Carbon−Hydrogen Bond Activation with a Cyclometalated Zirconocene Hydride:  Mechanistic Differences between Arene and Alkane Reductive Elimination

Wesley H. Bernskoetter; Jaime A. Pool; Emil Lobkovsky; Paul J. Chirik

doi:10.1021/om0508379

Carbon−Hydrogen Bond Activation with a Cyclometalated Zirconocene Hydride: Mechanistic Differences between Arene and Alkane Reductive Elimination

Organometallics ◽

10.1021/om0508379 ◽

2006 ◽

Vol 25 (5) ◽

pp. 1092-1100 ◽

Cited By ~ 11

Author(s):

Wesley H. Bernskoetter ◽

Jaime A. Pool ◽

Emil Lobkovsky ◽

Paul J. Chirik

Keyword(s):

Hydrogen Bond ◽

Bond Activation ◽

Reductive Elimination ◽

Carbon Hydrogen Bond Activation

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The Mechanism of Silicon−Hydrogen and Carbon−Hydrogen Bond Activation by Iridium(III): Production of a Silylene Complex and the First Direct Observation of Ir(III)/Ir(V) C−H Bond Oxidative Addition and Reductive Elimination

Journal of the American Chemical Society ◽

10.1021/ja992954z ◽

2000 ◽

Vol 122 (8) ◽

pp. 1816-1817 ◽

Cited By ~ 67

Author(s):

Steven R. Klei ◽

T. Don Tilley ◽

Robert G. Bergman

Keyword(s):

Hydrogen Bond ◽

Direct Observation ◽

Bond Activation ◽

Oxidative Addition ◽

Reductive Elimination ◽

Carbon Hydrogen Bond Activation

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A structural, kinetic and thermodynamic study of the reversible thermal carbon-hydrogen bond activation/reductive elimination of alkanes at iridium

Journal of the American Chemical Society ◽

10.1021/ja00267a025 ◽

1986 ◽

Vol 108 (7) ◽

pp. 1537-1550 ◽

Cited By ~ 130

Author(s):

J. Michael. Buchanan ◽

Jeffrey M. Stryker ◽

Robert G. Bergman

Keyword(s):

Hydrogen Bond ◽

Bond Activation ◽

Reductive Elimination ◽

Thermodynamic Study ◽

Carbon Hydrogen Bond Activation ◽

Kinetic And Thermodynamic Study

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Pd‐Au Supported Reduced Graphene Oxide Catalyst for Carbon‐ Hydrogen Bond Activation in Benzene

ChemistrySelect ◽

10.1002/slct.202101988 ◽

2021 ◽

Vol 6 (28) ◽

pp. 7111-7117

Author(s):

Deepika Sharma ◽

Kamal Kishor Thakur ◽

Neeraj Gupta

Keyword(s):

Hydrogen Bond ◽

Graphene Oxide ◽

Reduced Graphene Oxide ◽

Oxide Catalyst ◽

Bond Activation ◽

Reduced Graphene ◽

Carbon Hydrogen Bond Activation

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Modeling the Proposed Intermediate in Alkane Carbon−Hydrogen Bond Activation by Cp*(PMe3)Ir(Me)OTf: Synthesis and Stability of Novel Organometallic Iridium(V) Complexes

Organometallics ◽

10.1021/om990255p ◽

1999 ◽

Vol 18 (14) ◽

pp. 2707-2717 ◽

Cited By ~ 39

Author(s):

Peter J. Alaimo ◽

Robert G. Bergman

Keyword(s):

Hydrogen Bond ◽

Bond Activation ◽

Carbon Hydrogen Bond Activation

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Photochemical generation of reactive transition-metal intermediates from air-stable precursors. Carbon-hydrogen bond activation via near-ultraviolet photolysis of CpIr(L)(oxalate) and CpIr(L)(N3)2 complexes

Inorganic Chemistry ◽

10.1021/ic00004a043 ◽

1991 ◽

Vol 30 (4) ◽

pp. 836-840 ◽

Cited By ~ 16

Author(s):

Daniel A. Freedman ◽

Kent R. Mann

Keyword(s):

Hydrogen Bond ◽

Transition Metal ◽

Bond Activation ◽

Photochemical Generation ◽

Near Ultraviolet ◽

Carbon Hydrogen Bond Activation ◽

Ultraviolet Photolysis

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Carbon-hydrogen bond activation using a bis(phosphine)iridium carbonyl hydride and the carbonylation of benzene

Organometallics ◽

10.1021/om00078a013 ◽

1983 ◽

Vol 2 (6) ◽

pp. 764-767 ◽

Cited By ~ 42

Author(s):

