Synthesis, Structural Characterization, and Catalytic Evaluation of Palladium Complexes with Homologous Ferrocene-Based Pyridylphosphine Ligands

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Ulrich Siemeling ◽  
Ivana Císařová
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Reactions of telluro ethers with common cyclopalladation precursors gave a variety of palladium complexes ranging from mononuclear,trans-[PdCl2(TeR2)2] to binuclear [Pd2(μ-Cl)2Cl2(TeRR′)2], cyclopalladated [Pd2(μ-OAc)2{RTeCH2C6H2(4,6-Me2)}2] and products formed by Te–C bond cleavage.


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