Molecular Structure and Isomerization in Square-Planar Edge-Sharing Dinuclear Complexes with Alkynyl Bridges

2002 ◽  
Vol 21 (13) ◽  
pp. 2627-2634 ◽  
Author(s):  
Gabriel Aullón ◽  
Santiago Alvarez
Keyword(s):  
Molecular Structure ◽  
Dinuclear Complexes ◽  
Square Planar

scholarly journals The Crystal and Molecular Structure of a trans Square-Planar Complex of Tellurium Dimethanethiosulphonate with Thiourea.

1965 ◽  
Vol 19 ◽  
pp. 2361-2368 ◽  
Author(s):  
Olav Foss ◽  
Kjartan Marøy ◽  
Steinar Husebye ◽  
Svein Solheimsnes ◽  
Brita Swan ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Crystal And Molecular Structure ◽  
Planar Complex ◽  
Square Planar

scholarly journals The Crystal and Molecular Structure of a trans Square-Planar Complex of Tellurium Dibenzenethiosulphonate with Trimethylenethiourea.

1969 ◽  
Vol 23 ◽  
pp. 3206-3216 ◽  
Author(s):  
Kjell Åse ◽  
Georg Lundgren ◽  
Wanda Mark ◽  
Hans Lundström ◽  
Gunner Borch ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Crystal And Molecular Structure ◽  
Planar Complex ◽  
Square Planar

scholarly journals Metal Complexes of π-Expanded Ligand (7): Syntheses, Structures and Properties of Pt(II) Complexes Containing the Isomeric 1- and 2-Alkyliminomethyl Pyrene Ligands

Crystals ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 476 ◽  
Author(s):  
Xuan-Dien Luong ◽  
Xuan-Truong Nguyen
Keyword(s):  
Molecular Structure ◽  
Planar Geometry ◽  
X Ray Diffraction ◽  
X Ray ◽  
Pt Complex ◽  
Physico Chemical ◽  
Clear Explanation ◽  
Square Planar ◽  
Structures And Properties ◽  
The Relationship

A [O,N] bidentate π-expanded ligand system, (E)-1-(n-octylimino)methylpyren-2-ol (2), was newly synthesized via a six-step synthesis from pyrene. The ligand 2 reacts with [PtCl2(PhCN)2] in chlorobenzene and the presence of a base at reflux for 2 h under the formation of (2(Pt)) complex with a yield of 70%. The molecular structure of (2(Pt)), studied by common spectroscopic methods and X-ray diffraction, shows a square planar geometry with a trans-configuration of the ligands. The molecular structure, absorption spectra, electrochemical properties, and phosphorescence characteristics of the (2(Pt)) complex are discussed, emphasizing the comparison with those of the previously reported Pt complex (1(Pt)) containing the isomeric ligands of 2, (E)-2-(n-octylimino)methylpyren-1-ol. The DFT calculations of the two Pt complexes are carried out and exhibit a clear explanation of the relationship between their physico-chemical characteristics.

scholarly journals Bis(μ-diisopropylphosphanido-κ2 P:P)bis[hydrido(triisopropylphosphane-κP)platinum(II)]

2012 ◽  
Vol 68 (6) ◽  
pp. m808-m808
Author(s):  
Nicole Arnold ◽  
Holger Braunschweig ◽  
Alexander Damme
Keyword(s):  
Molecular Structure ◽  
Title Compound ◽  
The Other ◽  
Planar Structure ◽  
Square Planar

In the centrosymmetric molecular structure of the title compound [Pt2(C6H14P)2H2(C9H21P)2], each PtII atom is bound on one side to a phosphane ligand (PiPr3) and a hydrido ligand. On the other side, it is bound to two phosphanide ligands (μ-PiPr2), which engage a bridging position between the two PtII atoms, forming a distorted square-planar structure motif. The Pt...Pt distance is 3.6755 (2) Å. A comparable molecular structure was observed for bis(μ-di-tert-butylphosphanido)bis[hydrido(triethylphosphane)platinum(II)] [Itazaki et al. (2004). Organometallics, 23, 1610–1621].

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