Barbara J. Fisher ◽

Richard Eisenberg

Keyword(s):

Hydrogen Bond ◽

Bond Activation ◽

Carbon Hydrogen Bond Activation

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Aromatic and aldehyde carbon–hydrogen bond activation at cationic Rh(III) centers. Evaluation of electronic substituent effects on aldehyde binding and C–H oxidative addition

Polyhedron ◽

10.1016/j.poly.2004.09.005 ◽

2004 ◽

Vol 23 (17) ◽

pp. 2943-2954 ◽

Cited By ~ 23

Author(s):

Britton K. Corkey ◽

Felicia L. Taw ◽

Robert G. Bergman ◽

Maurice Brookhart

Keyword(s):

Hydrogen Bond ◽

Bond Activation ◽

Oxidative Addition ◽

Substituent Effects ◽

Carbon Hydrogen Bond Activation

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Cationic η2-arene complexes of rhenium in carbon-hydrogen bond activation

Journal of the American Chemical Society ◽

10.1021/ja00340a033 ◽

1983 ◽

Vol 105 (2) ◽

pp. 305-306 ◽

Cited By ~ 30

Author(s):

James R. Sweet ◽

William A. G. Graham

Keyword(s):

Hydrogen Bond ◽

Bond Activation ◽

Arene Complexes ◽

Carbon Hydrogen Bond Activation

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Orthometallation in iridium N-heterocycle stabilized carbene complexes via carbon halogen and carbon hydrogen bond activation induced by silver nanoparticles

Inorganica Chimica Acta ◽

10.1016/j.ica.2018.10.016 ◽

2019 ◽

Vol 486 ◽

pp. 1-7 ◽

Cited By ~ 2

Author(s):

Andrew C. Marr ◽

Graham C. Saunders ◽

Hayden P. Thomas ◽

Yue-Ming Wang

Keyword(s):

Hydrogen Bond ◽

Silver Nanoparticles ◽

Bond Activation ◽

Carbene Complexes ◽

Carbon Hydrogen Bond Activation

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New cationic bis(.eta.3-allyl)ruthenium(IV) complexes from allylic carbon-hydrogen bond activation of alkenes

Organometallics ◽

10.1021/om00031a050 ◽

1993 ◽

Vol 12 (7) ◽

pp. 2752-2756 ◽

Cited By ~ 7

Author(s):

Kenji Itoh ◽

Katsuyuki Masuda ◽

Hideaki Ikeda

Keyword(s):

Hydrogen Bond ◽

Bond Activation ◽

Carbon Hydrogen Bond Activation

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Carbon−Hydrogen Bond Activation with a Cyclometalated Zirconocene Hydride: Mechanistic Differences between Arene and Alkane Reductive Elimination

The Mechanism of Silicon−Hydrogen and Carbon−Hydrogen Bond Activation by Iridium(III): Production of a Silylene Complex and the First Direct Observation of Ir(III)/Ir(V) C−H Bond Oxidative Addition and Reductive Elimination

A structural, kinetic and thermodynamic study of the reversible thermal carbon-hydrogen bond activation/reductive elimination of alkanes at iridium

Pd‐Au Supported Reduced Graphene Oxide Catalyst for Carbon‐ Hydrogen Bond Activation in Benzene

Modeling the Proposed Intermediate in Alkane Carbon−Hydrogen Bond Activation by Cp*(PMe3)Ir(Me)OTf: Synthesis and Stability of Novel Organometallic Iridium(V) Complexes

Photochemical generation of reactive transition-metal intermediates from air-stable precursors. Carbon-hydrogen bond activation via near-ultraviolet photolysis of Cp*Ir(L)(oxalate) and Cp*Ir(L)(N3)2 complexes

Carbon-hydrogen bond activation using a bis(phosphine)iridium carbonyl hydride and the carbonylation of benzene

Aromatic and aldehyde carbon–hydrogen bond activation at cationic Rh(III) centers. Evaluation of electronic substituent effects on aldehyde binding and C–H oxidative addition

Cationic η2-arene complexes of rhenium in carbon-hydrogen bond activation

Orthometallation in iridium N-heterocycle stabilized carbene complexes via carbon halogen and carbon hydrogen bond activation induced by silver nanoparticles

New cationic bis(.eta.3-allyl)ruthenium(IV) complexes from allylic carbon-hydrogen bond activation of alkenes

Photochemical generation of reactive transition-metal intermediates from air-stable precursors. Carbon-hydrogen bond activation via near-ultraviolet photolysis of CpIr(L)(oxalate) and CpIr(L)(N3)2 complexes