Mixed-metal carbonyl complexes of chromium, molybdenum, and tungsten containing bridging Ph2PCH2CH2PPh2

1981 ◽  
Vol 20 (1) ◽  
pp. 283-284 ◽  
Author(s):  
R. L. Keiter ◽  
S. L. Kaiser ◽  
N. P. Hansen ◽  
J. W. Brodack ◽  
L. W. Cary
2014 ◽  
Vol 69 (11-12) ◽  
pp. 1215-1220
Author(s):  
Peter M. Fritz ◽  
Wolfgang Sacher ◽  
Wolfgang Beck

Abstract By use of Re(CO)5FBF3 the complexes with a single unsupported halide or pseudohalide bridge [Cp(OC)2Fe-X-Re(CO)5]+ BF4- (X=Cl, I, PPh2), (OC)5M-X-Re(CO)5 (M=Cr, W; X=Br, I, CN, NCS, SH), (OC)5W-N≡C-C[-C≡N-Re(CO)5]2+ BF4-, Cp(OC)(NC)Fe-C≡N-Re(CO)5, and [(OC)5Re-N3-Re(CO)5]+ BF4- have been synthesized.


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