Palladium Complexes with Carbene and Phosphine Ligands: Synthesis, Structural Characterization, and Direct Arylation Reactions between Aryl Halides and Alkynes

2010 ◽  
Vol 29 (2) ◽  
pp. 463-472 ◽  
Author(s):  
Kai-Ting Chan ◽  
Yi-Hua Tsai ◽  
Wu-Shien Lin ◽  
Jia-Rong Wu ◽  
Shih-Jung Chen ◽  
...  
2009 ◽  
Vol 28 (4) ◽  
pp. 1180-1192 ◽  
Author(s):  
Jitte Flapper ◽  
Huub Kooijman ◽  
Martin Lutz ◽  
Anthony L. Spek ◽  
Piet W. N. M. van Leeuwen ◽  
...  

2010 ◽  
Vol 49 (11) ◽  
pp. 2004-2008 ◽  
Author(s):  
Wei Liu ◽  
Hao Cao ◽  
Aiwen Lei

1999 ◽  
Vol 284 (2) ◽  
pp. 278-283 ◽  
Author(s):  
Shan-Ming Kuang ◽  
Li-Ming Zhang ◽  
Zheng-Zhi Zhang ◽  
Bo-Mu Wu ◽  
Thomas C.W. Mak

2021 ◽  
Vol 10 (4) ◽  
pp. 64-68
Author(s):  
Cuong Vu Minh ◽  
Anh Nguyen Thai ◽  
Nam Phan Thanh Son ◽  
Tung Nguyen Thanh

Coupling reagents toward direct arylation of C2-H bonds in aryl azoles are often limited to aryl halides. Herein we report a functionalization of the acidic sp2 C-H bonds in benzothiazoles with benzaldehyde derivatives. Reactions proceeded in the presence of commercially ready CuFe2O4 catalyst. Scope of functional groups included chloro, nitro, cyano, and ester groups.


2021 ◽  
Author(s):  
Mickaël Avanthay ◽  
Robin Bedford ◽  
Callum Begg ◽  
Dietrich Böse ◽  
Jonathan Clayden ◽  
...  

A recent report in Nature Catalysis detailed the potentially paradigm-shifting organocatalysis of Suzuki cross-coupling of aryl halides with aryl boronic acids, catalysed by simple amine species. We have conducted a reinvestigation of key claims in this paper across multiple academic and industrial laboratories that shows that the observed catalytic activity cannot be due to the amine, but rather is due to tricyclohexylphosphine palladium complexes that are readily entrained during the purification of the amine<b>.</b>


Synthesis ◽  
2019 ◽  
Vol 51 (17) ◽  
pp. 3287-3294
Author(s):  
Antonio Arcadi ◽  
Sandro Cacchi ◽  
Giancarlo Fabrizi ◽  
Andrea Fochetti ◽  
Francesca Ghirga ◽  
...  

A straightforward approach to the synthesis of the challenging 12-arylindolo[1,2-c]quinazolin-6(5H)-ones through the palladium-catalyzed direct arylation of N-benzyl and NH-free [1,2-c]quinazolin-6(5H)-ones with aryl halides is described.


1996 ◽  
Vol 35 (21) ◽  
pp. 6221-6229 ◽  
Author(s):  
Cristina Bolzati ◽  
Francesco Tisato ◽  
Fiorenzo Refosco ◽  
Giuliano Bandoli ◽  
Alessandro Dolmella

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