Organometallic chalcogen complexes. XXIII. Preparation and structural characterization of a mixed transition metal cluster complex, [Re2Mo(h5-C5H5)(CO)8](S)[SMo(h5-C5H5)(CO)3], containing triply and quadruply bridging sulfur atoms. New synthetic route to highly clustered metal-sulfur systems

1971 ◽  
Vol 93 (23) ◽  
pp. 6326-6327 ◽  
Author(s):  
Phillip J. Vergamini ◽  
Heinrich Vahrenkamp ◽  
Lawrence F. Dahl
Keyword(s):  
Transition Metal ◽  
Structural Characterization ◽  
Metal Cluster ◽  
Cluster Complex ◽  
Synthetic Route ◽  
Transition Metal Cluster ◽  
Mixed Transition

Mixed Transition Metal/Lanthanide Complexes: Structural Characterization of Solids Containing Cage Amine Chromium(III) Cations and Tris(dipicolinato)lanthanide Anions

1995 ◽  
Vol 48 (4) ◽  
pp. 807 ◽  
Author(s):  
JM Harrowfield ◽  
Y Kim ◽  
BW Skelton ◽  
AH White
Keyword(s):  
Transition Metal ◽  
Crystal Lattice ◽  
Structural Characterization ◽  
Lanthanide Complexes ◽  
Room Temperature ◽  
X Ray ◽  
Structure Determinations ◽  
Full Structure ◽  
Mixed Transition

As the foundation to a survey of interactions between chromium(III) and lanthanide(III) ions within the same crystal lattice, a series of complexes of stoichiometry [Cr((NH2)2sar)]- [ Ln ( dipic )3].8H2O (sar = 3,6,10,13,16,19-hexaazabicyclo[6.6.6] icosane, Ln = La-Lu plus Y, dipic = pyridine-2,6-dicarboxylate) has been synthesized and structurally characterized by room-temperature single-crystal X-ray studies. An isomorphous series is found for all Ln, being triclinic, Pī , a ≈ 18.1, b ≈ 13.3, c ≈ 11 Ǻ, α ≈ 111.5, β ≈ 96.2, γ ≈ 109.2°, Z = 2 formula units, full structure determinations being recorded for Ln = La (conventional R 0.048 on |F| for No 6494 independent 'observed' [I > 3σ(I)] reflections at convergence), Ce (R 0.036 for No 8980) and Lu (R 0.046 for No 6791). A less well defined protonated series, with a 2:3 Cr/ Ln ratio, has also been characterized specifically for Ln = La [orthorhombic, Pbca , a 26.223(8), b 53.17(3), c 18.329(9) Ǻ, Z = 8; R 0.092 for No 5104], the lutetium analogue having a similar cell.

scholarly journals Synthesis and Crystal Structure of a Novel Octahedral Fe4Cr2 Transition Metal Cluster Complex Cp2Cr2Fe4(CO)12(μ6-O)

1999 ◽  
Vol 23 (6) ◽  
pp. 388-389
Author(s):  
Li-Cheng Song ◽  
Wen-Qi Gao ◽  
Xiao-Ying Huang
Keyword(s):  
Crystal Structure ◽  
Transition Metal ◽  
Diffraction Analysis ◽  
Metal Cluster ◽  
Cluster Complex ◽  
X Ray Diffraction ◽  
Synthesis And Crystal Structure ◽  
X Ray ◽  
Transition Metal Cluster

Reaction of Cp(OC)2Cr=S = Cr(CO)2Cp with Fe3(CO)12 affords an encapsulated μ6-O octahedral Fe4Cr2 cluster complex Cp2Cr2Fe4(CO)12(μ6-O), whose crystal structure is determined by X-ray diffraction analysis.

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