Halide versus Aryl−Aryl Reductive Elimination in Pt(IV)−Phosphine Complexes

2006 ◽  
Vol 128 (27) ◽  
pp. 8710-8711 ◽  
Author(s):  
Anette Yahav-Levi ◽  
Israel Goldberg ◽  
Arkadi Vigalok
Keyword(s):  
Aryl Halide ◽  
Reductive Elimination ◽  
Phosphine Complexes

Intermolecular Oxidative Addition of Aryl Halides to Platinum(II) Alkyl Complexes

2018 ◽  
Author(s):  
Kristof Altus ◽  
Eric Bowes ◽  
D. Dawson Beattie ◽  
Jennifer Love
Keyword(s):  
Aryl Halide ◽  
Oxidative Addition ◽  
Reductive Elimination ◽  
Aryl Halides ◽  
Alkyl Complexes ◽  
Species Isolation

We report the first well-defined example of intermolecular aryl halide oxidative addition (OA) to Pt(II). Complexes of the type (IMes)PtMe<sub>2</sub>(L) and (IMes’)PtMe(L) (L = SMe<sub>2</sub>, pyridine; IMes = <i>N,N</i>-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene; IMes’ = cyclometalated IMes) undergo intermolecular OA of phenyl iodide (PhI) at 60 °C, producing toluene <i>via</i> reductive elimination from a proposed Pt(IV)-phenyl species. Isolation of a model Pt(IV) OA product provides evidence for a Pt(II)/(IV) pathway. The OA of PhI is not limited to Pt(II)-IMes complexes;analogous reactions also proceed with phosphine-ligated Pt(II) dialkyl complexes, demonstrating that this reaction is feasible for a variety of electron-rich Pt(II) complexes bearing labile ligands.

Intermolecular Oxidative Addition of Aryl Halides to Platinum(II) Alkyl Complexes

2018 ◽  
Author(s):  
Kristof Altus ◽  
Eric Bowes ◽  
D. Dawson Beattie ◽  
Jennifer Love
Keyword(s):  
Aryl Halide ◽  
Oxidative Addition ◽  
Reductive Elimination ◽  
Aryl Halides ◽  
Alkyl Complexes ◽  
Species Isolation

We report the first well-defined example of intermolecular aryl halide oxidative addition (OA) to Pt(II). Complexes of the type (IMes)PtMe<sub>2</sub>(L) and (IMes’)PtMe(L) (L = SMe<sub>2</sub>, pyridine; IMes = <i>N,N</i>-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene; IMes’ = cyclometalated IMes) undergo intermolecular OA of phenyl iodide (PhI) at 60 °C, producing toluene <i>via</i> reductive elimination from a proposed Pt(IV)-phenyl species. Isolation of a model Pt(IV) OA product provides evidence for a Pt(II)/(IV) pathway. The OA of PhI is not limited to Pt(II)-IMes complexes;analogous reactions also proceed with phosphine-ligated Pt(II) dialkyl complexes, demonstrating that this reaction is feasible for a variety of electron-rich Pt(II) complexes bearing labile ligands.

Transfer of Aryl Halide to Alkyl Halide: Reductive Elimination of Alkylhalide from Alkylpalladium Halides Containingsyn-β-Hydrogen Atoms

2014 ◽  
Vol 53 (52) ◽  
pp. 14533-14537 ◽  
Author(s):  
Wei Hao ◽  
Junnian Wei ◽  
Weizhi Geng ◽  
Wen-Xiong Zhang ◽  
Zhenfeng Xi
Keyword(s):  
Aryl Halide ◽  
Alkyl Halide ◽  
Reductive Elimination ◽  
Hydrogen Atoms

Transfer of Aryl Halide to Alkyl Halide: Reductive Elimination of Alkylhalide from Alkylpalladium Halides Containingsyn-β-Hydrogen Atoms

2014 ◽  
Vol 126 (52) ◽  
pp. 14761-14765 ◽  
Author(s):  
Wei Hao ◽  
Junnian Wei ◽  
Weizhi Geng ◽  
Wen-Xiong Zhang ◽  
Zhenfeng Xi
Keyword(s):  
Aryl Halide ◽  
Alkyl Halide ◽  
Reductive Elimination ◽  
Hydrogen Atoms

Molecular mechanism of acid-triggered aryl–halide reductive elimination in well-defined aryl–CuIII–halide species

2010 ◽  
Vol 39 (43) ◽  
pp. 10458 ◽  
Author(s):  
Alicia Casitas ◽  
Albert Poater ◽  
Miquel Solà ◽  
Shannon S. Stahl ◽  
Miquel Costas ◽  
...  
Keyword(s):  
Molecular Mechanism ◽  
Aryl Halide ◽  
Reductive Elimination

Tethered Indenyl−Phosphine Complexes of Ruthenium(II) via Reductive Elimination of a Ruthenium(IV) Complex

2007 ◽  
Vol 26 (14) ◽  
pp. 3352-3361 ◽  
Author(s):  
Sin Yee Ng ◽  
Geok Kheng Tan ◽  
Lip Lin Koh ◽  
Weng Kee Leong ◽  
Lai Yoong Goh
Keyword(s):  
Reductive Elimination ◽  
Phosphine Complexes

ChemInform Abstract: Transfer of Aryl Halide to Alkyl Halide: Reductive Elimination of Alkylhalide from Alkylpalladium Halides Containing syn-β-Hydrogen Atoms.

ChemInform ◽  
2015 ◽  
Vol 46 (20) ◽  
pp. no-no
Author(s):  
Wei Hao ◽  
Junnian Wei ◽  
Weizhi Geng ◽  
Wen-Xiong Zhang ◽  
Zhenfeng Xi
Keyword(s):  
Aryl Halide ◽  
Alkyl Halide ◽  
Reductive Elimination ◽  
Hydrogen Atoms
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