First in-plane coordination of a simple monoolefin in a square-planar complex. Molecular structure of .eta.3-methallyl(triphenylphosphine)(styrene)platinum(II) cation

1983 ◽  
Vol 105 (8) ◽  
pp. 2482-2483 ◽  
Author(s):  
Kunio Miki ◽  
Yasushi Kai ◽  
Nobutami Kasai ◽  
Hideo Kurosawa
Keyword(s):  
Molecular Structure ◽  
Planar Complex ◽  
Square Planar

scholarly journals The Crystal and Molecular Structure of a trans Square-Planar Complex of Tellurium Dimethanethiosulphonate with Thiourea.

1965 ◽  
Vol 19 ◽  
pp. 2361-2368 ◽  
Author(s):  
Olav Foss ◽  
Kjartan Marøy ◽  
Steinar Husebye ◽  
Svein Solheimsnes ◽  
Brita Swan ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Crystal And Molecular Structure ◽  
Planar Complex ◽  
Square Planar

scholarly journals The Crystal and Molecular Structure of a trans Square-Planar Complex of Tellurium Dibenzenethiosulphonate with Trimethylenethiourea.

1969 ◽  
Vol 23 ◽  
pp. 3206-3216 ◽  
Author(s):  
Kjell Åse ◽  
Georg Lundgren ◽  
Wanda Mark ◽  
Hans Lundström ◽  
Gunner Borch ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Crystal And Molecular Structure ◽  
Planar Complex ◽  
Square Planar

scholarly journals The Crystal and Molecular Structure of a trans Square-planar Complex of Tellurium dibenzenethiosulphonate with Ethylenethiourea.

1971 ◽  
Vol 25 ◽  
pp. 2467-2475 ◽  
Author(s):  
Kjell Åse ◽  
Knut Maartmann-Moe ◽  
Jon Oddvar Solheim ◽  
Kjartan Marøy ◽  
Kjeld Schaumburg ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Crystal And Molecular Structure ◽  
Planar Complex ◽  
Square Planar

scholarly journals The Crystal and Molecular Structure of a trans Square-Planar Complex of Tellurium Dibenzenethiosulphonate with Tetramethylthiourea.

1974 ◽  
Vol 28a ◽  
pp. 104-112 ◽  
Author(s):  
Kjell Åse ◽  
Ingvald Roti ◽  
Jon Songstad ◽  
C. E. Schäffer ◽  
Alf Bjørseth ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Crystal And Molecular Structure ◽  
Planar Complex ◽  
Square Planar

scholarly journals Metal Complexes of π-Expanded Ligand (7): Syntheses, Structures and Properties of Pt(II) Complexes Containing the Isomeric 1- and 2-Alkyliminomethyl Pyrene Ligands

Crystals ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 476 ◽  
Author(s):  
Xuan-Dien Luong ◽  
Xuan-Truong Nguyen
Keyword(s):  
Molecular Structure ◽  
Planar Geometry ◽  
X Ray Diffraction ◽  
X Ray ◽  
Pt Complex ◽  
Physico Chemical ◽  
Clear Explanation ◽  
Square Planar ◽  
Structures And Properties ◽  
The Relationship

A [O,N] bidentate π-expanded ligand system, (E)-1-(n-octylimino)methylpyren-2-ol (2), was newly synthesized via a six-step synthesis from pyrene. The ligand 2 reacts with [PtCl2(PhCN)2] in chlorobenzene and the presence of a base at reflux for 2 h under the formation of (2(Pt)) complex with a yield of 70%. The molecular structure of (2(Pt)), studied by common spectroscopic methods and X-ray diffraction, shows a square planar geometry with a trans-configuration of the ligands. The molecular structure, absorption spectra, electrochemical properties, and phosphorescence characteristics of the (2(Pt)) complex are discussed, emphasizing the comparison with those of the previously reported Pt complex (1(Pt)) containing the isomeric ligands of 2, (E)-2-(n-octylimino)methylpyren-1-ol. The DFT calculations of the two Pt complexes are carried out and exhibit a clear explanation of the relationship between their physico-chemical characteristics.

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