Synthesis and Structural Characterization of the μ-η1:η5-Ph2PC5H4Ligand-Containing Transition-Metal Cluster and Dinuclear Complexes (μ-η1:η5-Ph2PC5H4)(μ3-S)MFeCo(CO)7(M = Mo, W), (μ-η1:η5-Ph2PC5H4)(μ3-RC)MCo2(CO)7(M = Mo, W; R = Me, Ph), and (μ-η1:η5-Ph2PC5H4)CpMo2(CO)5Obtained from the Studied Isolobal Displacement Reactions

2007 ◽  
Vol 26 (8) ◽  
pp. 1966-1971 ◽  
Author(s):  
Li-Cheng Song ◽  
Guang-Ao Yu ◽  
Yang Liu ◽  
Bang-Shao Yin ◽  
Xiao-Guang Zhang ◽  
...  
Keyword(s):  
Transition Metal ◽  
Structural Characterization ◽  
Metal Cluster ◽  
Dinuclear Complexes ◽  
Transition Metal Cluster ◽  
Displacement Reactions

Isolobal displacement methodology for the synthesis of transition-metal cluster complexes containing various biscyclopentadienyl ligands

2001 ◽  
Vol 73 (2) ◽  
pp. 305-309 ◽  
Author(s):  
Li-Cheng Song ◽  
Dian-Shun Guo
Keyword(s):  
Transition Metal ◽  
Crown Ethers ◽  
Metal Cluster ◽  
Tetrahedral Cluster ◽  
Cluster Complexes ◽  
Transition Metal Cluster ◽  
Displacement Reactions

The isolobal displacement methodology for the synthesis of biscyclopentadienyl-bridged transition-metal cluster complexes has been developed. This methodology involves various isolobal displacement reactions between tetrahedral cluster substrates and Mo/W-containing isolobal reagents, leading to a series of linear biscyclopentadienyl-bridged cluster complexes and cyclic biscyclopentadienyl-bridged cluster crown ethers, respectively.

Sign in / Sign up

Export Citation Format

Share Document