New Mixed-Metal Sulfido Metal Carbonyl Complexes by Insertion of Metal Carbonyl Groups into the S−S Bond of CpMoMn(CO)5(μ-S2)

2003 ◽  
Vol 22 (12) ◽  
pp. 2492-2497 ◽  
Author(s):  
Richard D. Adams ◽  
Shaobin Miao
Keyword(s):  
Metal Carbonyl ◽  
Carbonyl Groups ◽  
Carbonyl Complexes ◽  
Mixed Metal ◽  
Metal Carbonyl Complexes

Carbonyl migration from phosphorus to the metal in binuclear phosphaketenyl metal carbonyl complexes to give bridging diphosphido complexes

2015 ◽  
Vol 39 (2) ◽  
pp. 1390-1403 ◽  
Author(s):  
Wenjun Lü ◽  
Chaoyang Wang ◽  
Qiong Luo ◽  
Qian-shu Li ◽  
Yaoming Xie ◽  
...  
Keyword(s):  
Metal Carbonyl ◽  
Carbonyl Groups ◽  
Carbonyl Complexes ◽  
Metal Carbonyl Complexes

Carbonyl groups from bridging phosphaketenyl ligands in Mn2(CO)8(μ-PCO)2 are predicted to migrate from phosphorus to manganese upon decarbonylation, giving the diphosphido Mn2(CO)n+2(μ-P2) derivatives.

THE PHOTOCHEMISTRY OF CR(CO)6 IN HIGH PRESSURE LOW TEMPERATURE POLYMER MATRIX MONITORED BY FOURIER TRANSFORM INFRARED AND UV-VIS SPECTROSCOPY

2016 ◽  
Vol 78 (6-4) ◽  
Author(s):  
Farah W. Harun
Keyword(s):  
Low Temperature ◽  
Polymer Matrix ◽  
Matrix Material ◽  
Metal Carbonyl ◽  
Carbonyl Groups ◽  
Carbonyl Complexes ◽  
Metal Carbonyl Complexes ◽  
Teflon Af ◽  
Vis Spectroscopy ◽  
New Type

The aim of this work is to develop a new type of polymer matrix which can be used to study the reactive intermediates produced from UV photolysis of metal carbonyl complexes measured with FTIR as well as UV-vis spectroscopy. The photochemistry of Cr(CO)6 impregnated in Teflon-AF polymer with the presence of N2, CH4 and even weak ligand i.e.Xe and He were conducted at extremely low temperature.  Photolysis of Cr(CO)6 under N2 environment produces up to four carbonyl groups being replaced with the N2. Meanwhile, the photochemistry of Cr(CO)6 under Xe and CH4 produce the reactive complexes of Cr(CO)5(Xe) and Cr(CO)5(CH4)respectively. Teflon-AF was found to be the suitable matrix material as the –C–F– bond binds very weakly to the metal center.

New Mixed-Metal Carbonyl Complexes Containing Bridging 2-Mercapto-1-methylimidazole Ligand

2009 ◽  
Vol 635 (1) ◽  
pp. 76-87 ◽  
Author(s):  
Shishir Ghosh ◽  
Shariff E. Kabir ◽  
Salina Pervin ◽  
G. M. Golzar Hossain ◽  
Daniel T. Haworth ◽  
...  
Keyword(s):  
Metal Carbonyl ◽  
Carbonyl Complexes ◽  
Mixed Metal ◽  
Metal Carbonyl Complexes

Mixed-metal carbonyl complexes of chromium, molybdenum, and tungsten containing bridging Ph2PCH2CH2PPh2

1981 ◽  
Vol 20 (1) ◽  
pp. 283-284 ◽  
Author(s):  
R. L. Keiter ◽  
S. L. Kaiser ◽  
N. P. Hansen ◽  
J. W. Brodack ◽  
L. W. Cary
Keyword(s):  
Metal Carbonyl ◽  
Carbonyl Complexes ◽  
Mixed Metal ◽  
Metal Carbonyl Complexes ◽  
And Tungsten

MULTIPLE SCATTERING EFFECTS IN THE COBALT K-EDGE EXAFS OF METAL CARBONYL COMPLEXES

1986 ◽  
Vol 47 (C8) ◽  
pp. C8-589-C8-592
Author(s):  
N. BINSTED ◽  
S. L. COOK ◽  
J. EVANS ◽  
R. J. PRICE ◽  
G. N. GREAVES
Keyword(s):  
Multiple Scattering ◽  
Metal Carbonyl ◽  
Carbonyl Complexes ◽  
Metal Carbonyl Complexes ◽  
Scattering Effects ◽  
Multiple Scattering Effects
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